Oxidation of 5-hydroxymethylfurfural on supported ag, au, pd and bimetallic pd-au catalysts

Detalhes bibliográficos
Autor(a) principal: German, Dmitrii
Data de Publicação: 2021
Outros Autores: Pakrieva, Ekaterina, Kolobova, Ekaterina, Carabineiro, Sónia A. C., Stucchi, Marta, Villa, Alberto, Prati, Laura, Bogdanchikova, Nina, Corberán, Vicente Cortés, Pestryakov, Alexey
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/111969
Resumo: Fundacao para a Ciencia e Tecnologia (FCT), Portugal, through project UIDB/00100/2020 of the Centro de Quimica Estrutural; Associate Laboratory for Green Chemistry-LAQV,financed by national funds from FCT/MCTES (UIDB/50006/2020); FCT Scientific Employment Stimulus-Institutional Call (CEECINST/00102/2018) and PTDC/QEQ-QIN/3967/2014; Tomsk Polytechnic University Competitiveness Enhancement Program project VIU-RSCBMT-197/2020; Russian Foundation of Basic Research, project 18-29-24037; Tomsk Polytechnic University State Task `Science' (project FSWW-2020-0011) andMICINN project CTQ2017-86170-R (Spain).
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spelling Oxidation of 5-hydroxymethylfurfural on supported ag, au, pd and bimetallic pd-au catalystsEffect of the support2,5-furandicarboxylic acid5-hydroxymethylfurfuralBimetallic catalystsGoldMetal oxidesNanoparticlesPalladiumSelective oxidationSibunit carbonSilverSupport modificationCatalysisPhysical and Theoretical ChemistryFundacao para a Ciencia e Tecnologia (FCT), Portugal, through project UIDB/00100/2020 of the Centro de Quimica Estrutural; Associate Laboratory for Green Chemistry-LAQV,financed by national funds from FCT/MCTES (UIDB/50006/2020); FCT Scientific Employment Stimulus-Institutional Call (CEECINST/00102/2018) and PTDC/QEQ-QIN/3967/2014; Tomsk Polytechnic University Competitiveness Enhancement Program project VIU-RSCBMT-197/2020; Russian Foundation of Basic Research, project 18-29-24037; Tomsk Polytechnic University State Task `Science' (project FSWW-2020-0011) andMICINN project CTQ2017-86170-R (Spain).Oxidation of 5-hydroxymethylfurfural (HMF), a major feedstock derived from waste/fresh biomass, into 2,5-furandicarboxylic acid (FDCA) is an important transformation for the production of biodegradable plastics. Herein, we investigated the effect of the support (unmodified and modified titania, commercial alumina, and untreated and treated Sibunit carbon) of mono-and bimetallic catalysts based on noble metals (Ag, Au, Pd) on selective HMF oxidation with molecular oxygen to FDCA under mild and basic reaction conditions. The higher selectivity to FDCA was obtained when metals were supported on Sibunit carbon (Cp). The order of noble metal in terms of catalyst selectivity was: Ag < Au < Pd < PdAu. Finally, FDCA production on the most efficient PdAu NPs catalysts supported on Sibunit depended on the treatment applied to this carbon support in the order: PdAu/Cp < PdAu/Cp-HNO3 < PdAu/Cp-NH4OH. These bimetallic catalysts were characterized by nitrogen adsorption-desorption, inductively coupled plasma atomic emission spectroscopy, high resolution transmission electron microscopy, energy dispersive spectroscopy, X-ray diffraction, Hammet indicator method and X-ray photoelectron spectroscopy. The functionalization of Sibunit surface by HNO3 and NH4OH led to a change in the contribution of the active states of Pd and Au due to promotion effect of N-doping and, as a consequence, to higher FDCA production. HMF oxidation catalyzed by bimetallic catalysts is a structure sensitive reaction.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNGerman, DmitriiPakrieva, EkaterinaKolobova, EkaterinaCarabineiro, Sónia A. C.Stucchi, MartaVilla, AlbertoPrati, LauraBogdanchikova, NinaCorberán, Vicente CortésPestryakov, Alexey2021-02-16T23:30:25Z2021-01-142021-01-14T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article20application/pdfhttp://hdl.handle.net/10362/111969eng2073-4344PURE: 27963232https://doi.org/10.3390/catal11010115info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T04:55:44Zoai:run.unl.pt:10362/111969Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:42:02.471581Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Oxidation of 5-hydroxymethylfurfural on supported ag, au, pd and bimetallic pd-au catalysts
