Phosphorus fractionation in volcanic lake sediments (Azores – Portugal)
Autor(a) principal: | |
---|---|
Data de Publicação: | 2008 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | https://hdl.handle.net/1822/7536 |
Resumo: | The phosphorus distribution in volcanic sediments of three lakes that are under different anthropogenic pressures in São Miguel island (Azores – Portugal) was evaluated using a sequential extraction scheme. The P-fractionation scheme employs sequential extractions of sediment with NH4Cl, bicarbonate-dithionite (BD), NaOH (at room temperature), HCl and NaOH (at 85 °C) to obtain five P-fractions. The P-fractionation shows that in lakes with higher trophic status (Lake Furnas and Lake Sete Cidades), the NaOH extracted P is the dominant fraction, that contribute with more than 50% to total sedimentary phosphorus. The rank order of P-fractionation for these two lakes was NaOH > NaOH (85 °C) > HCl > BD > NH4Cl for Furnas lake and NaOH > HCl > NaOH (85 °C) > NH4Cl > BD for Sete Cidades lake. On the other hand, the trend of P contribution in the oligotrophic lake Fogo shows that the most inert P pools have the higher concentrations, with more than 50% of the P contribution from the last extraction step with NaOH at 85 °C. For this lake, the rank order of P-fractionation was NH4Cl > BD > NaOH > HCl > NaOH (85 °C). The Phosphorus Maximum Solubilization Potential (P-MSP) was also calculated and the results show that for the more bio-available P-fractions (first and second extraction step), the P-MSP values for Furnas and Sete Cidades lakes are sensibly higher than the results obtained in Fogo lake, an indication of the non-point diffuse load discharged in the first ones. |
id |
RCAP_43f71c73a99b6229e778885ef4918e6f |
---|---|
oai_identifier_str |
oai:repositorium.sdum.uminho.pt:1822/7536 |
network_acronym_str |
RCAP |
network_name_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository_id_str |
7160 |
spelling |
Phosphorus fractionation in volcanic lake sediments (Azores – Portugal)EutrophicationPhosphorus extractionSedimentVolcanic lakesScience & TechnologyThe phosphorus distribution in volcanic sediments of three lakes that are under different anthropogenic pressures in São Miguel island (Azores – Portugal) was evaluated using a sequential extraction scheme. The P-fractionation scheme employs sequential extractions of sediment with NH4Cl, bicarbonate-dithionite (BD), NaOH (at room temperature), HCl and NaOH (at 85 °C) to obtain five P-fractions. The P-fractionation shows that in lakes with higher trophic status (Lake Furnas and Lake Sete Cidades), the NaOH extracted P is the dominant fraction, that contribute with more than 50% to total sedimentary phosphorus. The rank order of P-fractionation for these two lakes was NaOH > NaOH (85 °C) > HCl > BD > NH4Cl for Furnas lake and NaOH > HCl > NaOH (85 °C) > NH4Cl > BD for Sete Cidades lake. On the other hand, the trend of P contribution in the oligotrophic lake Fogo shows that the most inert P pools have the higher concentrations, with more than 50% of the P contribution from the last extraction step with NaOH at 85 °C. For this lake, the rank order of P-fractionation was NH4Cl > BD > NaOH > HCl > NaOH (85 °C). The Phosphorus Maximum Solubilization Potential (P-MSP) was also calculated and the results show that for the more bio-available P-fractions (first and second extraction step), the P-MSP values for Furnas and Sete Cidades lakes are sensibly higher than the results obtained in Fogo lake, an indication of the non-point diffuse load discharged in the first ones.Fundação para a Ciência e a Tecnologia (FCT)Elsevier Ltd.Universidade do MinhoRibeiro, DanielMartins, GilbertoNogueira, R.Cruz, J. VirgílioBrito, A. G.2008-012008-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/7536eng"Chemosphere". ISSN 0045-6535. 70:7 (Jan. 2008) 1256-1263.0045-653510.1016/j.chemosphere.2007.07.06417868771info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-25T02:12:12Zoai:repositorium.sdum.uminho.pt:1822/7536Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-25T02:12:12Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Phosphorus fractionation in volcanic lake sediments (Azores – Portugal) |
title |
Phosphorus fractionation in volcanic lake sediments (Azores – Portugal) |
spellingShingle |
Phosphorus fractionation in volcanic lake sediments (Azores – Portugal) Ribeiro, Daniel Eutrophication Phosphorus extraction Sediment Volcanic lakes Science & Technology |
title_short |
Phosphorus fractionation in volcanic lake sediments (Azores – Portugal) |
title_full |
Phosphorus fractionation in volcanic lake sediments (Azores – Portugal) |
title_fullStr |
Phosphorus fractionation in volcanic lake sediments (Azores – Portugal) |
title_full_unstemmed |
Phosphorus fractionation in volcanic lake sediments (Azores – Portugal) |
title_sort |
Phosphorus fractionation in volcanic lake sediments (Azores – Portugal) |
author |
Ribeiro, Daniel |
author_facet |
Ribeiro, Daniel Martins, Gilberto Nogueira, R. Cruz, J. Virgílio Brito, A. G. |
author_role |
author |
author2 |
Martins, Gilberto Nogueira, R. Cruz, J. Virgílio Brito, A. G. |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Ribeiro, Daniel Martins, Gilberto Nogueira, R. Cruz, J. Virgílio Brito, A. G. |
dc.subject.por.fl_str_mv |
Eutrophication Phosphorus extraction Sediment Volcanic lakes Science & Technology |
topic |
Eutrophication Phosphorus extraction Sediment Volcanic lakes Science & Technology |
description |
The phosphorus distribution in volcanic sediments of three lakes that are under different anthropogenic pressures in São Miguel island (Azores – Portugal) was evaluated using a sequential extraction scheme. The P-fractionation scheme employs sequential extractions of sediment with NH4Cl, bicarbonate-dithionite (BD), NaOH (at room temperature), HCl and NaOH (at 85 °C) to obtain five P-fractions. The P-fractionation shows that in lakes with higher trophic status (Lake Furnas and Lake Sete Cidades), the NaOH extracted P is the dominant fraction, that contribute with more than 50% to total sedimentary phosphorus. The rank order of P-fractionation for these two lakes was NaOH > NaOH (85 °C) > HCl > BD > NH4Cl for Furnas lake and NaOH > HCl > NaOH (85 °C) > NH4Cl > BD for Sete Cidades lake. On the other hand, the trend of P contribution in the oligotrophic lake Fogo shows that the most inert P pools have the higher concentrations, with more than 50% of the P contribution from the last extraction step with NaOH at 85 °C. For this lake, the rank order of P-fractionation was NH4Cl > BD > NaOH > HCl > NaOH (85 °C). The Phosphorus Maximum Solubilization Potential (P-MSP) was also calculated and the results show that for the more bio-available P-fractions (first and second extraction step), the P-MSP values for Furnas and Sete Cidades lakes are sensibly higher than the results obtained in Fogo lake, an indication of the non-point diffuse load discharged in the first ones. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-01 2008-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://hdl.handle.net/1822/7536 |
url |
https://hdl.handle.net/1822/7536 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
"Chemosphere". ISSN 0045-6535. 70:7 (Jan. 2008) 1256-1263. 0045-6535 10.1016/j.chemosphere.2007.07.064 17868771 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Ltd. |
publisher.none.fl_str_mv |
Elsevier Ltd. |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
mluisa.alvim@gmail.com |
_version_ |
1817545324004114432 |