Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide

Detalhes bibliográficos
Autor(a) principal: Martins, Luisa
Data de Publicação: 2013
Outros Autores: Almeida, M. Peixoto de, Carabineiro, S. A. C., Figueiredo, J. L., Pombeiro, Armando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.21/8648
Resumo: The hydrotris(pyrazol-1-yl)methane iron(II) complex [FeCl2{h3-HC(pz)3}] (pz=pyrazol-1-yl) (1) was immobilized on three diferente carbon materials (activated carbon, carbon xerogel and multi-walled carbon nanotubes) with three different surface treatments (original, treated with nitric acid, and treated with nitric acid followed by sodium hydroxide) to produce active, selective and recyclable catalysts. The heterogenisation process was more efficient for carbon nanotubes treated with nitric acid and sodium hydroxide. An outstanding improved catalytic performance of complex 1 upon heterogenisation on carbon nanotubes treated with nitric acid and sodium hydroxide (turnover numbers up to 5.6_103 and overall yield of 21 %), relative to the homogeneous system, was achieved for the single-pot peroxidative oxidation of cyclohexane to the cyclohexanone and cyclohexanol mixture. The heterogenised systems allowed their easy recovery and reuse, at least for five consecutive cycles, maintaining 96% of the initial activity and concomitante rather high selectivity to cyclohexanol and cyclohexanone.
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spelling Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxideAlkanesCarbonIronHeterogenizationOxidationSupported catalystsThe hydrotris(pyrazol-1-yl)methane iron(II) complex [FeCl2{h3-HC(pz)3}] (pz=pyrazol-1-yl) (1) was immobilized on three diferente carbon materials (activated carbon, carbon xerogel and multi-walled carbon nanotubes) with three different surface treatments (original, treated with nitric acid, and treated with nitric acid followed by sodium hydroxide) to produce active, selective and recyclable catalysts. The heterogenisation process was more efficient for carbon nanotubes treated with nitric acid and sodium hydroxide. An outstanding improved catalytic performance of complex 1 upon heterogenisation on carbon nanotubes treated with nitric acid and sodium hydroxide (turnover numbers up to 5.6_103 and overall yield of 21 %), relative to the homogeneous system, was achieved for the single-pot peroxidative oxidation of cyclohexane to the cyclohexanone and cyclohexanol mixture. The heterogenised systems allowed their easy recovery and reuse, at least for five consecutive cycles, maintaining 96% of the initial activity and concomitante rather high selectivity to cyclohexanol and cyclohexanone.Wiley-VCH VerlagRCIPLMartins, LuisaAlmeida, M. Peixoto deCarabineiro, S. A. C.Figueiredo, J. L.Pombeiro, Armando2018-07-02T14:22:28Z2013-122013-12-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.21/8648engMARTINS, Luísa Margarida D. R. S.; [et al] – Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide. C hemCatChem. ISSN:1867-3899. Vol. 5, N.º 12, pp. 3847-3856.1867-389910.1002/cctc.201300432metadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-08-03T09:56:20Zoai:repositorio.ipl.pt:10400.21/8648Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:17:22.623133Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide
title Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide
spellingShingle Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide
Martins, Luisa
Alkanes
Carbon
Iron
Heterogenization
Oxidation
Supported catalysts
title_short Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide
title_full Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide
title_fullStr Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide
title_full_unstemmed Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide
title_sort Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide
author Martins, Luisa
author_facet Martins, Luisa
Almeida, M. Peixoto de
Carabineiro, S. A. C.
Figueiredo, J. L.
Pombeiro, Armando
author_role author
author2 Almeida, M. Peixoto de
Carabineiro, S. A. C.
Figueiredo, J. L.
Pombeiro, Armando
author2_role author
author
author
author
dc.contributor.none.fl_str_mv RCIPL
dc.contributor.author.fl_str_mv Martins, Luisa
Almeida, M. Peixoto de
Carabineiro, S. A. C.
Figueiredo, J. L.
Pombeiro, Armando
dc.subject.por.fl_str_mv Alkanes
Carbon
Iron
Heterogenization
Oxidation
Supported catalysts
topic Alkanes
Carbon
Iron
Heterogenization
Oxidation
Supported catalysts
description The hydrotris(pyrazol-1-yl)methane iron(II) complex [FeCl2{h3-HC(pz)3}] (pz=pyrazol-1-yl) (1) was immobilized on three diferente carbon materials (activated carbon, carbon xerogel and multi-walled carbon nanotubes) with three different surface treatments (original, treated with nitric acid, and treated with nitric acid followed by sodium hydroxide) to produce active, selective and recyclable catalysts. The heterogenisation process was more efficient for carbon nanotubes treated with nitric acid and sodium hydroxide. An outstanding improved catalytic performance of complex 1 upon heterogenisation on carbon nanotubes treated with nitric acid and sodium hydroxide (turnover numbers up to 5.6_103 and overall yield of 21 %), relative to the homogeneous system, was achieved for the single-pot peroxidative oxidation of cyclohexane to the cyclohexanone and cyclohexanol mixture. The heterogenised systems allowed their easy recovery and reuse, at least for five consecutive cycles, maintaining 96% of the initial activity and concomitante rather high selectivity to cyclohexanol and cyclohexanone.
publishDate 2013
dc.date.none.fl_str_mv 2013-12
2013-12-01T00:00:00Z
2018-07-02T14:22:28Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.21/8648
url http://hdl.handle.net/10400.21/8648
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv MARTINS, Luísa Margarida D. R. S.; [et al] – Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide. C hemCatChem. ISSN:1867-3899. Vol. 5, N.º 12, pp. 3847-3856.
1867-3899
10.1002/cctc.201300432
dc.rights.driver.fl_str_mv metadata only access
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rights_invalid_str_mv metadata only access
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley-VCH Verlag
publisher.none.fl_str_mv Wiley-VCH Verlag
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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