Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons

Detalhes bibliográficos
Autor(a) principal: Bernardo-Gil, M. G.
Data de Publicação: 1988
Outros Autores: Soares, Luís Jesus Santos
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/41780
Resumo: Mutual binary solubility data for perfluoromethylcyclohexane+n-hexane, n-heptane, n-octane, n-nonane, 1-hexene and 1-heptene are reported. NRTL and UNIQUAC parameters, for each experimental temperature, were obtained using a NewtonRaphson technique and the parameters so obtained were linearly correlated with T and T1. UNIFAC group parameters for the interaction CH2/CF3 and CH=CH2/CF3 were obtained from mutual solubility data using the same technique. UNIFAC parameters were correlated with the number of carbon atoms and temperature.
id RCAP_4f16c5d3a6eb0c95d7202619cc825140
oai_identifier_str oai:repositorium.sdum.uminho.pt:1822/41780
network_acronym_str RCAP
network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str 7160
spelling Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbonsScience & TechnologyMutual binary solubility data for perfluoromethylcyclohexane+n-hexane, n-heptane, n-octane, n-nonane, 1-hexene and 1-heptene are reported. NRTL and UNIQUAC parameters, for each experimental temperature, were obtained using a NewtonRaphson technique and the parameters so obtained were linearly correlated with T and T1. UNIFAC group parameters for the interaction CH2/CF3 and CH=CH2/CF3 were obtained from mutual solubility data using the same technique. UNIFAC parameters were correlated with the number of carbon atoms and temperature.ElsevierUniversidade do MinhoBernardo-Gil, M. G.Soares, Luís Jesus Santos19881988-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/41780engBernardo-Gil, M. G.; Soares, L., Mutual binary solubilities: perfluoromethylcyclohexanehydrocarbons. Fluid Phase Equilibria, 41(1-2), 205-214, 19880378-38120378-381210.1016/0378-3812(88)80045-1http://www.journals.elsevier.com/fluid-phase-equilibria/info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:30:42Zoai:repositorium.sdum.uminho.pt:1822/41780Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:25:56.769581Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons
title Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons
spellingShingle Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons
Bernardo-Gil, M. G.
Science & Technology
title_short Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons
title_full Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons
title_fullStr Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons
title_full_unstemmed Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons
title_sort Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons
author Bernardo-Gil, M. G.
author_facet Bernardo-Gil, M. G.
Soares, Luís Jesus Santos
author_role author
author2 Soares, Luís Jesus Santos
author2_role author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Bernardo-Gil, M. G.
Soares, Luís Jesus Santos
dc.subject.por.fl_str_mv Science & Technology
topic Science & Technology
description Mutual binary solubility data for perfluoromethylcyclohexane+n-hexane, n-heptane, n-octane, n-nonane, 1-hexene and 1-heptene are reported. NRTL and UNIQUAC parameters, for each experimental temperature, were obtained using a NewtonRaphson technique and the parameters so obtained were linearly correlated with T and T1. UNIFAC group parameters for the interaction CH2/CF3 and CH=CH2/CF3 were obtained from mutual solubility data using the same technique. UNIFAC parameters were correlated with the number of carbon atoms and temperature.
publishDate 1988
dc.date.none.fl_str_mv 1988
1988-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/41780
url http://hdl.handle.net/1822/41780
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Bernardo-Gil, M. G.; Soares, L., Mutual binary solubilities: perfluoromethylcyclohexanehydrocarbons. Fluid Phase Equilibria, 41(1-2), 205-214, 1988
0378-3812
0378-3812
10.1016/0378-3812(88)80045-1
http://www.journals.elsevier.com/fluid-phase-equilibria/
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
_version_ 1799132745400582144