High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteries
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2023 |
| Outros Autores: | , , , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| Texto Completo: | https://hdl.handle.net/1822/93621 |
Resumo: | The Supporting Information is available free of charge at: https://pubs.acs.org/doi/10.1021/acsami.3c03361 |
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High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteriesternary compositesPVDF copolymerslithium salt and ionic liquidssolid polymer electrolyteslithium-ion batteriesCiências Naturais::Ciências QuímicasEnergias renováveis e acessíveisThe Supporting Information is available free of charge at: https://pubs.acs.org/doi/10.1021/acsami.3c03361Renewable energy sources require efficient energy storage systems. Lithium-ion batteries stand out among those systems, but safety and cycling stability problems still need to be improved. This can be achieved by the implementation of solid polymer electrolytes (SPE) instead of the typically used separator/electrolyte system. Thus, ternary SPEs have been developed based on poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene), P(VDF-TrFE-CFE) as host polymers, clinoptilolite (CPT) zeolite added to stabilize the battery cycling performance, and ionic liquids (ILs) (1-butyl-3-methylimidazolium thiocyanate ([BMIM][SCN])), 1-methyl-1-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([PMPyr][TFSI]) or lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), incorporated to increase the ionic conductivity. The samples were processed by doctor blade with solvent evaporation at 160 °C. The nature of the polymer matrix and fillers affect the morphology and mechanical properties of the samples and play an important role in electrochemical parameters such as ionic conductivity value, electrochemical window stability, and lithium-transference number. The best ionic conductivity (4.2 × 10–5 S cm–1) and lithium transference number (0.59) were obtained for the PVDF-HFP-CPT-[PMPyr][TFSI] sample. Charge–discharge battery tests at C/10 showed excellent battery performance with values of 150 mAh g–1 after 50 cycles, regardless of the polymer matrix and IL used. In the rate performance tests, the best SPE was the one based on the P(VDF-TrFE-CFE) host polymer, with a discharge value at C-rate of 98.7 mAh g–1, as it promoted ionic dissociation. This study proves for the first time the suitability of P(VDF-TrFE-CFE) as SPE in lithium-ion batteries, showing the relevance of the proper selection of the polymer matrix, IL type, and lithium salt in the formulation of the ternary SPE, in order to optimize solid-state battery performance. In particular, the enhancement of the ionic conductivity provided by the IL and the effect of the high dielectric constant polymer P(VDF-TrFE-CFE) in improving battery cyclability in a wide range of discharge rates must be highlighted.The authors thank the Fundação para a Ciência e Tecnologia (FCT) for financial support under the framework of Strategic Funding UIDB/04650/2020, UID/FIS/04650/2020, UID/EEA/04436/2020, and UID/QUI/00686/2020 and under Projects MIT-EXPL/TDI/0033/2021, POCI-01-0247-FEDER-046985, and 2022.03931.PTDC funded by national funds through FCT and by the ERDF through the COMPETE2020─Programa Operacional Competitividade e Internacionalização (POCI). The authors also thank the FCT for financial support under Grant SFRH/BD/140842/2018 (J.C.B.) and FCT Investigator Contracts 2020.02915.CEECIND (D.M.C), CEECIND/00833/2017 (R.G.), and 2020.04028.CEECIND (C.M.C.). This study forms part of the Advanced Materials program and was supported by MCIN with funding from European Union NextGenerationEU (Grant PRTR-C17.I1) and by the Basque Government under the IKUR program. The authors are thankful for technical and human support provided by SGIker (UPV/EHU/ERDF, EU).American Chemical Society (ACS)Universidade do MinhoBarbosa, João C.Correia, Daniela Maria SilvaFidalgo-Marijuan, ArkaitzGonçalves, Renato FerreiraFerdov, S.de Zea Bermudez, VerónicaLanceros-Méndez, S.Costa, Carlos Miguel Silva20232023-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/93621engBarbosa, J. C., Correia, D. M., Fidalgo-Marijuan, A., Gonçalves, R., Ferdov, S., de