Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2023 |
| Outros Autores: | , , , , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| Texto Completo: | http://hdl.handle.net/10362/164427 |
Resumo: | A.V.G. and K.T.M. thank FCT and Instituto Superior Técnico (DL 57/2016, L 57/2017 and CEEC Institutional 2018 Programs, Contracts no: IST-ID/110/2018 and IST-ID/85/2018). VAA is grateful to Associação do Instituto Superior Técnico para Investigação e Desenvolvimento for her research fellowship through grant no: BL110/2022-IST-ID. K.T.M. and A.V.G. acknowledge the support by the Baku State University (Azerbaijan). A.R.R. thanks the Erasmus Program of the University of Milan and the Instituto Superior Técnico for a traineeship at the IST. Authors thank the Portuguese NMR Network (IST-UL Centre) and the IST Node of the Portuguese Network of mass-spectrometry. NMR spectrometers are part of The National NMR Facility, supported by FCT (ROTEIRO/0031/2013-PINFRA/22161/2016) (co- financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. |
| id |
RCAP_7ff3cd0a42db0afd6e4d882dc6e05752 |
|---|---|
| oai_identifier_str |
oai:run.unl.pt:10362/164427 |
| network_acronym_str |
RCAP |
| network_name_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| repository_id_str |
7160 |
| spelling |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) ComplexesCatalytic Application in Cycloaddition Reaction of CO2 with EpoxidesChemistry(all)Chemical Engineering(all)A.V.G. and K.T.M. thank FCT and Instituto Superior Técnico (DL 57/2016, L 57/2017 and CEEC Institutional 2018 Programs, Contracts no: IST-ID/110/2018 and IST-ID/85/2018). VAA is grateful to Associação do Instituto Superior Técnico para Investigação e Desenvolvimento for her research fellowship through grant no: BL110/2022-IST-ID. K.T.M. and A.V.G. acknowledge the support by the Baku State University (Azerbaijan). A.R.R. thanks the Erasmus Program of the University of Milan and the Instituto Superior Técnico for a traineeship at the IST. Authors thank the Portuguese NMR Network (IST-UL Centre) and the IST Node of the Portuguese Network of mass-spectrometry. NMR spectrometers are part of The National NMR Facility, supported by FCT (ROTEIRO/0031/2013-PINFRA/22161/2016) (co- financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society.Three new zinc(II) complexes [Zn(H2L3)2(H2O)3] (Zn2), [Zn(H3L2a)(H2O)3]n (Zn3) (H3L2a = 2,4-diiodo-5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene)hydrazineyl)isophthalate) and [Zn(HL4)(DMF)(H2O)]n (Zn4) were synthesized by the reaction of Zn(II) salts with 5-(2-(2,4-dioxopentan-3-ylidene)hydrazineyl) isophthalic acid (H3L3), 2,4,6-triiodo-5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene)hydrazineyl) isophthalic acid (H5L2) (in the presence of NH2OH·HCl) and 5-(2-(2,4-dioxopentan-3-ylidene)hydrazineyl)-2,4,6-triiodoisophthalic acid (H3L4), respectively. According to the X-ray structural analysis, the intramolecular resonance-assisted hydrogen bond ring remains intact, with N···O distances of 2.562(5) and 2.573(5) Å in Zn2, 2.603(6) Å in Zn3, and 2.563(8) Å in Zn4. In the crystal packing of Zn3, the cooperation of I···O and I···I types of halogen bonds between tectons leads to a one-dimensional supramolecular polymer, while I···O interactions aggregate 1D chains of coordination polymer Zn4. These new complexes (Zn2, Zn3, and Zn4) and known [Zn(H3L1)(H2O)2]n (Zn1) (H3L1 = 5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene) hydrazineyl)isophthalate), {[Zn(H3L1)(H2O)3]·3H2O}n (Zn5), [Cd(H3L1)(H2O)2]n (Cd1), {[Cd(HL3)(H2O)2(DMF)]·H2O}n (Cd2), [Cd(H3L3)]n (Cd-3), {[Cd2(μ-H2O)2(μ-H2L4)2(H2L4)2]·2H2O}n (Cd4), and {[Cd(H3L1)(H2O)3]·4H2O}n (Cd5) were tested as catalysts in the cycloaddition reaction of CO2 with epoxides in the presence of tetrabutylammonium halides as the cocatalyst. The halogen-bonded catalyst Zn4 is the most efficient one in the presence of tetrabutylammonium bromide by affording a high yield (85-99%) of cyclic carbonates under solvent-free conditions after 48 h at 40 bar and 80 °C.