Hydrothermal synthesis and optimization of boron doped LiZr2(PO4)3 Li-ion solid electrolyte

Detalhes bibliográficos
Autor(a) principal: Yang, Tao
Data de Publicação: 2018
Outros Autores: Almeida, Carlosde, Han, Dezhi, Meng, Lijian, Deng, Jiguang, Silva, E.L. da, Santos, M.C., Shi, Shikao
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.22/11090
Resumo: Boron doped LiZr2(PO4)3 electrolyte was successfully synthesized via facile hydrothermal synthesis. Our results show that boron doping mainly happens on the Zr-site of Li1+xZr2-xBx(PO4)3 not the P-site of Li1+6xZr2(P1-xBxO4)3. Rietveld refinement of the unit-cell parameters was performed, and it was verified by consideration of Vegard’s law that it is possible to obtain phase purity up to x= 0.05 in Li1+xZr2-xBx(PO4)3. This corresponds with phases present in the XRD data, which shows the additional presence of the low temperature (monoclinic) phase for the powder sintered at 1200ºC for 12h of compositions with x ≥ 0.075. The compositions inside the solid solution undergo the phase transition from triclinic to rhombohedral when heating from 25 to 100ºC.
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spelling Hydrothermal synthesis and optimization of boron doped LiZr2(PO4)3 Li-ion solid electrolyteLi1+xZr2-xBx(PO4)3Solid ElectrolyteLithium-Air BatteriesHydrothermalGelBoron doped LiZr2(PO4)3 electrolyte was successfully synthesized via facile hydrothermal synthesis. Our results show that boron doping mainly happens on the Zr-site of Li1+xZr2-xBx(PO4)3 not the P-site of Li1+6xZr2(P1-xBxO4)3. Rietveld refinement of the unit-cell parameters was performed, and it was verified by consideration of Vegard’s law that it is possible to obtain phase purity up to x= 0.05 in Li1+xZr2-xBx(PO4)3. This corresponds with phases present in the XRD data, which shows the additional presence of the low temperature (monoclinic) phase for the powder sintered at 1200ºC for 12h of compositions with x ≥ 0.075. The compositions inside the solid solution undergo the phase transition from triclinic to rhombohedral when heating from 25 to 100ºC.ElsevierRepositório Científico do Instituto Politécnico do PortoYang, TaoAlmeida, CarlosdeHan, DezhiMeng, LijianDeng, JiguangSilva, E.L. daSantos, M.C.Shi, Shikao20182119-01-01T00:00:00Z2018-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.22/11090eng0169-433210.1016/j.apsusc.2018.02.158metadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-03-13T12:53:09Zoai:recipp.ipp.pt:10400.22/11090Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T17:31:25.870277Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Hydrothermal synthesis and optimization of boron doped LiZr2(PO4)3 Li-ion solid electrolyte
title Hydrothermal synthesis and optimization of boron doped LiZr2(PO4)3 Li-ion solid electrolyte
spellingShingle Hydrothermal synthesis and optimization of boron doped LiZr2(PO4)3 Li-ion solid electrolyte
Yang, Tao
Li1+xZr2-xBx(PO4)3
Solid Electrolyte
Lithium-Air Batteries
Hydrothermal
Gel
title_short Hydrothermal synthesis and optimization of boron doped LiZr2(PO4)3 Li-ion solid electrolyte
title_full Hydrothermal synthesis and optimization of boron doped LiZr2(PO4)3 Li-ion solid electrolyte
title_fullStr Hydrothermal synthesis and optimization of boron doped LiZr2(PO4)3 Li-ion solid electrolyte
title_full_unstemmed Hydrothermal synthesis and optimization of boron doped LiZr2(PO4)3 Li-ion solid electrolyte
title_sort Hydrothermal synthesis and optimization of boron doped LiZr2(PO4)3 Li-ion solid electrolyte
author Yang, Tao
author_facet Yang, Tao
Almeida, Carlosde
Han, Dezhi
Meng, Lijian
Deng, Jiguang
Silva, E.L. da
Santos, M.C.
Shi, Shikao
author_role author
author2 Almeida, Carlosde
Han, Dezhi
Meng, Lijian
Deng, Jiguang
Silva, E.L. da
Santos, M.C.
Shi, Shikao
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Repositório Científico do Instituto Politécnico do Porto
dc.contributor.author.fl_str_mv Yang, Tao
Almeida, Carlosde
Han, Dezhi
Meng, Lijian
Deng, Jiguang
Silva, E.L. da
Santos, M.C.
Shi, Shikao
dc.subject.por.fl_str_mv Li1+xZr2-xBx(PO4)3
Solid Electrolyte
Lithium-Air Batteries
Hydrothermal
Gel
topic Li1+xZr2-xBx(PO4)3
Solid Electrolyte
Lithium-Air Batteries
Hydrothermal
Gel
description Boron doped LiZr2(PO4)3 electrolyte was successfully synthesized via facile hydrothermal synthesis. Our results show that boron doping mainly happens on the Zr-site of Li1+xZr2-xBx(PO4)3 not the P-site of Li1+6xZr2(P1-xBxO4)3. Rietveld refinement of the unit-cell parameters was performed, and it was verified by consideration of Vegard’s law that it is possible to obtain phase purity up to x= 0.05 in Li1+xZr2-xBx(PO4)3. This corresponds with phases present in the XRD data, which shows the additional presence of the low temperature (monoclinic) phase for the powder sintered at 1200ºC for 12h of compositions with x ≥ 0.075. The compositions inside the solid solution undergo the phase transition from triclinic to rhombohedral when heating from 25 to 100ºC.
publishDate 2018
dc.date.none.fl_str_mv 2018
2018-01-01T00:00:00Z
2119-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.22/11090
url http://hdl.handle.net/10400.22/11090
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0169-4332
10.1016/j.apsusc.2018.02.158
dc.rights.driver.fl_str_mv metadata only access
info:eu-repo/semantics/openAccess
rights_invalid_str_mv metadata only access
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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