The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst

Detalhes bibliográficos
Autor(a) principal: Sobral, Abílio J. F. N.
Data de Publicação: 2001
Outros Autores: Gonsalves, António M. d'A. Rocha
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/8300
https://doi.org/10.1002/jpp.332
Resumo: The 2,3,7,8,12,13,17,18-octaphenylporphyrinato manganese(III) chloride was prepared and its behaviour as epoxidation catalyst was studied. The role of the phenyl substituents in the ß-pyrrolic positions concerning the stability of the catalyst to the reaction conditions and the efficiency and selectivity of the oxidations was accessed in a comparative study with MnTPP and MnEtio II. Copyright © 2001 John Wiley & Sons, Ltd.
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spelling The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalystThe 2,3,7,8,12,13,17,18-octaphenylporphyrinato manganese(III) chloride was prepared and its behaviour as epoxidation catalyst was studied. The role of the phenyl substituents in the ß-pyrrolic positions concerning the stability of the catalyst to the reaction conditions and the efficiency and selectivity of the oxidations was accessed in a comparative study with MnTPP and MnEtio II. Copyright © 2001 John Wiley & Sons, Ltd.2001info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/8300http://hdl.handle.net/10316/8300https://doi.org/10.1002/jpp.332engJournal of Porphyrins and Phthalocyanines. 5:4 (2001) 428-430Sobral, Abílio J. F. N.Gonsalves, António M. d'A. Rochainfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2020-05-25T13:13:16Zoai:estudogeral.uc.pt:10316/8300Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:01:12.291401Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst
title The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst
spellingShingle The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst
Sobral, Abílio J. F. N.
title_short The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst
title_full The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst
title_fullStr The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst
title_full_unstemmed The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst
title_sort The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst
author Sobral, Abílio J. F. N.
author_facet Sobral, Abílio J. F. N.
Gonsalves, António M. d'A. Rocha
author_role author
author2 Gonsalves, António M. d'A. Rocha
author2_role author
dc.contributor.author.fl_str_mv Sobral, Abílio J. F. N.
Gonsalves, António M. d'A. Rocha
description The 2,3,7,8,12,13,17,18-octaphenylporphyrinato manganese(III) chloride was prepared and its behaviour as epoxidation catalyst was studied. The role of the phenyl substituents in the ß-pyrrolic positions concerning the stability of the catalyst to the reaction conditions and the efficiency and selectivity of the oxidations was accessed in a comparative study with MnTPP and MnEtio II. Copyright © 2001 John Wiley & Sons, Ltd.
publishDate 2001
dc.date.none.fl_str_mv 2001
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dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/8300
http://hdl.handle.net/10316/8300
https://doi.org/10.1002/jpp.332
url http://hdl.handle.net/10316/8300
https://doi.org/10.1002/jpp.332
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dc.relation.none.fl_str_mv Journal of Porphyrins and Phthalocyanines. 5:4 (2001) 428-430
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