Zea Bermudez, V., … Costa, C. M. (2023, June 28). High Performance Ternary Solid Polymer Electrolytes Based on High Dielectric Poly(vinylidene fluoride) Copolymers for Solid State Lithium-Ion Batteries. ACS Applied Materials & Interfaces. American Chemical Society (ACS). http://doi.org/10.1021/acsami.3c033611944-82441944-825210.1021/acsami.3c0336137379238https://pubs.acs.org/doi/10.1021/acsami.3c03361info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-11-16T01:30:18Zoai:repositorium.sdum.uminho.pt:1822/93621Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-11-16T01:30:18Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
| dc.title.none.fl_str_mv |
High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteries |
| title |
High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteries |
| spellingShingle |
High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteries Barbosa, João C. ternary composites PVDF copolymers lithium salt and ionic liquids solid polymer electrolytes lithium-ion batteries Ciências Naturais::Ciências Químicas Energias renováveis e acessíveis |
| title_short |
High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteries |
| title_full |
High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteries |
| title_fullStr |
High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteries |
| title_full_unstemmed |
High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteries |
| title_sort |
High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteries |
| author |
Barbosa, João C. |
| author_facet |
Barbosa, João C. Correia, Daniela Maria Silva Fidalgo-Marijuan, Arkaitz Gonçalves, Renato Ferreira Ferdov, S. de Zea Bermudez, Verónica Lanceros-Méndez, S. Costa, Carlos Miguel Silva |
| author_role |
author |
| author2 |
Correia, Daniela Maria Silva Fidalgo-Marijuan, Arkaitz Gonçalves, Renato Ferreira Ferdov, S. de Zea Bermudez, Verónica Lanceros-Méndez, S. Costa, Carlos Miguel Silva |
| author2_role |
author author author author author author author |
| dc.contributor.none.fl_str_mv |
Universidade do Minho |
| dc.contributor.author.fl_str_mv |
Barbosa, João C. Correia, Daniela Maria Silva Fidalgo-Marijuan, Arkaitz Gonçalves, Renato Ferreira Ferdov, S. de Zea Bermudez, Verónica Lanceros-Méndez, S. Costa, Carlos Miguel Silva |
| dc.subject.por.fl_str_mv |
ternary composites PVDF copolymers lithium salt and ionic liquids solid polymer electrolytes lithium-ion batteries Ciências Naturais::Ciências Químicas Energias renováveis e acessíveis |
| topic |
ternary composites PVDF copolymers lithium salt and ionic liquids solid polymer electrolytes lithium-ion batteries Ciências Naturais::Ciências Químicas Energias renováveis e acessíveis |
| description |
The Supporting Information is available free of charge at: https://pubs.acs.org/doi/10.1021/acsami.3c03361 |
| publishDate |
2023 |
| dc.date.none.fl_str_mv |
2023 2023-01-01T00:00:00Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
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article |
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publishedVersion |
| dc.identifier.uri.fl_str_mv |
https://hdl.handle.net/1822/93621 |
| url |
https://hdl.handle.net/1822/93621 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
Barbosa, J. C., Correia, D. M., Fidalgo-Marijuan, A., Gonçalves, R., Ferdov, S., de Zea Bermudez, V., … Costa, C. M. (2023, June 28). High Performance Ternary Solid Polymer Electrolytes Based on High Dielectric Poly(vinylidene fluoride) Copolymers for Solid State Lithium-Ion Batteries. ACS Applied Materials & Interfaces. American Chemical Society (ACS). http://doi.org/10.1021/acsami.3c03361 1944-8244 1944-8252 10.1021/acsami.3c03361 37379238 https://pubs.acs.org/doi/10.1021/acsami.3c03361 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
| dc.publisher.none.fl_str_mv |
American Chemical Society (ACS) |
| publisher.none.fl_str_mv |
American Chemical Society (ACS) |
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reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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mluisa.alvim@gmail.com |
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