A greener route to prepare PEBAX®1074 membranes for gas separation processes

Detalhes bibliográficos
Autor(a) principal: Ortiz-Albo, Paloma
Data de Publicação: 2024
Outros Autores: Alves, Vítor D., Kumakiri, Izumi, Crespo, João, Neves, Luísa A.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/164517
Resumo: Funding Information: The authors acknowledge “ Fundação para a Ciência e Tecnologia ” through the PhD grant SFRH/BD/139389/2018 (P. Ortiz-Albo). This work was also supported by the Associate Laboratory for Green Chemistry- LAQV (Portugal) and LEAF—Linking Landscape, Environment, Agriculture and Food—Research Center , which are financed by national funds from FCT / MCTES ( UIDB/50006/2020 , UIDP/50006/2020 and UIDB/04129/2020 ) and for the research project PTDC / CTM - CTM/29869/2017 and Chugoku Regional Innovation Research Center, Japan . Funding Information: The authors acknowledge “ Fundação para a Ciência e Tecnologia ” through the PhD grant SFRH/BD/139389/2018 (P. Ortiz-Albo). This work was also supported by the Associate Laboratory for Green Chemistry- LAQV (Portugal) and LEAF—Linking Landscape, Environment, Agriculture and Food—Research Center , which are financed by national funds from FCT / MCTES ( UIDB/50006/2020 , UIDP/50006/2020 and UIDB/04129/2020 ) and for the research project PTDC / CTM - CTM/29869/2017 and Chugoku Regional Innovation Research Center, Japan . Luísa A. Neves acknowledge Fundação para a Ciência e a Tecnologia (FCT)/MCTES) for the assistant researcher contract under Scientific Employment Stimulus ( 2022.00689.CEECIND ). Publisher Copyright: © 2023 The Authors
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spelling A greener route to prepare PEBAX®1074 membranes for gas separation processesGas separationGreen solventPhase inversionPolymeric membranesRhodiasolv®PolarcleanBiochemistryMaterials Science(all)Physical and Theoretical ChemistryFiltration and SeparationSDG 9 - Industry, Innovation, and InfrastructureFunding Information: The authors acknowledge “ Fundação para a Ciência e Tecnologia ” through the PhD grant SFRH/BD/139389/2018 (P. Ortiz-Albo). This work was also supported by the Associate Laboratory for Green Chemistry- LAQV (Portugal) and LEAF—Linking Landscape, Environment, Agriculture and Food—Research Center , which are financed by national funds from FCT / MCTES ( UIDB/50006/2020 , UIDP/50006/2020 and UIDB/04129/2020 ) and for the research project PTDC / CTM - CTM/29869/2017 and Chugoku Regional Innovation Research Center, Japan . Funding Information: The authors acknowledge “ Fundação para a Ciência e Tecnologia ” through the PhD grant SFRH/BD/139389/2018 (P. Ortiz-Albo). This work was also supported by the Associate Laboratory for Green Chemistry- LAQV (Portugal) and LEAF—Linking Landscape, Environment, Agriculture and Food—Research Center , which are financed by national funds from FCT / MCTES ( UIDB/50006/2020 , UIDP/50006/2020 and UIDB/04129/2020 ) and for the research project PTDC / CTM - CTM/29869/2017 and Chugoku Regional Innovation Research Center, Japan . Luísa A. Neves acknowledge Fundação para a Ciência e a Tecnologia (FCT)/MCTES) for the assistant researcher contract under Scientific Employment Stimulus ( 2022.00689.CEECIND ). Publisher Copyright: © 2023 The AuthorsThe solvent used in membrane fabrication is crucial for a potential industrial application, with a direct effect on its safety, environmental and economic impact. Thus, in the last years, the search for greener and safer solvents became of utmost importance aiming for a sustainable fabrication of highly performing membranes, since that also affects the final membrane morphology. Typically, solvent evaporation-based methods are used for the preparation of membranes for gas separation processes, such as dip-coating and spray coating methods. The advantage of this approach relies on the possibility of using greener non-toxic solvents, such as water and ethanol. However, an alternative route might involve the use of phase inversion methods. In this procedure, the selection of the solvent will play an even more important role, with an impact on the gas separation membrane properties. Small defects or structural changes will decisively alter the final membrane performance. In this work, it is presented for the first time the alternative use of a non-toxic and eco-friendly solvent, Rhodiasolv®Polarclean, for the preparation of CO2-selective PEBAX®-based membranes using a hybrid phase inversion method. This preliminary study evaluates the relationship between the fabrication protocol, with