The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | https://repositorio-aberto.up.pt/handle/10216/83330 |
Resumo: | Nanocomposites of ultra-high molecular weight polyethylene reinforced with multiwalled carbon nanotubes (UHMWPE/MWCNT) have been prepared with different volume fractions of MWCNTs: 0.2, 0.4, 0.6, 0.8 and 1.0%. DMTA experiments were carried out using a TA Instruments Q800 equipment and the samples were cut from the compressed sheets of polymer and composites. The experiments were conducted on each sample at 12 different frequencies varying from 0.1 Hz to 100 Hz over the temperature range of 22-82 degrees C at an interval of 5 degrees C where the reference temperature was kept at 37 degrees C. It was verified that both horizontal and vertical shifts are necessary to superimpose the dynamic modulus/frequency curves of all cases. The MWCNT did not seem to change the viscoelastic nature of the UHMWPE, i.e. incorporation of up to I wt.% of MWCNTs has negligible influence on the viscoelastic behaviour of the UHMWPE. Hence the same analytical model is applicable for the viscoelastic description of the nanocomposites. |
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The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethyleneEngenharia dos materiaisMaterials engineeringNanocomposites of ultra-high molecular weight polyethylene reinforced with multiwalled carbon nanotubes (UHMWPE/MWCNT) have been prepared with different volume fractions of MWCNTs: 0.2, 0.4, 0.6, 0.8 and 1.0%. DMTA experiments were carried out using a TA Instruments Q800 equipment and the samples were cut from the compressed sheets of polymer and composites. The experiments were conducted on each sample at 12 different frequencies varying from 0.1 Hz to 100 Hz over the temperature range of 22-82 degrees C at an interval of 5 degrees C where the reference temperature was kept at 37 degrees C. It was verified that both horizontal and vertical shifts are necessary to superimpose the dynamic modulus/frequency curves of all cases. The MWCNT did not seem to change the viscoelastic nature of the UHMWPE, i.e. incorporation of up to I wt.% of MWCNTs has negligible influence on the viscoelastic behaviour of the UHMWPE. Hence the same analytical model is applicable for the viscoelastic description of the nanocomposites.20132013-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://repositorio-aberto.up.pt/handle/10216/83330eng0263-822310.1016/j.compstruct.2013.05.027Rui Miranda GuedesCeleste M. C. PereiraAlexandra FonsecaMónica S. A. Oliveirainfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-11-29T12:57:44Zoai:repositorio-aberto.up.pt:10216/83330Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T23:30:30.361114Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene |
title |
The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene |
spellingShingle |
The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene Rui Miranda Guedes Engenharia dos materiais Materials engineering |
title_short |
The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene |
title_full |
The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene |
title_fullStr |
The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene |
title_full_unstemmed |
The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene |
title_sort |
The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene |
author |
Rui Miranda Guedes |
author_facet |
Rui Miranda Guedes Celeste M. C. Pereira Alexandra Fonseca Mónica S. A. Oliveira |
author_role |
author |
author2 |
Celeste M. C. Pereira Alexandra Fonseca Mónica S. A. Oliveira |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Rui Miranda Guedes Celeste M. C. Pereira Alexandra Fonseca Mónica S. A. Oliveira |
dc.subject.por.fl_str_mv |
Engenharia dos materiais Materials engineering |
topic |
Engenharia dos materiais Materials engineering |
description |
Nanocomposites of ultra-high molecular weight polyethylene reinforced with multiwalled carbon nanotubes (UHMWPE/MWCNT) have been prepared with different volume fractions of MWCNTs: 0.2, 0.4, 0.6, 0.8 and 1.0%. DMTA experiments were carried out using a TA Instruments Q800 equipment and the samples were cut from the compressed sheets of polymer and composites. The experiments were conducted on each sample at 12 different frequencies varying from 0.1 Hz to 100 Hz over the temperature range of 22-82 degrees C at an interval of 5 degrees C where the reference temperature was kept at 37 degrees C. It was verified that both horizontal and vertical shifts are necessary to superimpose the dynamic modulus/frequency curves of all cases. The MWCNT did not seem to change the viscoelastic nature of the UHMWPE, i.e. incorporation of up to I wt.% of MWCNTs has negligible influence on the viscoelastic behaviour of the UHMWPE. Hence the same analytical model is applicable for the viscoelastic description of the nanocomposites. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013 2013-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://repositorio-aberto.up.pt/handle/10216/83330 |
url |
https://repositorio-aberto.up.pt/handle/10216/83330 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
0263-8223 10.1016/j.compstruct.2013.05.027 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799135613305225216 |