Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide
Autor(a) principal: | |
---|---|
Data de Publicação: | 2013 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.21/8648 |
Resumo: | The hydrotris(pyrazol-1-yl)methane iron(II) complex [FeCl2{h3-HC(pz)3}] (pz=pyrazol-1-yl) (1) was immobilized on three diferente carbon materials (activated carbon, carbon xerogel and multi-walled carbon nanotubes) with three different surface treatments (original, treated with nitric acid, and treated with nitric acid followed by sodium hydroxide) to produce active, selective and recyclable catalysts. The heterogenisation process was more efficient for carbon nanotubes treated with nitric acid and sodium hydroxide. An outstanding improved catalytic performance of complex 1 upon heterogenisation on carbon nanotubes treated with nitric acid and sodium hydroxide (turnover numbers up to 5.6_103 and overall yield of 21 %), relative to the homogeneous system, was achieved for the single-pot peroxidative oxidation of cyclohexane to the cyclohexanone and cyclohexanol mixture. The heterogenised systems allowed their easy recovery and reuse, at least for five consecutive cycles, maintaining 96% of the initial activity and concomitante rather high selectivity to cyclohexanol and cyclohexanone. |
id |
RCAP_524fb1bee453cbf75eb5099f2ce82049 |
---|---|
oai_identifier_str |
oai:repositorio.ipl.pt:10400.21/8648 |
network_acronym_str |
RCAP |
network_name_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository_id_str |
7160 |
spelling |
Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxideAlkanesCarbonIronHeterogenizationOxidationSupported catalystsThe hydrotris(pyrazol-1-yl)methane iron(II) complex [FeCl2{h3-HC(pz)3}] (pz=pyrazol-1-yl) (1) was immobilized on three diferente carbon materials (activated carbon, carbon xerogel and multi-walled carbon nanotubes) with three different surface treatments (original, treated with nitric acid, and treated with nitric acid followed by sodium hydroxide) to produce active, selective and recyclable catalysts. The heterogenisation process was more efficient for carbon nanotubes treated with nitric acid and sodium hydroxide. An outstanding improved catalytic performance of complex 1 upon heterogenisation on carbon nanotubes treated with nitric acid and sodium hydroxide (turnover numbers up to 5.6_103 and overall yield of 21 %), relative to the homogeneous system, was achieved for the single-pot peroxidative oxidation of cyclohexane to the cyclohexanone and cyclohexanol mixture. The heterogenised systems allowed their easy recovery and reuse, at least for five consecutive cycles, maintaining 96% of the initial activity and concomitante rather high selectivity to cyclohexanol and cyclohexanone.Wiley-VCH VerlagRCIPLMartins, LuisaAlmeida, M. Peixoto deCarabineiro, S. A. C.Figueiredo, J. L.Pombeiro, Armando2018-07-02T14:22:28Z2013-122013-12-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.21/8648engMARTINS, Luísa Margarida D. R. S.; [et al] – Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide. C hemCatChem. ISSN:1867-3899. Vol. 5, N.º 12, pp. 3847-3856.1867-389910.1002/cctc.201300432metadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-08-03T09:56:20Zoai:repositorio.ipl.pt:10400.21/8648Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:17:22.623133Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide |
title |
Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide |
spellingShingle |
Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide Martins, Luisa Alkanes Carbon Iron Heterogenization Oxidation Supported catalysts |
title_short |
Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide |
title_full |
Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide |
title_fullStr |
Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide |
title_full_unstemmed |
Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide |
title_sort |
Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide |
author |
Martins, Luisa |
author_facet |
Martins, Luisa Almeida, M. Peixoto de Carabineiro, S. A. C. Figueiredo, J. L. Pombeiro, Armando |
author_role |
author |
author2 |
Almeida, M. Peixoto de Carabineiro, S. A. C. Figueiredo, J. L. Pombeiro, Armando |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
RCIPL |
dc.contributor.author.fl_str_mv |
Martins, Luisa Almeida, M. Peixoto de Carabineiro, S. A. C. Figueiredo, J. L. Pombeiro, Armando |
dc.subject.por.fl_str_mv |
Alkanes Carbon Iron Heterogenization Oxidation Supported catalysts |
topic |
Alkanes Carbon Iron Heterogenization Oxidation Supported catalysts |
description |
The hydrotris(pyrazol-1-yl)methane iron(II) complex [FeCl2{h3-HC(pz)3}] (pz=pyrazol-1-yl) (1) was immobilized on three diferente carbon materials (activated carbon, carbon xerogel and multi-walled carbon nanotubes) with three different surface treatments (original, treated with nitric acid, and treated with nitric acid followed by sodium hydroxide) to produce active, selective and recyclable catalysts. The heterogenisation process was more efficient for carbon nanotubes treated with nitric acid and sodium hydroxide. An outstanding improved catalytic performance of complex 1 upon heterogenisation on carbon nanotubes treated with nitric acid and sodium hydroxide (turnover numbers up to 5.6_103 and overall yield of 21 %), relative to the homogeneous system, was achieved for the single-pot peroxidative oxidation of cyclohexane to the cyclohexanone and cyclohexanol mixture. The heterogenised systems allowed their easy recovery and reuse, at least for five consecutive cycles, maintaining 96% of the initial activity and concomitante rather high selectivity to cyclohexanol and cyclohexanone. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-12 2013-12-01T00:00:00Z 2018-07-02T14:22:28Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.21/8648 |
url |
http://hdl.handle.net/10400.21/8648 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
MARTINS, Luísa Margarida D. R. S.; [et al] – Heterogenisation of a c-scorpionate feII complex on carbon materials for cyclohexane oxidation with hydrogen peroxide. C hemCatChem. ISSN:1867-3899. Vol. 5, N.º 12, pp. 3847-3856. 1867-3899 10.1002/cctc.201300432 |
dc.rights.driver.fl_str_mv |
metadata only access info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
metadata only access |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Wiley-VCH Verlag |
publisher.none.fl_str_mv |
Wiley-VCH Verlag |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
_version_ |
1799133435296481280 |