the resulting structural, thermal, and mechanical membrane properties for self-standing membranes. The gas separation performance was tested for different gases: H2, N2, O2, CO2 and CH4. This analysis also includes a comparison with the commonly used, although strongly restricted and hazardous, solvent N-Methyl-2-Pyrrolidone (NMP).DQ - Departamento de QuímicaLAQV@REQUIMTERUNOrtiz-Albo, PalomaAlves, Vítor D.Kumakiri, IzumiCrespo, JoãoNeves, Luísa A.2024-03-06T00:23:49Z2024-022024-02-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article9application/pdfhttp://hdl.handle.net/10362/164517eng0376-7388PURE: 84622056https://doi.org/10.1016/j.memsci.2023.122346info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:52:51Zoai:run.unl.pt:10362/164517Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T04:00:13.596418Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv A greener route to prepare PEBAX®1074 membranes for gas separation processes
title A greener route to prepare PEBAX®1074 membranes for gas separation processes
spellingShingle A greener route to prepare PEBAX®1074 membranes for gas separation processes
Ortiz-Albo, Paloma
Gas separation
Green solvent
Phase inversion
Polymeric membranes
Rhodiasolv®Polarclean
Biochemistry
Materials Science(all)
Physical and Theoretical Chemistry
Filtration and Separation
SDG 9 - Industry, Innovation, and Infrastructure
title_short A greener route to prepare PEBAX®1074 membranes for gas separation processes
title_full A greener route to prepare PEBAX®1074 membranes for gas separation processes
title_fullStr A greener route to prepare PEBAX®1074 membranes for gas separation processes
title_full_unstemmed A greener route to prepare PEBAX®1074 membranes for gas separation processes
title_sort A greener route to prepare PEBAX®1074 membranes for gas separation processes
author Ortiz-Albo, Paloma
author_facet Ortiz-Albo, Paloma
Alves, Vítor D.
Kumakiri, Izumi
Crespo, João
Neves, Luísa A.
author_role author
author2 Alves, Vítor D.
Kumakiri, Izumi
Crespo, João
Neves, Luísa A.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv DQ - Departamento de Química
LAQV@REQUIMTE
RUN
dc.contributor.author.fl_str_mv Ortiz-Albo, Paloma
Alves, Vítor D.
Kumakiri, Izumi
Crespo, João
Neves, Luísa A.
dc.subject.por.fl_str_mv Gas separation
Green solvent
Phase inversion
Polymeric membranes
Rhodiasolv®Polarclean
Biochemistry
Materials Science(all)
Physical and Theoretical Chemistry
Filtration and Separation
SDG 9 - Industry, Innovation, and Infrastructure
topic Gas separation
Green solvent
Phase inversion
Polymeric membranes
Rhodiasolv®Polarclean
Biochemistry
Materials Science(all)
Physical and Theoretical Chemistry
Filtration and Separation
SDG 9 - Industry, Innovation, and Infrastructure
description Funding Information: The authors acknowledge “ Fundação para a Ciência e Tecnologia ” through the PhD grant SFRH/BD/139389/2018 (P. Ortiz-Albo). This work was also supported by the Associate Laboratory for Green Chemistry- LAQV (Portugal) and LEAF—Linking Landscape, Environment, Agriculture and Food—Research Center , which are financed by national funds from FCT / MCTES ( UIDB/50006/2020 , UIDP/50006/2020 and UIDB/04129/2020 ) and for the research project PTDC / CTM - CTM/29869/2017 and Chugoku Regional Innovation Research Center, Japan . Funding Information: The authors acknowledge “ Fundação para a Ciência e Tecnologia ” through the PhD grant SFRH/BD/139389/2018 (P. Ortiz-Albo). This work was also supported by the Associate Laboratory for Green Chemistry- LAQV (Portugal) and LEAF—Linking Landscape, Environment, Agriculture and Food—Research Center , which are financed by national funds from FCT / MCTES ( UIDB/50006/2020 , UIDP/50006/2020 and UIDB/04129/2020 ) and for the research project PTDC / CTM - CTM/29869/2017 and Chugoku Regional Innovation Research Center, Japan . Luísa A. Neves acknowledge Fundação para a Ciência e a Tecnologia (FCT)/MCTES) for the assistant researcher contract under Scientific Employment Stimulus ( 2022.00689.CEECIND ). Publisher Copyright: © 2023 The Authors
publishDate 2024
dc.date.none.fl_str_mv 2024-03-06T00:23:49Z
2024-02
2024-02-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/164517
url http://hdl.handle.net/10362/164517
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0376-7388
PURE: 84622056
https://doi.org/10.1016/j.memsci.2023.122346
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
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dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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