Three robust Zn(Ⅱ)-coordination polymers as dual-responsive chemosensors for efficient sensing of enrofloxacin and acetylacetone

Detalhes bibliográficos
Autor(a) principal: Wang, Xiang-Wen
Data de Publicação: 2023
Outros Autores: Fu, Lianshe, Cui, Guang-Hua
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10773/37939
Resumo: Designing efficient and stable non-precious coordination polymers remains a challenge for the luminescent sensing of enrofloxacin and acetylacetone. Three Zn(Ⅱ)-coordination polymers with the formula {[Zn2(L)(BTC)(OH)]·H2O}n (1), [Zn1.5(L)(MIP)(OH)]n (2) and [Zn(L)(DBT)]n (3); L = 2-(2-Pyridin-3-yl-vinyl)-1H-benzimidazole, H3BTC = 1,3,5-benzene tricarboxylic acid, H2MIP = 5-methylisophthalic acid, and H2DBT = 2,5-dibromoterephthalic acid were hydrothermally synthesized and characterized. 1 reveals an unusual 3D topology, 2 displays a 3D mog framework, while 3 exhibits (4,5)-connected 3D xah framework. 1∼3 are firstly dual-functional luminescence sensors for detecting enrofloxacin and acetylacetone, expressing high selectivity and sensitivity. Quick and visual detection of enrofloxacin and acetylacetone without any pretreatment is realized by using CP 1∼3 paper-based sensors. Furthermore, the fluorescence sensing mechanism was discussed in detail.
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spelling Three robust Zn(Ⅱ)-coordination polymers as dual-responsive chemosensors for efficient sensing of enrofloxacin and acetylacetoneAcetylacetoneEnrofloxacinStabilityVisual fluorescenceZn(Ⅱ)-coordination polymersDesigning efficient and stable non-precious coordination polymers remains a challenge for the luminescent sensing of enrofloxacin and acetylacetone. Three Zn(Ⅱ)-coordination polymers with the formula {[Zn2(L)(BTC)(OH)]·H2O}n (1), [Zn1.5(L)(MIP)(OH)]n (2) and [Zn(L)(DBT)]n (3); L = 2-(2-Pyridin-3-yl-vinyl)-1H-benzimidazole, H3BTC = 1,3,5-benzene tricarboxylic acid, H2MIP = 5-methylisophthalic acid, and H2DBT = 2,5-dibromoterephthalic acid were hydrothermally synthesized and characterized. 1 reveals an unusual 3D topology, 2 displays a 3D mog framework, while 3 exhibits (4,5)-connected 3D xah framework. 1∼3 are firstly dual-functional luminescence sensors for detecting enrofloxacin and acetylacetone, expressing high selectivity and sensitivity. Quick and visual detection of enrofloxacin and acetylacetone without any pretreatment is realized by using CP 1∼3 paper-based sensors. Furthermore, the fluorescence sensing mechanism was discussed in detail.Elsevier2025-10-05T00:00:00Z2023-10-05T00:00:00Z2023-10-05info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/37939eng0022-286010.1016/j.molstruc.2023.135881Wang, Xiang-WenFu, LiansheCui, Guang-Huainfo:eu-repo/semantics/embargoedAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T12:14:06Zoai:ria.ua.pt:10773/37939Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:08:31.694228Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Three robust Zn(Ⅱ)-coordination polymers as dual-responsive chemosensors for efficient sensing of enrofloxacin and acetylacetone
title Three robust Zn(Ⅱ)-coordination polymers as dual-responsive chemosensors for efficient sensing of enrofloxacin and acetylacetone
spellingShingle Three robust Zn(Ⅱ)-coordination polymers as dual-responsive chemosensors for efficient sensing of enrofloxacin and acetylacetone
Wang, Xiang-Wen
Acetylacetone
Enrofloxacin
Stability
Visual fluorescence
Zn(Ⅱ)-coordination polymers
title_short Three robust Zn(Ⅱ)-coordination polymers as dual-responsive chemosensors for efficient sensing of enrofloxacin and acetylacetone
title_full Three robust Zn(Ⅱ)-coordination polymers as dual-responsive chemosensors for efficient sensing of enrofloxacin and acetylacetone
title_fullStr Three robust Zn(Ⅱ)-coordination polymers as dual-responsive chemosensors for efficient sensing of enrofloxacin and acetylacetone
title_full_unstemmed Three robust Zn(Ⅱ)-coordination polymers as dual-responsive chemosensors for efficient sensing of enrofloxacin and acetylacetone
title_sort Three robust Zn(Ⅱ)-coordination polymers as dual-responsive chemosensors for efficient sensing of enrofloxacin and acetylacetone
author Wang, Xiang-Wen
author_facet Wang, Xiang-Wen
Fu, Lianshe
Cui, Guang-Hua
author_role author
author2 Fu, Lianshe
Cui, Guang-Hua
author2_role author
author
dc.contributor.author.fl_str_mv Wang, Xiang-Wen
Fu, Lianshe
Cui, Guang-Hua
dc.subject.por.fl_str_mv Acetylacetone
Enrofloxacin
Stability
Visual fluorescence
Zn(Ⅱ)-coordination polymers
topic Acetylacetone
Enrofloxacin
Stability
Visual fluorescence
Zn(Ⅱ)-coordination polymers
description Designing efficient and stable non-precious coordination polymers remains a challenge for the luminescent sensing of enrofloxacin and acetylacetone. Three Zn(Ⅱ)-coordination polymers with the formula {[Zn2(L)(BTC)(OH)]·H2O}n (1), [Zn1.5(L)(MIP)(OH)]n (2) and [Zn(L)(DBT)]n (3); L = 2-(2-Pyridin-3-yl-vinyl)-1H-benzimidazole, H3BTC = 1,3,5-benzene tricarboxylic acid, H2MIP = 5-methylisophthalic acid, and H2DBT = 2,5-dibromoterephthalic acid were hydrothermally synthesized and characterized. 1 reveals an unusual 3D topology, 2 displays a 3D mog framework, while 3 exhibits (4,5)-connected 3D xah framework. 1∼3 are firstly dual-functional luminescence sensors for detecting enrofloxacin and acetylacetone, expressing high selectivity and sensitivity. Quick and visual detection of enrofloxacin and acetylacetone without any pretreatment is realized by using CP 1∼3 paper-based sensors. Furthermore, the fluorescence sensing mechanism was discussed in detail.
publishDate 2023
dc.date.none.fl_str_mv 2023-10-05T00:00:00Z
2023-10-05
2025-10-05T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10773/37939
url http://hdl.handle.net/10773/37939
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0022-2860
10.1016/j.molstruc.2023.135881
dc.rights.driver.fl_str_mv info:eu-repo/semantics/embargoedAccess
eu_rights_str_mv embargoedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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