Studies on Polybenzimidazole and Methanesulfonate Protic-Ionic-Liquids-Based Composite Polymer Electrolyte Membranes

Detalhes bibliográficos
Autor(a) principal: Anis, Arfat
Data de Publicação: 2023
Outros Autores: Alam, Manawwer, Alhamidi, Abdullah, Gupta, Ravindra Kumar, Tariq, Mohammad, Al-Zahrani, Saeed M.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/158485
Resumo: Funding Information: This project was funded by the National Plan for Science, Technology and Innovation (MAARIFAH), King Abdulaziz City for Science and Technology, Kingdom of Saudi Arabia, Award Number (2-17-01-001-0042). Publisher Copyright: © 2023 by the authors.
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spelling Studies on Polybenzimidazole and Methanesulfonate Protic-Ionic-Liquids-Based Composite Polymer Electrolyte MembranesFTIR spectroscopyionic conductivityNMR analysispolymer electrolyte membraneprotic ionic liquids polybenzimidazolethermal analysisChemistry(all)Polymers and PlasticsSDG 7 - Affordable and Clean EnergyFunding Information: This project was funded by the National Plan for Science, Technology and Innovation (MAARIFAH), King Abdulaziz City for Science and Technology, Kingdom of Saudi Arabia, Award Number (2-17-01-001-0042). Publisher Copyright: © 2023 by the authors.In the present work, different methanesulfonate-based protic ionic liquids (PILs) were synthesized and their structural characterization was performed using FTIR, 1H, and 13C NMR spectroscopy. Their thermal behavior and stability were studied using DSC and TGA, respectively, and EIS was used to study the ionic conductivity of these PILs. The PIL, which was diethanolammonium-methanesulfonate-based due to its compatibility with polybenzimidazole (PBI) to form composite membranes, was used to prepare proton-conducting polymer electrolyte membranes (PEMs) for prospective high-temperature fuel cell application. The prepared PEMs were further characterized using FTIR, DSC, TGA, SEM, and EIS. The FTIR results indicated good interaction among the PEM components and the DSC results suggested good miscibility and a plasticizing effect of the incorporated PIL in the PBI polymer matrix. All the PEMs showed good thermal stability and good proton conductivity for prospective high-temperature fuel cell application.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNAnis, ArfatAlam, ManawwerAlhamidi, AbdullahGupta, Ravindra KumarTariq, MohammadAl-Zahrani, Saeed M.2023-09-29T22:22:20Z2023-06-262023-06-26T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article16application/pdfhttp://hdl.handle.net/10362/158485eng2073-4360PURE: 72782742https://doi.org/10.3390/polym15132821info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:40:54Zoai:run.unl.pt:10362/158485Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:57:10.048851Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Studies on Polybenzimidazole and Methanesulfonate Protic-Ionic-Liquids-Based Composite Polymer Electrolyte Membranes
title Studies on Polybenzimidazole and Methanesulfonate Protic-Ionic-Liquids-Based Composite Polymer Electrolyte Membranes
spellingShingle Studies on Polybenzimidazole and Methanesulfonate Protic-Ionic-Liquids-Based Composite Polymer Electrolyte Membranes
Anis, Arfat
FTIR spectroscopy
ionic conductivity
NMR analysis
polymer electrolyte membrane
protic ionic liquids polybenzimidazole
thermal analysis
Chemistry(all)
Polymers and Plastics
SDG 7 - Affordable and Clean Energy
title_short Studies on Polybenzimidazole and Methanesulfonate Protic-Ionic-Liquids-Based Composite Polymer Electrolyte Membranes
title_full Studies on Polybenzimidazole and Methanesulfonate Protic-Ionic-Liquids-Based Composite Polymer Electrolyte Membranes
title_fullStr Studies on Polybenzimidazole and Methanesulfonate Protic-Ionic-Liquids-Based Composite Polymer Electrolyte Membranes
title_full_unstemmed Studies on Polybenzimidazole and Methanesulfonate Protic-Ionic-Liquids-Based Composite Polymer Electrolyte Membranes
title_sort Studies on Polybenzimidazole and Methanesulfonate Protic-Ionic-Liquids-Based Composite Polymer Electrolyte Membranes
author Anis, Arfat
author_facet Anis, Arfat
Alam, Manawwer
Alhamidi, Abdullah
Gupta, Ravindra Kumar
Tariq, Mohammad
Al-Zahrani, Saeed M.
author_role author
author2 Alam, Manawwer
Alhamidi, Abdullah
Gupta, Ravindra Kumar
Tariq, Mohammad
Al-Zahrani, Saeed M.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Anis, Arfat
Alam, Manawwer
Alhamidi, Abdullah
Gupta, Ravindra Kumar
Tariq, Mohammad
Al-Zahrani, Saeed M.
dc.subject.por.fl_str_mv FTIR spectroscopy
ionic conductivity
NMR analysis
polymer electrolyte membrane
protic ionic liquids polybenzimidazole
thermal analysis
Chemistry(all)
Polymers and Plastics
SDG 7 - Affordable and Clean Energy
topic FTIR spectroscopy
ionic conductivity
NMR analysis
polymer electrolyte membrane
protic ionic liquids polybenzimidazole
thermal analysis
Chemistry(all)
Polymers and Plastics
SDG 7 - Affordable and Clean Energy
description Funding Information: This project was funded by the National Plan for Science, Technology and Innovation (MAARIFAH), King Abdulaziz City for Science and Technology, Kingdom of Saudi Arabia, Award Number (2-17-01-001-0042). Publisher Copyright: © 2023 by the authors.
publishDate 2023
dc.date.none.fl_str_mv 2023-09-29T22:22:20Z
2023-06-26
2023-06-26T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/158485
url http://hdl.handle.net/10362/158485
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2073-4360
PURE: 72782742
https://doi.org/10.3390/polym15132821
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 16
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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