Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons
Autor(a) principal: | |
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Data de Publicação: | 1988 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/1822/41780 |
Resumo: | Mutual binary solubility data for perfluoromethylcyclohexane+n-hexane, n-heptane, n-octane, n-nonane, 1-hexene and 1-heptene are reported. NRTL and UNIQUAC parameters, for each experimental temperature, were obtained using a NewtonRaphson technique and the parameters so obtained were linearly correlated with T and T1. UNIFAC group parameters for the interaction CH2/CF3 and CH=CH2/CF3 were obtained from mutual solubility data using the same technique. UNIFAC parameters were correlated with the number of carbon atoms and temperature. |
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Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbonsScience & TechnologyMutual binary solubility data for perfluoromethylcyclohexane+n-hexane, n-heptane, n-octane, n-nonane, 1-hexene and 1-heptene are reported. NRTL and UNIQUAC parameters, for each experimental temperature, were obtained using a NewtonRaphson technique and the parameters so obtained were linearly correlated with T and T1. UNIFAC group parameters for the interaction CH2/CF3 and CH=CH2/CF3 were obtained from mutual solubility data using the same technique. UNIFAC parameters were correlated with the number of carbon atoms and temperature.ElsevierUniversidade do MinhoBernardo-Gil, M. G.Soares, Luís Jesus Santos19881988-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/41780engBernardo-Gil, M. G.; Soares, L., Mutual binary solubilities: perfluoromethylcyclohexanehydrocarbons. Fluid Phase Equilibria, 41(1-2), 205-214, 19880378-38120378-381210.1016/0378-3812(88)80045-1http://www.journals.elsevier.com/fluid-phase-equilibria/info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:30:42Zoai:repositorium.sdum.uminho.pt:1822/41780Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:25:56.769581Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons |
title |
Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons |
spellingShingle |
Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons Bernardo-Gil, M. G. Science & Technology |
title_short |
Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons |
title_full |
Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons |
title_fullStr |
Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons |
title_full_unstemmed |
Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons |
title_sort |
Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons |
author |
Bernardo-Gil, M. G. |
author_facet |
Bernardo-Gil, M. G. Soares, Luís Jesus Santos |
author_role |
author |
author2 |
Soares, Luís Jesus Santos |
author2_role |
author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Bernardo-Gil, M. G. Soares, Luís Jesus Santos |
dc.subject.por.fl_str_mv |
Science & Technology |
topic |
Science & Technology |
description |
Mutual binary solubility data for perfluoromethylcyclohexane+n-hexane, n-heptane, n-octane, n-nonane, 1-hexene and 1-heptene are reported. NRTL and UNIQUAC parameters, for each experimental temperature, were obtained using a NewtonRaphson technique and the parameters so obtained were linearly correlated with T and T1. UNIFAC group parameters for the interaction CH2/CF3 and CH=CH2/CF3 were obtained from mutual solubility data using the same technique. UNIFAC parameters were correlated with the number of carbon atoms and temperature. |
publishDate |
1988 |
dc.date.none.fl_str_mv |
1988 1988-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1822/41780 |
url |
http://hdl.handle.net/1822/41780 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Bernardo-Gil, M. G.; Soares, L., Mutual binary solubilities: perfluoromethylcyclohexanehydrocarbons. Fluid Phase Equilibria, 41(1-2), 205-214, 1988 0378-3812 0378-3812 10.1016/0378-3812(88)80045-1 http://www.journals.elsevier.com/fluid-phase-equilibria/ |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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