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNAliyeva, Vusala A.Paninho, Ana B.Nunes, Ana V. M.Karmakar, AnirbanGurbanov, Atash V.Rutigliano, Arianna R.Gallo, EmmaMahmudov, Kamran T.Pombeiro, Armando J. L.2024-03-04T23:57:09Z2023-11-142023-11-14T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article11application/pdfhttp://hdl.handle.net/10362/164427eng2470-1343PURE: 83889461https://doi.org/10.1021/acsomega.3c04262info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T18:19:04Zoai:run.unl.pt:10362/164427Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T18:19:04Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
| dc.title.none.fl_str_mv |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes Catalytic Application in Cycloaddition Reaction of CO2 with Epoxides |
| title |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| spellingShingle |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes Aliyeva, Vusala A. Chemistry(all) Chemical Engineering(all) |
| title_short |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| title_full |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| title_fullStr |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| title_full_unstemmed |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| title_sort |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| author |
Aliyeva, Vusala A. |
| author_facet |
Aliyeva, Vusala A. Paninho, Ana B. Nunes, Ana V. M. Karmakar, Anirban Gurbanov, Atash V. Rutigliano, Arianna R. Gallo, Emma Mahmudov, Kamran T. Pombeiro, Armando J. L. |
| author_role |
author |
| author2 |
Paninho, Ana B. Nunes, Ana V. M. Karmakar, Anirban Gurbanov, Atash V. Rutigliano, Arianna R. Gallo, Emma Mahmudov, Kamran T. Pombeiro, Armando J. L. |
| author2_role |
author author author author author author author author |
| dc.contributor.none.fl_str_mv |
LAQV@REQUIMTE DQ - Departamento de Química RUN |
| dc.contributor.author.fl_str_mv |
Aliyeva, Vusala A. Paninho, Ana B. Nunes, Ana V. M. Karmakar, Anirban Gurbanov, Atash V. Rutigliano, Arianna R. Gallo, Emma Mahmudov, Kamran T. Pombeiro, Armando J. L. |
| dc.subject.por.fl_str_mv |
Chemistry(all) Chemical Engineering(all) |
| topic |
Chemistry(all) Chemical Engineering(all) |
| description |
A.V.G. and K.T.M. thank FCT and Instituto Superior Técnico (DL 57/2016, L 57/2017 and CEEC Institutional 2018 Programs, Contracts no: IST-ID/110/2018 and IST-ID/85/2018). VAA is grateful to Associação do Instituto Superior Técnico para Investigação e Desenvolvimento for her research fellowship through grant no: BL110/2022-IST-ID. K.T.M. and A.V.G. acknowledge the support by the Baku State University (Azerbaijan). A.R.R. thanks the Erasmus Program of the University of Milan and the Instituto Superior Técnico for a traineeship at the IST. Authors thank the Portuguese NMR Network (IST-UL Centre) and the IST Node of the Portuguese Network of mass-spectrometry. NMR spectrometers are part of The National NMR Facility, supported by FCT (ROTEIRO/0031/2013-PINFRA/22161/2016) (co- financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. |
| publishDate |
2023 |
| dc.date.none.fl_str_mv |
2023-11-14 2023-11-14T00:00:00Z 2024-03-04T23:57:09Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/164427 |
| url |
http://hdl.handle.net/10362/164427 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
2470-1343 PURE: 83889461 https://doi.org/10.1021/acsomega.3c04262 |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
11 application/pdf |
| dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
| instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
| instacron_str |
RCAAP |
| institution |
RCAAP |
| reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
| repository.mail.fl_str_mv |
mluisa.alvim@gmail.com |
| _version_ |
1817545992434614272 |