Characterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabrics
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/1822/17304 |
Resumo: | The ‘double function’ of laccase, from the ascomycete Myceliophthora, to depolymerise/polymerise lignin was studied in this work. A lignosulfonate (LS) compound was oxidised by enzymatic action and several techniques were applied to measure the polymeric changes obtained. This study was focused on the attachment level of the oxidised LS at the flax surface. RESULTS: Modified solutions were studied in terms of surface charge. Zeta potential values obtained showed an increase of polymerisation after several days of incubation. The change in molecular weight after LS polymerisation was detected using gel permeation chromatography. An increase of 1700 Da was achieved. Fourier transform infrared and UV-visible spectroscopy techniques were applied and the results showed an increase of the degree of polymerisation. The colour strength of flax fabrics incubated with oxidised LS solutions was also measured and an increase of K/S (K, absorption coefficient; S, scattering coefficient) after enzymatic oxidation was observed. CONCLUSION: The oxidised lignin products obtained show good potential for use in natural surface modification of textile materials containing flavonoids. These findings have important practical implications for lignocellulosic fibre coloration, where new polymers can replace harsh chemicals in the textile industry. Copyright © 2009 Society of Chemical Industry |
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7160 |
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Characterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabricsFTIRGel permeation chromatography (GPC)LaccaseLignosulfonatesUV-visible spectroscopyScience & TechnologyThe ‘double function’ of laccase, from the ascomycete Myceliophthora, to depolymerise/polymerise lignin was studied in this work. A lignosulfonate (LS) compound was oxidised by enzymatic action and several techniques were applied to measure the polymeric changes obtained. This study was focused on the attachment level of the oxidised LS at the flax surface. RESULTS: Modified solutions were studied in terms of surface charge. Zeta potential values obtained showed an increase of polymerisation after several days of incubation. The change in molecular weight after LS polymerisation was detected using gel permeation chromatography. An increase of 1700 Da was achieved. Fourier transform infrared and UV-visible spectroscopy techniques were applied and the results showed an increase of the degree of polymerisation. The colour strength of flax fabrics incubated with oxidised LS solutions was also measured and an increase of K/S (K, absorption coefficient; S, scattering coefficient) after enzymatic oxidation was observed. CONCLUSION: The oxidised lignin products obtained show good potential for use in natural surface modification of textile materials containing flavonoids. These findings have important practical implications for lignocellulosic fibre coloration, where new polymers can replace harsh chemicals in the textile industry. Copyright © 2009 Society of Chemical IndustryWileyUniversidade do MinhoKim, SuyeonSilva, Carla Manuela Pereira Marinho daZille, AndreaLópez, C.Evtuguin, D. V.Paulo, Artur Cavaco20092009-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/17304eng1097-012610.1002/pi.2600info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:25:14Zoai:repositorium.sdum.uminho.pt:1822/17304Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:19:27.198394Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Characterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabrics |
title |
Characterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabrics |
spellingShingle |
Characterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabrics Kim, Suyeon FTIR Gel permeation chromatography (GPC) Laccase Lignosulfonates UV-visible spectroscopy Science & Technology |
title_short |
Characterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabrics |
title_full |
Characterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabrics |
title_fullStr |
Characterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabrics |
title_full_unstemmed |
Characterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabrics |
title_sort |
Characterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabrics |
author |
Kim, Suyeon |
author_facet |
Kim, Suyeon Silva, Carla Manuela Pereira Marinho da Zille, Andrea López, C. Evtuguin, D. V. Paulo, Artur Cavaco |
author_role |
author |
author2 |
Silva, Carla Manuela Pereira Marinho da Zille, Andrea López, C. Evtuguin, D. V. Paulo, Artur Cavaco |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Kim, Suyeon Silva, Carla Manuela Pereira Marinho da Zille, Andrea López, C. Evtuguin, D. V. Paulo, Artur Cavaco |
dc.subject.por.fl_str_mv |
FTIR Gel permeation chromatography (GPC) Laccase Lignosulfonates UV-visible spectroscopy Science & Technology |
topic |
FTIR Gel permeation chromatography (GPC) Laccase Lignosulfonates UV-visible spectroscopy Science & Technology |
description |
The ‘double function’ of laccase, from the ascomycete Myceliophthora, to depolymerise/polymerise lignin was studied in this work. A lignosulfonate (LS) compound was oxidised by enzymatic action and several techniques were applied to measure the polymeric changes obtained. This study was focused on the attachment level of the oxidised LS at the flax surface. RESULTS: Modified solutions were studied in terms of surface charge. Zeta potential values obtained showed an increase of polymerisation after several days of incubation. The change in molecular weight after LS polymerisation was detected using gel permeation chromatography. An increase of 1700 Da was achieved. Fourier transform infrared and UV-visible spectroscopy techniques were applied and the results showed an increase of the degree of polymerisation. The colour strength of flax fabrics incubated with oxidised LS solutions was also measured and an increase of K/S (K, absorption coefficient; S, scattering coefficient) after enzymatic oxidation was observed. CONCLUSION: The oxidised lignin products obtained show good potential for use in natural surface modification of textile materials containing flavonoids. These findings have important practical implications for lignocellulosic fibre coloration, where new polymers can replace harsh chemicals in the textile industry. Copyright © 2009 Society of Chemical Industry |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009 2009-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1822/17304 |
url |
http://hdl.handle.net/1822/17304 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1097-0126 10.1002/pi.2600 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Wiley |
publisher.none.fl_str_mv |
Wiley |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
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1799132653642842112 |