F---H···F hydrogen bond in diphenylguanidinium hydrogen bifluoride

Detalhes bibliográficos
Autor(a) principal: Silva, Manuela Ramos
Data de Publicação: 2001
Outros Autores: Paixão, José A., Beja, Ana Matos, Veiga, Luiz Alte da
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/5229
https://doi.org/10.1016/S0022-1139(00)00351-1
Resumo: The crystal structure of C13H14N3+FHF- is reported. The structure contains the strong hydrogen-bonded system, the bifluoride anion F---H···F-. The geometry of this anion deviates significantly from linearity but has the H atom in an approximate centered position. The F···F distance is 2.293(3) Å, considerably less than twice the van der Waals radius of fluorine, as expected from a very strong hydrogen bond.
id RCAP_57d3d8617a073346525b22cd0830f2cb
oai_identifier_str oai:estudogeral.uc.pt:10316/5229
network_acronym_str RCAP
network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str 7160
spelling F---H···F hydrogen bond in diphenylguanidinium hydrogen bifluorideDiphenylguanidinium fluoride hydrogen fluorideDiphenylguanidinium bifluorideHydrogen bondX-ray structure determinationThe crystal structure of C13H14N3+FHF- is reported. The structure contains the strong hydrogen-bonded system, the bifluoride anion F---H···F-. The geometry of this anion deviates significantly from linearity but has the H atom in an approximate centered position. The F···F distance is 2.293(3) Å, considerably less than twice the van der Waals radius of fluorine, as expected from a very strong hydrogen bond.http://www.sciencedirect.com/science/article/B6TGD-423HKRV-N/1/b518b985ecb521192bfdbc57a27df65d2001info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttp://hdl.handle.net/10316/5229http://hdl.handle.net/10316/5229https://doi.org/10.1016/S0022-1139(00)00351-1engJournal of Fluorine Chemistry. 107:1 (2001) 117-120Silva, Manuela RamosPaixão, José A.Beja, Ana MatosVeiga, Luiz Alte dainfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2021-07-20T09:59:37Zoai:estudogeral.uc.pt:10316/5229Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:01:22.407170Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv F---H···F hydrogen bond in diphenylguanidinium hydrogen bifluoride
title F---H···F hydrogen bond in diphenylguanidinium hydrogen bifluoride
spellingShingle F---H···F hydrogen bond in diphenylguanidinium hydrogen bifluoride
Silva, Manuela Ramos
Diphenylguanidinium fluoride hydrogen fluoride
Diphenylguanidinium bifluoride
Hydrogen bond
X-ray structure determination
title_short F---H···F hydrogen bond in diphenylguanidinium hydrogen bifluoride
title_full F---H···F hydrogen bond in diphenylguanidinium hydrogen bifluoride
title_fullStr F---H···F hydrogen bond in diphenylguanidinium hydrogen bifluoride
title_full_unstemmed F---H···F hydrogen bond in diphenylguanidinium hydrogen bifluoride
title_sort F---H···F hydrogen bond in diphenylguanidinium hydrogen bifluoride
author Silva, Manuela Ramos
author_facet Silva, Manuela Ramos
Paixão, José A.
Beja, Ana Matos
Veiga, Luiz Alte da
author_role author
author2 Paixão, José A.
Beja, Ana Matos
Veiga, Luiz Alte da
author2_role author
author
author
dc.contributor.author.fl_str_mv Silva, Manuela Ramos
Paixão, José A.
Beja, Ana Matos
Veiga, Luiz Alte da
dc.subject.por.fl_str_mv Diphenylguanidinium fluoride hydrogen fluoride
Diphenylguanidinium bifluoride
Hydrogen bond
X-ray structure determination
topic Diphenylguanidinium fluoride hydrogen fluoride
Diphenylguanidinium bifluoride
Hydrogen bond
X-ray structure determination
description The crystal structure of C13H14N3+FHF- is reported. The structure contains the strong hydrogen-bonded system, the bifluoride anion F---H···F-. The geometry of this anion deviates significantly from linearity but has the H atom in an approximate centered position. The F···F distance is 2.293(3) Å, considerably less than twice the van der Waals radius of fluorine, as expected from a very strong hydrogen bond.
publishDate 2001
dc.date.none.fl_str_mv 2001
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/5229
http://hdl.handle.net/10316/5229
https://doi.org/10.1016/S0022-1139(00)00351-1
url http://hdl.handle.net/10316/5229
https://doi.org/10.1016/S0022-1139(00)00351-1
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal of Fluorine Chemistry. 107:1 (2001) 117-120
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv aplication/PDF
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
_version_ 1799133905318576128

Registros relacionados