Synthesis, crystal structure and magnetic properties of an alternating manganese chain

Detalhes bibliográficos
Autor(a) principal: Silva, Manuela Ramos
Data de Publicação: 2006
Outros Autores: Beja, Ana Matos, Paixão, José António, Martín-Gil, Jesus
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/4401
https://doi.org/10.1016/j.jssc.2006.03.024
Resumo: A new 1D complex has been prepared and characterized. X-ray single crystal structure confirms that the Mn(II) ions assemble in alternating chains with Mn-Mn distances of 3.8432(13) and 4.4428(14) Å. A 3D network of hydrogen bonds links the chains together. The temperature dependence of the magnetic susceptibility reveals that this compound undergoes a magnetic transition and exhibits an antiferromagnetic interaction in the low-temperature phase with two alternating exchange interactions of -2.32(1) and -5.55(1) cm-1.
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spelling Synthesis, crystal structure and magnetic properties of an alternating manganese chainMn(ii) complexesDimethylglycineX-ray structureAntiferromagnetic interactionA new 1D complex has been prepared and characterized. X-ray single crystal structure confirms that the Mn(II) ions assemble in alternating chains with Mn-Mn distances of 3.8432(13) and 4.4428(14) Å. A 3D network of hydrogen bonds links the chains together. The temperature dependence of the magnetic susceptibility reveals that this compound undergoes a magnetic transition and exhibits an antiferromagnetic interaction in the low-temperature phase with two alternating exchange interactions of -2.32(1) and -5.55(1) cm-1.http://www.sciencedirect.com/science/article/B6WM2-4JKC5PW-3/1/57fbdb3ac410627d046c6e4fdf2f0e392006info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttp://hdl.handle.net/10316/4401http://hdl.handle.net/10316/4401https://doi.org/10.1016/j.jssc.2006.03.024engJournal of Solid State Chemistry. 179:7 (2006) 2054-2058Silva, Manuela RamosBeja, Ana MatosPaixão, José AntónioMartín-Gil, Jesusinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2020-11-06T16:49:12Zoai:estudogeral.uc.pt:10316/4401Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:59:43.398605Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Synthesis, crystal structure and magnetic properties of an alternating manganese chain
title Synthesis, crystal structure and magnetic properties of an alternating manganese chain
spellingShingle Synthesis, crystal structure and magnetic properties of an alternating manganese chain
Silva, Manuela Ramos
Mn(ii) complexes
Dimethylglycine
X-ray structure
Antiferromagnetic interaction
title_short Synthesis, crystal structure and magnetic properties of an alternating manganese chain
title_full Synthesis, crystal structure and magnetic properties of an alternating manganese chain
title_fullStr Synthesis, crystal structure and magnetic properties of an alternating manganese chain
title_full_unstemmed Synthesis, crystal structure and magnetic properties of an alternating manganese chain
title_sort Synthesis, crystal structure and magnetic properties of an alternating manganese chain
author Silva, Manuela Ramos
author_facet Silva, Manuela Ramos
Beja, Ana Matos
Paixão, José António
Martín-Gil, Jesus
author_role author
author2 Beja, Ana Matos
Paixão, José António
Martín-Gil, Jesus
author2_role author
author
author
dc.contributor.author.fl_str_mv Silva, Manuela Ramos
Beja, Ana Matos
Paixão, José António
Martín-Gil, Jesus
dc.subject.por.fl_str_mv Mn(ii) complexes
Dimethylglycine
X-ray structure
Antiferromagnetic interaction
topic Mn(ii) complexes
Dimethylglycine
X-ray structure
Antiferromagnetic interaction
description A new 1D complex has been prepared and characterized. X-ray single crystal structure confirms that the Mn(II) ions assemble in alternating chains with Mn-Mn distances of 3.8432(13) and 4.4428(14) Å. A 3D network of hydrogen bonds links the chains together. The temperature dependence of the magnetic susceptibility reveals that this compound undergoes a magnetic transition and exhibits an antiferromagnetic interaction in the low-temperature phase with two alternating exchange interactions of -2.32(1) and -5.55(1) cm-1.
publishDate 2006
dc.date.none.fl_str_mv 2006
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/4401
http://hdl.handle.net/10316/4401
https://doi.org/10.1016/j.jssc.2006.03.024
url http://hdl.handle.net/10316/4401
https://doi.org/10.1016/j.jssc.2006.03.024
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal of Solid State Chemistry. 179:7 (2006) 2054-2058
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv aplication/PDF
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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