Effect of the support
title Oxidation of 5-hydroxymethylfurfural on supported ag, au, pd and bimetallic pd-au catalysts
spellingShingle Oxidation of 5-hydroxymethylfurfural on supported ag, au, pd and bimetallic pd-au catalysts
German, Dmitrii
2,5-furandicarboxylic acid
5-hydroxymethylfurfural
Bimetallic catalysts
Gold
Metal oxides
Nanoparticles
Palladium
Selective oxidation
Sibunit carbon
Silver
Support modification
Catalysis
Physical and Theoretical Chemistry
title_short Oxidation of 5-hydroxymethylfurfural on supported ag, au, pd and bimetallic pd-au catalysts
title_full Oxidation of 5-hydroxymethylfurfural on supported ag, au, pd and bimetallic pd-au catalysts
title_fullStr Oxidation of 5-hydroxymethylfurfural on supported ag, au, pd and bimetallic pd-au catalysts
title_full_unstemmed Oxidation of 5-hydroxymethylfurfural on supported ag, au, pd and bimetallic pd-au catalysts
title_sort Oxidation of 5-hydroxymethylfurfural on supported ag, au, pd and bimetallic pd-au catalysts
author German, Dmitrii
author_facet German, Dmitrii
Pakrieva, Ekaterina
Kolobova, Ekaterina
Carabineiro, Sónia A. C.
Stucchi, Marta
Villa, Alberto
Prati, Laura
Bogdanchikova, Nina
Corberán, Vicente Cortés
Pestryakov, Alexey
author_role author
author2 Pakrieva, Ekaterina
Kolobova, Ekaterina
Carabineiro, Sónia A. C.
Stucchi, Marta
Villa, Alberto
Prati, Laura
Bogdanchikova, Nina
Corberán, Vicente Cortés
Pestryakov, Alexey
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv German, Dmitrii
Pakrieva, Ekaterina
Kolobova, Ekaterina
Carabineiro, Sónia A. C.
Stucchi, Marta
Villa, Alberto
Prati, Laura
Bogdanchikova, Nina
Corberán, Vicente Cortés
Pestryakov, Alexey
dc.subject.por.fl_str_mv 2,5-furandicarboxylic acid
5-hydroxymethylfurfural
Bimetallic catalysts
Gold
Metal oxides
Nanoparticles
Palladium
Selective oxidation
Sibunit carbon
Silver
Support modification
Catalysis
Physical and Theoretical Chemistry
topic 2,5-furandicarboxylic acid
5-hydroxymethylfurfural
Bimetallic catalysts
Gold
Metal oxides
Nanoparticles
Palladium
Selective oxidation
Sibunit carbon
Silver
Support modification
Catalysis
Physical and Theoretical Chemistry
description Fundacao para a Ciencia e Tecnologia (FCT), Portugal, through project UIDB/00100/2020 of the Centro de Quimica Estrutural; Associate Laboratory for Green Chemistry-LAQV,financed by national funds from FCT/MCTES (UIDB/50006/2020); FCT Scientific Employment Stimulus-Institutional Call (CEECINST/00102/2018) and PTDC/QEQ-QIN/3967/2014; Tomsk Polytechnic University Competitiveness Enhancement Program project VIU-RSCBMT-197/2020; Russian Foundation of Basic Research, project 18-29-24037; Tomsk Polytechnic University State Task `Science' (project FSWW-2020-0011) andMICINN project CTQ2017-86170-R (Spain).
publishDate 2021
dc.date.none.fl_str_mv 2021-02-16T23:30:25Z
2021-01-14
2021-01-14T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/111969
url http://hdl.handle.net/10362/111969
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2073-4344
PURE: 27963232
https://doi.org/10.3390/catal11010115
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 20
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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