N-confused porphyrin immobilized on solid supports: synthesis and metal ions sensing efficacy
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/33909 |
Resumo: | In this work, the N-confused porphyrin 5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin (NCTPP) was immobilized on neutral or cationic supports based on silica and on Merrifield resin. The new materials were characterized by appropriate techniques (UV-Vis spectroscopy, SEM, and zeta potential analysis). Piezoelectric quartz crystal gold electrodes were coated with the different hybrids and their ability to interact with heavy metals was evaluated. The preliminary results obtained showed that the new materials can be explored for metal cations detection and the modification of the material surface is a key factor in tuning the metal selectivity. |
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N-confused porphyrin immobilized on solid supports: synthesis and metal ions sensing efficacyN-confused porphyrinsOrganic/inorganic hybridsMetal cationsAqueous solutionIn this work, the N-confused porphyrin 5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin (NCTPP) was immobilized on neutral or cationic supports based on silica and on Merrifield resin. The new materials were characterized by appropriate techniques (UV-Vis spectroscopy, SEM, and zeta potential analysis). Piezoelectric quartz crystal gold electrodes were coated with the different hybrids and their ability to interact with heavy metals was evaluated. The preliminary results obtained showed that the new materials can be explored for metal cations detection and the modification of the material surface is a key factor in tuning the metal selectivity.MDPI2022-05-17T17:05:13Z2018-04-01T00:00:00Z2018-04info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/33909eng10.3390/molecules23040867Gamelas, Sara R. D.Gomes, Ana T. P. C.Moura, Nuno M. M.Faustino, Maria A. F.Cavaleiro, José A. S.Lodeiro, CarlosVeríssimo, Marta I. S.Fernandes, TiagoDaniel-da-Silva, Ana L.Gomes, M. Teresa S. R.Neves, Maria G. P. M. S.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T12:04:27Zoai:ria.ua.pt:10773/33909Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:04:55.423281Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
N-confused porphyrin immobilized on solid supports: synthesis and metal ions sensing efficacy |
title |
N-confused porphyrin immobilized on solid supports: synthesis and metal ions sensing efficacy |
spellingShingle |
N-confused porphyrin immobilized on solid supports: synthesis and metal ions sensing efficacy Gamelas, Sara R. D. N-confused porphyrins Organic/inorganic hybrids Metal cations Aqueous solution |
title_short |
N-confused porphyrin immobilized on solid supports: synthesis and metal ions sensing efficacy |
title_full |
N-confused porphyrin immobilized on solid supports: synthesis and metal ions sensing efficacy |
title_fullStr |
N-confused porphyrin immobilized on solid supports: synthesis and metal ions sensing efficacy |
title_full_unstemmed |
N-confused porphyrin immobilized on solid supports: synthesis and metal ions sensing efficacy |
title_sort |
N-confused porphyrin immobilized on solid supports: synthesis and metal ions sensing efficacy |
author |
Gamelas, Sara R. D. |
author_facet |
Gamelas, Sara R. D. Gomes, Ana T. P. C. Moura, Nuno M. M. Faustino, Maria A. F. Cavaleiro, José A. S. Lodeiro, Carlos Veríssimo, Marta I. S. Fernandes, Tiago Daniel-da-Silva, Ana L. Gomes, M. Teresa S. R. Neves, Maria G. P. M. S. |
author_role |
author |
author2 |
Gomes, Ana T. P. C. Moura, Nuno M. M. Faustino, Maria A. F. Cavaleiro, José A. S. Lodeiro, Carlos Veríssimo, Marta I. S. Fernandes, Tiago Daniel-da-Silva, Ana L. Gomes, M. Teresa S. R. Neves, Maria G. P. M. S. |
author2_role |
author author author author author author author author author author |
dc.contributor.author.fl_str_mv |
Gamelas, Sara R. D. Gomes, Ana T. P. C. Moura, Nuno M. M. Faustino, Maria A. F. Cavaleiro, José A. S. Lodeiro, Carlos Veríssimo, Marta I. S. Fernandes, Tiago Daniel-da-Silva, Ana L. Gomes, M. Teresa S. R. Neves, Maria G. P. M. S. |
dc.subject.por.fl_str_mv |
N-confused porphyrins Organic/inorganic hybrids Metal cations Aqueous solution |
topic |
N-confused porphyrins Organic/inorganic hybrids Metal cations Aqueous solution |
description |
In this work, the N-confused porphyrin 5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin (NCTPP) was immobilized on neutral or cationic supports based on silica and on Merrifield resin. The new materials were characterized by appropriate techniques (UV-Vis spectroscopy, SEM, and zeta potential analysis). Piezoelectric quartz crystal gold electrodes were coated with the different hybrids and their ability to interact with heavy metals was evaluated. The preliminary results obtained showed that the new materials can be explored for metal cations detection and the modification of the material surface is a key factor in tuning the metal selectivity. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-04-01T00:00:00Z 2018-04 2022-05-17T17:05:13Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/33909 |
url |
http://hdl.handle.net/10773/33909 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.3390/molecules23040867 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
MDPI |
publisher.none.fl_str_mv |
MDPI |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799137704315715584 |