The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene

Detalhes bibliográficos
Autor(a) principal: Rui Miranda Guedes
Data de Publicação: 2013
Outros Autores: Celeste M. C. Pereira, Alexandra Fonseca, Mónica S. A. Oliveira
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: https://repositorio-aberto.up.pt/handle/10216/83330
Resumo: Nanocomposites of ultra-high molecular weight polyethylene reinforced with multiwalled carbon nanotubes (UHMWPE/MWCNT) have been prepared with different volume fractions of MWCNTs: 0.2, 0.4, 0.6, 0.8 and 1.0%. DMTA experiments were carried out using a TA Instruments Q800 equipment and the samples were cut from the compressed sheets of polymer and composites. The experiments were conducted on each sample at 12 different frequencies varying from 0.1 Hz to 100 Hz over the temperature range of 22-82 degrees C at an interval of 5 degrees C where the reference temperature was kept at 37 degrees C. It was verified that both horizontal and vertical shifts are necessary to superimpose the dynamic modulus/frequency curves of all cases. The MWCNT did not seem to change the viscoelastic nature of the UHMWPE, i.e. incorporation of up to I wt.% of MWCNTs has negligible influence on the viscoelastic behaviour of the UHMWPE. Hence the same analytical model is applicable for the viscoelastic description of the nanocomposites.
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spelling The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethyleneEngenharia dos materiaisMaterials engineeringNanocomposites of ultra-high molecular weight polyethylene reinforced with multiwalled carbon nanotubes (UHMWPE/MWCNT) have been prepared with different volume fractions of MWCNTs: 0.2, 0.4, 0.6, 0.8 and 1.0%. DMTA experiments were carried out using a TA Instruments Q800 equipment and the samples were cut from the compressed sheets of polymer and composites. The experiments were conducted on each sample at 12 different frequencies varying from 0.1 Hz to 100 Hz over the temperature range of 22-82 degrees C at an interval of 5 degrees C where the reference temperature was kept at 37 degrees C. It was verified that both horizontal and vertical shifts are necessary to superimpose the dynamic modulus/frequency curves of all cases. The MWCNT did not seem to change the viscoelastic nature of the UHMWPE, i.e. incorporation of up to I wt.% of MWCNTs has negligible influence on the viscoelastic behaviour of the UHMWPE. Hence the same analytical model is applicable for the viscoelastic description of the nanocomposites.20132013-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://repositorio-aberto.up.pt/handle/10216/83330eng0263-822310.1016/j.compstruct.2013.05.027Rui Miranda GuedesCeleste M. C. PereiraAlexandra FonsecaMónica S. A. Oliveirainfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-11-29T12:57:44Zoai:repositorio-aberto.up.pt:10216/83330Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T23:30:30.361114Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene
title The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene
spellingShingle The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene
Rui Miranda Guedes
Engenharia dos materiais
Materials engineering
title_short The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene
title_full The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene
title_fullStr The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene
title_full_unstemmed The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene
title_sort The effect of carbon nanotubes on viscoelastic behaviour of biomedical grade ultra-high molecular weight polyethylene
author Rui Miranda Guedes
author_facet Rui Miranda Guedes
Celeste M. C. Pereira
Alexandra Fonseca
Mónica S. A. Oliveira
author_role author
author2 Celeste M. C. Pereira
Alexandra Fonseca
Mónica S. A. Oliveira
author2_role author
author
author
dc.contributor.author.fl_str_mv Rui Miranda Guedes
Celeste M. C. Pereira
Alexandra Fonseca
Mónica S. A. Oliveira
dc.subject.por.fl_str_mv Engenharia dos materiais
Materials engineering
topic Engenharia dos materiais
Materials engineering
description Nanocomposites of ultra-high molecular weight polyethylene reinforced with multiwalled carbon nanotubes (UHMWPE/MWCNT) have been prepared with different volume fractions of MWCNTs: 0.2, 0.4, 0.6, 0.8 and 1.0%. DMTA experiments were carried out using a TA Instruments Q800 equipment and the samples were cut from the compressed sheets of polymer and composites. The experiments were conducted on each sample at 12 different frequencies varying from 0.1 Hz to 100 Hz over the temperature range of 22-82 degrees C at an interval of 5 degrees C where the reference temperature was kept at 37 degrees C. It was verified that both horizontal and vertical shifts are necessary to superimpose the dynamic modulus/frequency curves of all cases. The MWCNT did not seem to change the viscoelastic nature of the UHMWPE, i.e. incorporation of up to I wt.% of MWCNTs has negligible influence on the viscoelastic behaviour of the UHMWPE. Hence the same analytical model is applicable for the viscoelastic description of the nanocomposites.
publishDate 2013
dc.date.none.fl_str_mv 2013
2013-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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status_str publishedVersion
dc.identifier.uri.fl_str_mv https://repositorio-aberto.up.pt/handle/10216/83330
url https://repositorio-aberto.up.pt/handle/10216/83330
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0263-8223
10.1016/j.compstruct.2013.05.027
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