The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst
Autor(a) principal: | |
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Data de Publicação: | 2001 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10316/8300 https://doi.org/10.1002/jpp.332 |
Resumo: | The 2,3,7,8,12,13,17,18-octaphenylporphyrinato manganese(III) chloride was prepared and its behaviour as epoxidation catalyst was studied. The role of the phenyl substituents in the ß-pyrrolic positions concerning the stability of the catalyst to the reaction conditions and the efficiency and selectivity of the oxidations was accessed in a comparative study with MnTPP and MnEtio II. Copyright © 2001 John Wiley & Sons, Ltd. |
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The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalystThe 2,3,7,8,12,13,17,18-octaphenylporphyrinato manganese(III) chloride was prepared and its behaviour as epoxidation catalyst was studied. The role of the phenyl substituents in the ß-pyrrolic positions concerning the stability of the catalyst to the reaction conditions and the efficiency and selectivity of the oxidations was accessed in a comparative study with MnTPP and MnEtio II. Copyright © 2001 John Wiley & Sons, Ltd.2001info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/8300http://hdl.handle.net/10316/8300https://doi.org/10.1002/jpp.332engJournal of Porphyrins and Phthalocyanines. 5:4 (2001) 428-430Sobral, Abílio J. F. N.Gonsalves, António M. d'A. Rochainfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2020-05-25T13:13:16Zoai:estudogeral.uc.pt:10316/8300Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:01:12.291401Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst |
title |
The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst |
spellingShingle |
The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst Sobral, Abílio J. F. N. |
title_short |
The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst |
title_full |
The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst |
title_fullStr |
The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst |
title_full_unstemmed |
The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst |
title_sort |
The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation catalyst |
author |
Sobral, Abílio J. F. N. |
author_facet |
Sobral, Abílio J. F. N. Gonsalves, António M. d'A. Rocha |
author_role |
author |
author2 |
Gonsalves, António M. d'A. Rocha |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Sobral, Abílio J. F. N. Gonsalves, António M. d'A. Rocha |
description |
The 2,3,7,8,12,13,17,18-octaphenylporphyrinato manganese(III) chloride was prepared and its behaviour as epoxidation catalyst was studied. The role of the phenyl substituents in the ß-pyrrolic positions concerning the stability of the catalyst to the reaction conditions and the efficiency and selectivity of the oxidations was accessed in a comparative study with MnTPP and MnEtio II. Copyright © 2001 John Wiley & Sons, Ltd. |
publishDate |
2001 |
dc.date.none.fl_str_mv |
2001 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10316/8300 http://hdl.handle.net/10316/8300 https://doi.org/10.1002/jpp.332 |
url |
http://hdl.handle.net/10316/8300 https://doi.org/10.1002/jpp.332 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Porphyrins and Phthalocyanines. 5:4 (2001) 428-430 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799133904697819136 |