Evaluation of structural, optical and mechanical behaviour of L-argininium bis(trifluoroacetate) single crystal: an efficient organic material for second harmonic generation applications
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/37186 |
Resumo: | In the present technologically advanced era, non-linear optical materials especially organic derivatives are in the limelight due to their fast response in electro-optic switches and high nonlinear efficiency. Therefore, with respect to this behaviour, single crystals of L-argininium Bis(trifluoroacetate) (here in after called LABTF) an organic material was grown by slow evaporation solution growth technique. The grown single crystal was subjected to single crystal X-Ray diffractometer to validate its chemical structure and compound formation. The titled compound crystallizes into an asymmetric entity that comprises of one divalent L-argininium cation and two monovalent trifluoroacetic anion. All the intermolecular hydrogen bonds present in the LABTF crystal structure are investigated by 3D molecular Hirshfeld surface analysis and their relative involvements are disintegrated using 2D fingerprint plots. Further, the crystalline perfection assessment was performed using high-resolution X-Ray diffractometer which divulges the absence of structural grain boundaries in the obtained crystal. Thermal transport parameters of the titled compound were measured through Photoacoustic spectroscopy. The shock strength above which the crystal induces damage was found by the shock damage threshold technique. In addition, mechanical property related parameters such as hardness, stiffness and Young's Modulus were evaluated using the nanoindentation technique. These mechanical parameters resolve the reliability of devices and it can be enhanced by improving the crystal quality. |
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Evaluation of structural, optical and mechanical behaviour of L-argininium bis(trifluoroacetate) single crystal: an efficient organic material for second harmonic generation applicationsHigh-resolution X-Ray diffractionBirefringencePhotoacoustic spectroscopyThermal conductivityThermal effusivityDamage thresholdMechanical strengthNanoindentationStiffnessYoung's modulusIn the present technologically advanced era, non-linear optical materials especially organic derivatives are in the limelight due to their fast response in electro-optic switches and high nonlinear efficiency. Therefore, with respect to this behaviour, single crystals of L-argininium Bis(trifluoroacetate) (here in after called LABTF) an organic material was grown by slow evaporation solution growth technique. The grown single crystal was subjected to single crystal X-Ray diffractometer to validate its chemical structure and compound formation. The titled compound crystallizes into an asymmetric entity that comprises of one divalent L-argininium cation and two monovalent trifluoroacetic anion. All the intermolecular hydrogen bonds present in the LABTF crystal structure are investigated by 3D molecular Hirshfeld surface analysis and their relative involvements are disintegrated using 2D fingerprint plots. Further, the crystalline perfection assessment was performed using high-resolution X-Ray diffractometer which divulges the absence of structural grain boundaries in the obtained crystal. Thermal transport parameters of the titled compound were measured through Photoacoustic spectroscopy. The shock strength above which the crystal induces damage was found by the shock damage threshold technique. In addition, mechanical property related parameters such as hardness, stiffness and Young's Modulus were evaluated using the nanoindentation technique. These mechanical parameters resolve the reliability of devices and it can be enhanced by improving the crystal quality.Elsevier2023-04-19T14:56:49Z2019-06-01T00:00:00Z2019-06info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/37186eng0022-369710.1016/j.jpcs.2019.02.002Sonia, MsVijayan, N.Vij, MahakYadav, HarshKumar, RavinderSur, DebashishSingh, BudhendraMartin Britto Dhas, S.A.Verma, Sunilinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T12:11:43Zoai:ria.ua.pt:10773/37186Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:07:48.721193Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Evaluation of structural, optical and mechanical behaviour of L-argininium bis(trifluoroacetate) single crystal: an efficient organic material for second harmonic generation applications |
title |
