Morphology and miscibility of chitosan/soy protein blended membranes
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/1822/14292 |
Resumo: | A physico-chemical characterization of blended membranes composed by chitosan and soy protein has been carried out in order to probe the interactions that allow membranes to be formed from these biopolymer mixtures. These membranes are developed aiming at applications in wound healing and skin tissue engineering scaffolding. The structural features of chitosan/soy blended membranes were investigated by means of solid state carbon nuclear magnetic resonance (NMR), infrared spectroscopy (FTIR), contact angle, and atomic force microscopy. FTIR investigations suggested that chitosan and soy may have participated in a specific intermolecular interaction. The proton spin–lattice relaxation experiments in the rotating frame on blended membranes indicated that independently of the preparation conditions, the blend components are not completely miscible possibly due to a weak polymer–protein interaction. It was also shown that the blended systems showed a rougher surface morphology which was dependent of soy content in the blend system. |
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Morphology and miscibility of chitosan/soy protein blended membranesChitosanSoy proteinBlend membraneMiscibilityInteractionsTime relaxationScience & TechnologyA physico-chemical characterization of blended membranes composed by chitosan and soy protein has been carried out in order to probe the interactions that allow membranes to be formed from these biopolymer mixtures. These membranes are developed aiming at applications in wound healing and skin tissue engineering scaffolding. The structural features of chitosan/soy blended membranes were investigated by means of solid state carbon nuclear magnetic resonance (NMR), infrared spectroscopy (FTIR), contact angle, and atomic force microscopy. FTIR investigations suggested that chitosan and soy may have participated in a specific intermolecular interaction. The proton spin–lattice relaxation experiments in the rotating frame on blended membranes indicated that independently of the preparation conditions, the blend components are not completely miscible possibly due to a weak polymer–protein interaction. It was also shown that the blended systems showed a rougher surface morphology which was dependent of soy content in the blend system.ElsevierUniversidade do MinhoSilva, Simone SantosGoodfellow, Brian J.Benesch, JohanRocha, J.Mano, J. F.Reis, R. L.20072007-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/14292eng0144-861710.1016/j.carbpol.2007.02.023info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:04:58Zoai:repositorium.sdum.uminho.pt:1822/14292Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T18:55:18.294560Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Morphology and miscibility of chitosan/soy protein blended membranes |
title |
Morphology and miscibility of chitosan/soy protein blended membranes |
spellingShingle |
Morphology and miscibility of chitosan/soy protein blended membranes Silva, Simone Santos Chitosan Soy protein Blend membrane Miscibility Interactions Time relaxation Science & Technology |
title_short |
Morphology and miscibility of chitosan/soy protein blended membranes |
title_full |
Morphology and miscibility of chitosan/soy protein blended membranes |
title_fullStr |
Morphology and miscibility of chitosan/soy protein blended membranes |
title_full_unstemmed |
Morphology and miscibility of chitosan/soy protein blended membranes |
title_sort |
Morphology and miscibility of chitosan/soy protein blended membranes |
author |
Silva, Simone Santos |
author_facet |
Silva, Simone Santos Goodfellow, Brian J. Benesch, Johan Rocha, J. Mano, J. F. Reis, R. L. |
author_role |
author |
author2 |
Goodfellow, Brian J. Benesch, Johan Rocha, J. Mano, J. F. Reis, R. L. |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Silva, Simone Santos Goodfellow, Brian J. Benesch, Johan Rocha, J. Mano, J. F. Reis, R. L. |
dc.subject.por.fl_str_mv |
Chitosan Soy protein Blend membrane Miscibility Interactions Time relaxation Science & Technology |
topic |
Chitosan Soy protein Blend membrane Miscibility Interactions Time relaxation Science & Technology |
description |
A physico-chemical characterization of blended membranes composed by chitosan and soy protein has been carried out in order to probe the interactions that allow membranes to be formed from these biopolymer mixtures. These membranes are developed aiming at applications in wound healing and skin tissue engineering scaffolding. The structural features of chitosan/soy blended membranes were investigated by means of solid state carbon nuclear magnetic resonance (NMR), infrared spectroscopy (FTIR), contact angle, and atomic force microscopy. FTIR investigations suggested that chitosan and soy may have participated in a specific intermolecular interaction. The proton spin–lattice relaxation experiments in the rotating frame on blended membranes indicated that independently of the preparation conditions, the blend components are not completely miscible possibly due to a weak polymer–protein interaction. It was also shown that the blended systems showed a rougher surface morphology which was dependent of soy content in the blend system. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007 2007-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1822/14292 |
url |
http://hdl.handle.net/1822/14292 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
0144-8617 10.1016/j.carbpol.2007.02.023 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799132337674387456 |