Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methods
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/26511 |
Resumo: | Magnesium-aluminum-bismuth layered double hydroxides (Mg3Al1-xBix; LDHs) were prepared using both coprecipitation and sol-gel methods. For the preparation of Mg/Al/Bi LDH by the co-precipitation method, the appropriate amounts of dissolved starting materials (Al(NO3)3 · 9H2O, Mg(NO3)2 · 6H2O and Bi(NO3)3 · 5H2O) were mixed with a solution of NaHCO3:NaOH. In the sol-gel processing, the precursor Mg-Al-Bi-O gels were synthesized using the same starting materials and ethylene glycol as complexing agent. The mixed-metal oxides obtained by subsequent heating of Mg-Al-Bi-O gels at 650 °C were reconstructed to Mg3Al1-xBix LDHs in water at 80 °C. All the synthesized products were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM) and dielectric measurements. |
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Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methodsLayered double hydroxideBismuth substitutionCo-precipitationSol-gelDielectric propertiesMagnesium-aluminum-bismuth layered double hydroxides (Mg3Al1-xBix; LDHs) were prepared using both coprecipitation and sol-gel methods. For the preparation of Mg/Al/Bi LDH by the co-precipitation method, the appropriate amounts of dissolved starting materials (Al(NO3)3 · 9H2O, Mg(NO3)2 · 6H2O and Bi(NO3)3 · 5H2O) were mixed with a solution of NaHCO3:NaOH. In the sol-gel processing, the precursor Mg-Al-Bi-O gels were synthesized using the same starting materials and ethylene glycol as complexing agent. The mixed-metal oxides obtained by subsequent heating of Mg-Al-Bi-O gels at 650 °C were reconstructed to Mg3Al1-xBix LDHs in water at 80 °C. All the synthesized products were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM) and dielectric measurements.Sciendo2019-09-10T13:46:31Z2019-04-19T00:00:00Z2019-04-19info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/26511eng2083-133110.2478/msp-2019-0035Sokol, DenisIvanov, MaksimSalak, Andrei N.Grigalaitis, RobertasBanys, JurasKareiva, Aivarasinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T11:51:21Zoai:ria.ua.pt:10773/26511Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:59:29.369407Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methods |
title |
Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methods |
spellingShingle |
Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methods Sokol, Denis Layered double hydroxide Bismuth substitution Co-precipitation Sol-gel Dielectric properties |
title_short |
Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methods |
title_full |
Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methods |
title_fullStr |
Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methods |
title_full_unstemmed |
Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methods |
title_sort |
Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methods |
author |
Sokol, Denis |
author_facet |
Sokol, Denis Ivanov, Maksim Salak, Andrei N. Grigalaitis, Robertas Banys, Juras Kareiva, Aivaras |
author_role |
author |
author2 |
Ivanov, Maksim Salak, Andrei N. Grigalaitis, Robertas Banys, Juras Kareiva, Aivaras |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Sokol, Denis Ivanov, Maksim Salak, Andrei N. Grigalaitis, Robertas Banys, Juras Kareiva, Aivaras |
dc.subject.por.fl_str_mv |
Layered double hydroxide Bismuth substitution Co-precipitation Sol-gel Dielectric properties |
topic |
Layered double hydroxide Bismuth substitution Co-precipitation Sol-gel Dielectric properties |
description |
Magnesium-aluminum-bismuth layered double hydroxides (Mg3Al1-xBix; LDHs) were prepared using both coprecipitation and sol-gel methods. For the preparation of Mg/Al/Bi LDH by the co-precipitation method, the appropriate amounts of dissolved starting materials (Al(NO3)3 · 9H2O, Mg(NO3)2 · 6H2O and Bi(NO3)3 · 5H2O) were mixed with a solution of NaHCO3:NaOH. In the sol-gel processing, the precursor Mg-Al-Bi-O gels were synthesized using the same starting materials and ethylene glycol as complexing agent. The mixed-metal oxides obtained by subsequent heating of Mg-Al-Bi-O gels at 650 °C were reconstructed to Mg3Al1-xBix LDHs in water at 80 °C. All the synthesized products were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM) and dielectric measurements. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-09-10T13:46:31Z 2019-04-19T00:00:00Z 2019-04-19 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/26511 |
url |
http://hdl.handle.net/10773/26511 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
2083-1331 10.2478/msp-2019-0035 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Sciendo |
publisher.none.fl_str_mv |
Sciendo |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799137649296932864 |