Ground- and excited-state properties of some naphthoflavyliums

Detalhes bibliográficos
Autor(a) principal: Elhabiri, Mourad
Data de Publicação: 1996
Outros Autores: Figueiredo, Paulo, George, Florian, Cornard, Jean-Paul, Fougerousse, André, Merlin, Jean-Claude, Brouillard, Raymond
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10884/1339
Resumo: A series of five, structurally related, substituted 2-phenyl-benzopyrylium (flavylium) salts were synthesized and characterized by NMR, absorption, and fluorescence techniques. Their hydration and deprotonation constants were obtained through thermodynamic and relaxation kinetic methods. Metallic complexation with the two compounds possessing a catechol group and its effect on the fluorescence intensity was also studied. The ground state properties of the five pigments are correlated with the theoretical data collected through AM1 molecular orbital calculations.
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spelling Ground- and excited-state properties of some naphthoflavyliumsA series of five, structurally related, substituted 2-phenyl-benzopyrylium (flavylium) salts were synthesized and characterized by NMR, absorption, and fluorescence techniques. Their hydration and deprotonation constants were obtained through thermodynamic and relaxation kinetic methods. Metallic complexation with the two compounds possessing a catechol group and its effect on the fluorescence intensity was also studied. The ground state properties of the five pigments are correlated with the theoretical data collected through AM1 molecular orbital calculations.2018-09-04T09:58:24Z1996-01-01T00:00:00Z1996info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleimage/pnghttp://hdl.handle.net/10884/1339engElhabiri, MouradFigueiredo, PauloGeorge, FlorianCornard, Jean-PaulFougerousse, AndréMerlin, Jean-ClaudeBrouillard, Raymondinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-01-04T11:08:03Zoai:repositorio-cientifico.uatlantica.pt:10884/1339Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T01:29:54.528907Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Ground- and excited-state properties of some naphthoflavyliums
title Ground- and excited-state properties of some naphthoflavyliums
spellingShingle Ground- and excited-state properties of some naphthoflavyliums
Elhabiri, Mourad
title_short Ground- and excited-state properties of some naphthoflavyliums
title_full Ground- and excited-state properties of some naphthoflavyliums
title_fullStr Ground- and excited-state properties of some naphthoflavyliums
title_full_unstemmed Ground- and excited-state properties of some naphthoflavyliums
title_sort Ground- and excited-state properties of some naphthoflavyliums
author Elhabiri, Mourad
author_facet Elhabiri, Mourad
Figueiredo, Paulo
George, Florian
Cornard, Jean-Paul
Fougerousse, André
Merlin, Jean-Claude
Brouillard, Raymond
author_role author
author2 Figueiredo, Paulo
George, Florian
Cornard, Jean-Paul
Fougerousse, André
Merlin, Jean-Claude
Brouillard, Raymond
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Elhabiri, Mourad
Figueiredo, Paulo
George, Florian
Cornard, Jean-Paul
Fougerousse, André
Merlin, Jean-Claude
Brouillard, Raymond
description A series of five, structurally related, substituted 2-phenyl-benzopyrylium (flavylium) salts were synthesized and characterized by NMR, absorption, and fluorescence techniques. Their hydration and deprotonation constants were obtained through thermodynamic and relaxation kinetic methods. Metallic complexation with the two compounds possessing a catechol group and its effect on the fluorescence intensity was also studied. The ground state properties of the five pigments are correlated with the theoretical data collected through AM1 molecular orbital calculations.
publishDate 1996
dc.date.none.fl_str_mv 1996-01-01T00:00:00Z
1996
2018-09-04T09:58:24Z
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status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10884/1339
url http://hdl.handle.net/10884/1339
dc.language.iso.fl_str_mv eng
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dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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