Evaluation of structural, optical and mechanical behaviour of L-argininium bis(trifluoroacetate) single crystal: an efficient organic material for second harmonic generation applications |
spellingShingle |
Evaluation of structural, optical and mechanical behaviour of L-argininium bis(trifluoroacetate) single crystal: an efficient organic material for second harmonic generation applications Sonia, Ms High-resolution X-Ray diffraction Birefringence Photoacoustic spectroscopy Thermal conductivity Thermal effusivity Damage threshold Mechanical strength Nanoindentation Stiffness Young's modulus |
title_short |
Evaluation of structural, optical and mechanical behaviour of L-argininium bis(trifluoroacetate) single crystal: an efficient organic material for second harmonic generation applications |
title_full |
Evaluation of structural, optical and mechanical behaviour of L-argininium bis(trifluoroacetate) single crystal: an efficient organic material for second harmonic generation applications |
title_fullStr |
Evaluation of structural, optical and mechanical behaviour of L-argininium bis(trifluoroacetate) single crystal: an efficient organic material for second harmonic generation applications |
title_full_unstemmed |
Evaluation of structural, optical and mechanical behaviour of L-argininium bis(trifluoroacetate) single crystal: an efficient organic material for second harmonic generation applications |
title_sort |
Evaluation of structural, optical and mechanical behaviour of L-argininium bis(trifluoroacetate) single crystal: an efficient organic material for second harmonic generation applications |
author |
Sonia, Ms |
author_facet |
Sonia, Ms Vijayan, N. Vij, Mahak Yadav, Harsh Kumar, Ravinder Sur, Debashish Singh, Budhendra Martin Britto Dhas, S.A. Verma, Sunil |
author_role |
author |
author2 |
Vijayan, N. Vij, Mahak Yadav, Harsh Kumar, Ravinder Sur, Debashish Singh, Budhendra Martin Britto Dhas, S.A. Verma, Sunil |
author2_role |
author author author author author author author author |
dc.contributor.author.fl_str_mv |
Sonia, Ms Vijayan, N. Vij, Mahak Yadav, Harsh Kumar, Ravinder Sur, Debashish Singh, Budhendra Martin Britto Dhas, S.A. Verma, Sunil |
dc.subject.por.fl_str_mv |
High-resolution X-Ray diffraction Birefringence Photoacoustic spectroscopy Thermal conductivity Thermal effusivity Damage threshold Mechanical strength Nanoindentation Stiffness Young's modulus |
topic |
High-resolution X-Ray diffraction Birefringence Photoacoustic spectroscopy Thermal conductivity Thermal effusivity Damage threshold Mechanical strength Nanoindentation Stiffness Young's modulus |
description |
In the present technologically advanced era, non-linear optical materials especially organic derivatives are in the limelight due to their fast response in electro-optic switches and high nonlinear efficiency. Therefore, with respect to this behaviour, single crystals of L-argininium Bis(trifluoroacetate) (here in after called LABTF) an organic material was grown by slow evaporation solution growth technique. The grown single crystal was subjected to single crystal X-Ray diffractometer to validate its chemical structure and compound formation. The titled compound crystallizes into an asymmetric entity that comprises of one divalent L-argininium cation and two monovalent trifluoroacetic anion. All the intermolecular hydrogen bonds present in the LABTF crystal structure are investigated by 3D molecular Hirshfeld surface analysis and their relative involvements are disintegrated using 2D fingerprint plots. Further, the crystalline perfection assessment was performed using high-resolution X-Ray diffractometer which divulges the absence of structural grain boundaries in the obtained crystal. Thermal transport parameters of the titled compound were measured through Photoacoustic spectroscopy. The shock strength above which the crystal induces damage was found by the shock damage threshold technique. In addition, mechanical property related parameters such as hardness, stiffness and Young's Modulus were evaluated using the nanoindentation technique. These mechanical parameters resolve the reliability of devices and it can be enhanced by improving the crystal quality. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-06-01T00:00:00Z 2019-06 2023-04-19T14:56:49Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/37186 |
url |
http://hdl.handle.net/10773/37186 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
0022-3697 10.1016/j.jpcs.2019.02.002 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137732412309504 |