Regioselective enzymatic acylation of vicinal diols of steroids
Autor(a) principal: | |
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Data de Publicação: | 2005 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10316/5756 https://doi.org/10.1016/j.tet.2005.01.104 |
Resumo: | Monoacylated derivatives of a complete set of 2,3- and 3,4-vicinal diols of steroids were prepared by regioselective lipase-catalysed transesterification reactions. The enzymes displayed different selectivities towards the vicinal diols depending on the configuration of the hydroxyl groups. |
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Regioselective enzymatic acylation of vicinal diols of steroidsLipasesSteroidsRegioselectivityEnzymatic esterificationMonoacylated derivatives of a complete set of 2,3- and 3,4-vicinal diols of steroids were prepared by regioselective lipase-catalysed transesterification reactions. The enzymes displayed different selectivities towards the vicinal diols depending on the configuration of the hydroxyl groups.http://www.sciencedirect.com/science/article/B6THR-4FGX84H-2/1/c23744db4c590d02acf7c82018be57202005info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttp://hdl.handle.net/10316/5756http://hdl.handle.net/10316/5756https://doi.org/10.1016/j.tet.2005.01.104engTetrahedron. 61:12 (2005) 3065-3073Silva, M. Manuel CruzRiva, SergioMelo, M. Luísa Sá einfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2021-10-28T09:18:58Zoai:estudogeral.uc.pt:10316/5756Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:47:23.912915Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Regioselective enzymatic acylation of vicinal diols of steroids |
title |
Regioselective enzymatic acylation of vicinal diols of steroids |
spellingShingle |
Regioselective enzymatic acylation of vicinal diols of steroids Silva, M. Manuel Cruz Lipases Steroids Regioselectivity Enzymatic esterification |
title_short |
Regioselective enzymatic acylation of vicinal diols of steroids |
title_full |
Regioselective enzymatic acylation of vicinal diols of steroids |
title_fullStr |
Regioselective enzymatic acylation of vicinal diols of steroids |
title_full_unstemmed |
Regioselective enzymatic acylation of vicinal diols of steroids |
title_sort |
Regioselective enzymatic acylation of vicinal diols of steroids |
author |
Silva, M. Manuel Cruz |
author_facet |
Silva, M. Manuel Cruz Riva, Sergio Melo, M. Luísa Sá e |
author_role |
author |
author2 |
Riva, Sergio Melo, M. Luísa Sá e |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Silva, M. Manuel Cruz Riva, Sergio Melo, M. Luísa Sá e |
dc.subject.por.fl_str_mv |
Lipases Steroids Regioselectivity Enzymatic esterification |
topic |
Lipases Steroids Regioselectivity Enzymatic esterification |
description |
Monoacylated derivatives of a complete set of 2,3- and 3,4-vicinal diols of steroids were prepared by regioselective lipase-catalysed transesterification reactions. The enzymes displayed different selectivities towards the vicinal diols depending on the configuration of the hydroxyl groups. |
publishDate |
2005 |
dc.date.none.fl_str_mv |
2005 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10316/5756 http://hdl.handle.net/10316/5756 https://doi.org/10.1016/j.tet.2005.01.104 |
url |
http://hdl.handle.net/10316/5756 https://doi.org/10.1016/j.tet.2005.01.104 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Tetrahedron. 61:12 (2005) 3065-3073 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
aplication/PDF |
dc.source.none.fl_str_mv |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799133751152738304 |