Analytical methodologies for arsenic speciation in macroalgae: a critical review

Detalhes bibliográficos
Autor(a) principal: Reis, Vanessa A.T.
Data de Publicação: 2018
Outros Autores: Duarte, Armando C.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10773/36770
Resumo: Marine and estuarine macroalgae are increasingly used for direct consumption, due to its high content of essential nutrients. However, the toxicity of chemical forms of arsenic (As) present in macroalgae are becoming of great concern and an important research topic. This review will discuss the sophisticated analytical methodologies used for arsenic speciation, as well the investigation of cheaper and fit for purpose methods able to inform about the safety of macroalgae consumption. Furthermore, we will also discuss relevant speciation studies performed by various authors highlighting the methodologies and respective figures of merit for all components of As in macroalgae, not only inorganic As (iAs). Focusing on the steps prior to speciation, such as sample extraction and clean-up, it will be stressed the need to develop certified reference materials (CRMs) in order to assist in the validation of analytical methodologies for As speciation in macroalgae.
id RCAP_548ef663133f316846a545e6601273bc
oai_identifier_str oai:ria.ua.pt:10773/36770
network_acronym_str RCAP
network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str 7160
spelling Analytical methodologies for arsenic speciation in macroalgae: a critical reviewArsenicArsenateArseniteMacroalgaeSpeciationToxicityMarine and estuarine macroalgae are increasingly used for direct consumption, due to its high content of essential nutrients. However, the toxicity of chemical forms of arsenic (As) present in macroalgae are becoming of great concern and an important research topic. This review will discuss the sophisticated analytical methodologies used for arsenic speciation, as well the investigation of cheaper and fit for purpose methods able to inform about the safety of macroalgae consumption. Furthermore, we will also discuss relevant speciation studies performed by various authors highlighting the methodologies and respective figures of merit for all components of As in macroalgae, not only inorganic As (iAs). Focusing on the steps prior to speciation, such as sample extraction and clean-up, it will be stressed the need to develop certified reference materials (CRMs) in order to assist in the validation of analytical methodologies for As speciation in macroalgae.Elsevier2023-03-31T11:45:23Z2018-05-01T00:00:00Z2018-05info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/36770eng0165-993610.1016/j.trac.2018.02.003Reis, Vanessa A.T.Duarte, Armando C.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T12:10:52Zoai:ria.ua.pt:10773/36770Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:07:28.391466Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Analytical methodologies for arsenic speciation in macroalgae: a critical review
title Analytical methodologies for arsenic speciation in macroalgae: a critical review
spellingShingle Analytical methodologies for arsenic speciation in macroalgae: a critical review
Reis, Vanessa A.T.
Arsenic
Arsenate
Arsenite
Macroalgae
Speciation
Toxicity
title_short Analytical methodologies for arsenic speciation in macroalgae: a critical review
title_full Analytical methodologies for arsenic speciation in macroalgae: a critical review
title_fullStr Analytical methodologies for arsenic speciation in macroalgae: a critical review
title_full_unstemmed Analytical methodologies for arsenic speciation in macroalgae: a critical review
title_sort Analytical methodologies for arsenic speciation in macroalgae: a critical review
author Reis, Vanessa A.T.
author_facet Reis, Vanessa A.T.
Duarte, Armando C.
author_role author
author2 Duarte, Armando C.
author2_role author
dc.contributor.author.fl_str_mv Reis, Vanessa A.T.
Duarte, Armando C.
dc.subject.por.fl_str_mv Arsenic
Arsenate
Arsenite
Macroalgae
Speciation
Toxicity
topic Arsenic
Arsenate
Arsenite
Macroalgae
Speciation
Toxicity
description Marine and estuarine macroalgae are increasingly used for direct consumption, due to its high content of essential nutrients. However, the toxicity of chemical forms of arsenic (As) present in macroalgae are becoming of great concern and an important research topic. This review will discuss the sophisticated analytical methodologies used for arsenic speciation, as well the investigation of cheaper and fit for purpose methods able to inform about the safety of macroalgae consumption. Furthermore, we will also discuss relevant speciation studies performed by various authors highlighting the methodologies and respective figures of merit for all components of As in macroalgae, not only inorganic As (iAs). Focusing on the steps prior to speciation, such as sample extraction and clean-up, it will be stressed the need to develop certified reference materials (CRMs) in order to assist in the validation of analytical methodologies for As speciation in macroalgae.
publishDate 2018
dc.date.none.fl_str_mv 2018-05-01T00:00:00Z
2018-05
2023-03-31T11:45:23Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10773/36770
url http://hdl.handle.net/10773/36770
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0165-9936
10.1016/j.trac.2018.02.003
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
_version_ 1799137729846444032