Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxides

Detalhes bibliográficos
Autor(a) principal: Paul, Anup
Data de Publicação: 2023
Outros Autores: Garazade, Ismayil M., Karmakar, Anirban, Khan, Rais Ahmad, Guedes da Silva, Maria Fátima C., Nunes, Ana V. M., Pombeiro, Armando J. L.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/165592
Resumo: This research was funded by the FCT and IST, Portugal, for financial support through “DL/57/2017” (contract no. IST-ID/197/2019). I.M.G. is grateful to the State Program for Increasing the International Competitiveness of the higher education system of the Republic of Azerbaijan in 2019–2023, Ministry of Science and Education Republic of Azerbaijan. R.A.K. gratefully acknowledged Researchers Supporting Project (Project number, RSP2023R400), King Saud University, Riyadh, KSA. Publisher Copyright: © 2023 by the authors.
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spelling Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxidesamide functionalisedCOepoxidesMOFtetrazoleCatalysisEnvironmental Science(all)Physical and Theoretical ChemistrySDG 13 - Climate ActionThis research was funded by the FCT and IST, Portugal, for financial support through “DL/57/2017” (contract no. IST-ID/197/2019). I.M.G. is grateful to the State Program for Increasing the International Competitiveness of the higher education system of the Republic of Azerbaijan in 2019–2023, Ministry of Science and Education Republic of Azerbaijan. R.A.K. gratefully acknowledged Researchers Supporting Project (Project number, RSP2023R400), King Saud University, Riyadh, KSA. Publisher Copyright: © 2023 by the authors.In this study, we report the design, synthesis, and catalytic application of the novel nitrogen-rich Zn(II) MOF [Zn2(μ3-1κN,2κN′,3κO-HL)2(DMF)2]n·nH2O (HL2− = 4-((4-(1H-tetrazol-5-yl)phenyl)carbamoyl)benzoate), denoted as ZnMOF, for the efficient conversion of carbon dioxide (CO2) to cyclic carbonates via cycloaddition with epoxides. It was synthesised from a tetrazole appended amide-functionalised pro-ligand (H3L) and Zn(NO3)2·6H2O under hydrothermal conditions. The synthesised material was characterised namely by elemental analysis, infrared spectroscopy, powder X-ray diffraction (PXRD), and single-crystal X-ray diffraction analyses. The catalytic potential of ZnMOF was investigated in the CO2 cycloaddition reaction with various epoxides, with conversions ranging from 17% to 99%. The catalyst retained its activity across multiple reaction cycles, demonstrating its stability and reusability. The influence of co-catalysts on the reaction was explored, with tetrabutylammonium bromide (TBABr) emerging as the most effective one. A plausible reaction mechanism is proposed.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNPaul, AnupGarazade, Ismayil M.Karmakar, AnirbanKhan, Rais AhmadGuedes da Silva, Maria Fátima C.Nunes, Ana V. M.Pombeiro, Armando J. L.2024-03-28T23:58:28Z2023-12-202023-12-20T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article14application/pdfhttp://hdl.handle.net/10362/165592eng2073-4344PURE: 86714062https://doi.org/10.3390/catal14010006info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-07-08T01:33:33Zoai:run.unl.pt:10362/165592Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-07-08T01:33:33Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxides
title Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxides
spellingShingle Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxides
Paul, Anup
amide functionalised
CO
epoxides
MOF
tetrazole
Catalysis
Environmental Science(all)
Physical and Theoretical Chemistry
SDG 13 - Climate Action
title_short Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxides
title_full Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxides
title_fullStr Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxides
title_full_unstemmed Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxides
title_sort Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxides
author Paul, Anup
author_facet Paul, Anup
Garazade, Ismayil M.
Karmakar, Anirban
Khan, Rais Ahmad
Guedes da Silva, Maria Fátima C.
Nunes, Ana V. M.
Pombeiro, Armando J. L.
author_role author
author2 Garazade, Ismayil M.
Karmakar, Anirban
Khan, Rais Ahmad
Guedes da Silva, Maria Fátima C.
Nunes, Ana V. M.
Pombeiro, Armando J. L.
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Paul, Anup
Garazade, Ismayil M.
Karmakar, Anirban
Khan, Rais Ahmad
Guedes da Silva, Maria Fátima C.
Nunes, Ana V. M.
Pombeiro, Armando J. L.
dc.subject.por.fl_str_mv amide functionalised
CO
epoxides
MOF
tetrazole
Catalysis
Environmental Science(all)
Physical and Theoretical Chemistry
SDG 13 - Climate Action
topic amide functionalised
CO
epoxides
MOF
tetrazole
Catalysis
Environmental Science(all)
Physical and Theoretical Chemistry
SDG 13 - Climate Action
description This research was funded by the FCT and IST, Portugal, for financial support through “DL/57/2017” (contract no. IST-ID/197/2019). I.M.G. is grateful to the State Program for Increasing the International Competitiveness of the higher education system of the Republic of Azerbaijan in 2019–2023, Ministry of Science and Education Republic of Azerbaijan. R.A.K. gratefully acknowledged Researchers Supporting Project (Project number, RSP2023R400), King Saud University, Riyadh, KSA. Publisher Copyright: © 2023 by the authors.
publishDate 2023
dc.date.none.fl_str_mv 2023-12-20
2023-12-20T00:00:00Z
2024-03-28T23:58:28Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/165592
url http://hdl.handle.net/10362/165592
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2073-4344
PURE: 86714062
https://doi.org/10.3390/catal14010006
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 14
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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