Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode

Detalhes bibliográficos
Autor(a) principal: Lovric,Milivoj
Data de Publicação: 2020
Outros Autores: Komorsky-Lovric,Šebojka
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042020000300003
Resumo: An irreversible electrode reaction influenced by the reversible potential dependent inhibition is theoretically analysed. The consequence of reactivation of the electrode surface is the continuation of electro-oxidation and the appearance of the second anodic peak in cyclic voltammetry. An indicator of the change of the electrode kinetics caused by the inhibitor is proposed.
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spelling Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrodeelectrode reactivationinhibitionpartially blocked electrodesimulationAn irreversible electrode reaction influenced by the reversible potential dependent inhibition is theoretically analysed. The consequence of reactivation of the electrode surface is the continuation of electro-oxidation and the appearance of the second anodic peak in cyclic voltammetry. An indicator of the change of the electrode kinetics caused by the inhibitor is proposed.Sociedade Portuguesa de Electroquímica2020-06-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042020000300003Portugaliae Electrochimica Acta v.38 n.3 2020reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042020000300003Lovric,MilivojKomorsky-Lovric,Šebojkainfo:eu-repo/semantics/openAccess2024-02-06T17:07:32Zoai:scielo:S0872-19042020000300003Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:26.004815Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode
title Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode
spellingShingle Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode
Lovric,Milivoj
electrode reactivation
inhibition
partially blocked electrode
simulation
title_short Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode
title_full Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode
title_fullStr Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode
title_full_unstemmed Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode
title_sort Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode
author Lovric,Milivoj
author_facet Lovric,Milivoj
Komorsky-Lovric,Šebojka
author_role author
author2 Komorsky-Lovric,Šebojka
author2_role author
dc.contributor.author.fl_str_mv Lovric,Milivoj
Komorsky-Lovric,Šebojka
dc.subject.por.fl_str_mv electrode reactivation
inhibition
partially blocked electrode
simulation
topic electrode reactivation
inhibition
partially blocked electrode
simulation
description An irreversible electrode reaction influenced by the reversible potential dependent inhibition is theoretically analysed. The consequence of reactivation of the electrode surface is the continuation of electro-oxidation and the appearance of the second anodic peak in cyclic voltammetry. An indicator of the change of the electrode kinetics caused by the inhibitor is proposed.
publishDate 2020
dc.date.none.fl_str_mv 2020-06-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042020000300003
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042020000300003
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042020000300003
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
dc.source.none.fl_str_mv Portugaliae Electrochimica Acta v.38 n.3 2020
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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