Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes

Detalhes bibliográficos
Autor(a) principal: Aliyeva, Vusala A.
Data de Publicação: 2023
Outros Autores: Paninho, Ana B., Nunes, Ana V. M., Karmakar, Anirban, Gurbanov, Atash V., Rutigliano, Arianna R., Gallo, Emma, Mahmudov, Kamran T., Pombeiro, Armando J. L.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/164427
Resumo: A.V.G. and K.T.M. thank FCT and Instituto Superior Técnico (DL 57/2016, L 57/2017 and CEEC Institutional 2018 Programs, Contracts no: IST-ID/110/2018 and IST-ID/85/2018). VAA is grateful to Associação do Instituto Superior Técnico para Investigação e Desenvolvimento for her research fellowship through grant no: BL110/2022-IST-ID. K.T.M. and A.V.G. acknowledge the support by the Baku State University (Azerbaijan). A.R.R. thanks the Erasmus Program of the University of Milan and the Instituto Superior Técnico for a traineeship at the IST. Authors thank the Portuguese NMR Network (IST-UL Centre) and the IST Node of the Portuguese Network of mass-spectrometry. NMR spectrometers are part of The National NMR Facility, supported by FCT (ROTEIRO/0031/2013-PINFRA/22161/2016) (co- financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society.
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spelling Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) ComplexesCatalytic Application in Cycloaddition Reaction of CO2 with EpoxidesChemistry(all)Chemical Engineering(all)A.V.G. and K.T.M. thank FCT and Instituto Superior Técnico (DL 57/2016, L 57/2017 and CEEC Institutional 2018 Programs, Contracts no: IST-ID/110/2018 and IST-ID/85/2018). VAA is grateful to Associação do Instituto Superior Técnico para Investigação e Desenvolvimento for her research fellowship through grant no: BL110/2022-IST-ID. K.T.M. and A.V.G. acknowledge the support by the Baku State University (Azerbaijan). A.R.R. thanks the Erasmus Program of the University of Milan and the Instituto Superior Técnico for a traineeship at the IST. Authors thank the Portuguese NMR Network (IST-UL Centre) and the IST Node of the Portuguese Network of mass-spectrometry. NMR spectrometers are part of The National NMR Facility, supported by FCT (ROTEIRO/0031/2013-PINFRA/22161/2016) (co- financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society.Three new zinc(II) complexes [Zn(H2L3)2(H2O)3] (Zn2), [Zn(H3L2a)(H2O)3]n (Zn3) (H3L2a = 2,4-diiodo-5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene)hydrazineyl)isophthalate) and [Zn(HL4)(DMF)(H2O)]n (Zn4) were synthesized by the reaction of Zn(II) salts with 5-(2-(2,4-dioxopentan-3-ylidene)hydrazineyl) isophthalic acid (H3L3), 2,4,6-triiodo-5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene)hydrazineyl) isophthalic acid (H5L2) (in the presence of NH2OH·HCl) and 5-(2-(2,4-dioxopentan-3-ylidene)hydrazineyl)-2,4,6-triiodoisophthalic acid (H3L4), respectively. According to the X-ray structural analysis, the intramolecular resonance-assisted hydrogen bond ring remains intact, with N···O distances of 2.562(5) and 2.573(5) Å in Zn2, 2.603(6) Å in Zn3, and 2.563(8) Å in Zn4. In the crystal packing of Zn3, the cooperation of I···O and I···I types of halogen bonds between tectons leads to a one-dimensional supramolecular polymer, while I···O interactions aggregate 1D chains of coordination polymer Zn4. These new complexes (Zn2, Zn3, and Zn4) and known [Zn(H3L1)(H2O)2]n (Zn1) (H3L1 = 5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene) hydrazineyl)isophthalate), {[Zn(H3L1)(H2O)3]·3H2O}n (Zn5), [Cd(H3L1)(H2O)2]n (Cd1), {[Cd(HL3)(H2O)2(DMF)]·H2O}n (Cd2), [Cd(H3L3)]n (Cd-3), {[Cd2(μ-H2O)2(μ-H2L4)2(H2L4)2]·2H2O}n (Cd4), and {[Cd(H3L1)(H2O)3]·4H2O}n (Cd5) were tested as catalysts in the cycloaddition reaction of CO2 with epoxides in the presence of tetrabutylammonium halides as the cocatalyst. The halogen-bonded catalyst Zn4 is the most efficient one in the presence of tetrabutylammonium bromide by affording a high yield (85-99%) of cyclic carbonates under solvent-free conditions after 48 h at 40 bar and 80 °C.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNAliyeva, Vusala A.Paninho, Ana B.Nunes, Ana V. M.Karmakar, AnirbanGurbanov, Atash V.Rutigliano, Arianna R.Gallo, EmmaMahmudov, Kamran T.Pombeiro, Armando J. L.2024-03-04T23:57:09Z2023-11-142023-11-14T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article11application/pdfhttp://hdl.handle.net/10362/164427eng2470-1343PURE: 83889461https://doi.org/10.1021/acsomega.3c04262info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T18:19:04Zoai:run.unl.pt:10362/164427Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T18:19:04Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes
Catalytic Application in Cycloaddition Reaction of CO2 with Epoxides
title Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes
spellingShingle Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes
Aliyeva, Vusala A.
Chemistry(all)
Chemical Engineering(all)
title_short Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes
title_full Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes
title_fullStr Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes
title_full_unstemmed Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes
title_sort Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes
author Aliyeva, Vusala A.
author_facet Aliyeva, Vusala A.
Paninho, Ana B.
Nunes, Ana V. M.
Karmakar, Anirban
Gurbanov, Atash V.
Rutigliano, Arianna R.
Gallo, Emma
Mahmudov, Kamran T.
Pombeiro, Armando J. L.
author_role author
author2 Paninho, Ana B.
Nunes, Ana V. M.
Karmakar, Anirban
Gurbanov, Atash V.
Rutigliano, Arianna R.
Gallo, Emma
Mahmudov, Kamran T.
Pombeiro, Armando J. L.
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Aliyeva, Vusala A.
Paninho, Ana B.
Nunes, Ana V. M.
Karmakar, Anirban
Gurbanov, Atash V.
Rutigliano, Arianna R.
Gallo, Emma
Mahmudov, Kamran T.
Pombeiro, Armando J. L.
dc.subject.por.fl_str_mv Chemistry(all)
Chemical Engineering(all)
topic Chemistry(all)
Chemical Engineering(all)
description A.V.G. and K.T.M. thank FCT and Instituto Superior Técnico (DL 57/2016, L 57/2017 and CEEC Institutional 2018 Programs, Contracts no: IST-ID/110/2018 and IST-ID/85/2018). VAA is grateful to Associação do Instituto Superior Técnico para Investigação e Desenvolvimento for her research fellowship through grant no: BL110/2022-IST-ID. K.T.M. and A.V.G. acknowledge the support by the Baku State University (Azerbaijan). A.R.R. thanks the Erasmus Program of the University of Milan and the Instituto Superior Técnico for a traineeship at the IST. Authors thank the Portuguese NMR Network (IST-UL Centre) and the IST Node of the Portuguese Network of mass-spectrometry. NMR spectrometers are part of The National NMR Facility, supported by FCT (ROTEIRO/0031/2013-PINFRA/22161/2016) (co- financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society.
publishDate 2023
dc.date.none.fl_str_mv 2023-11-14
2023-11-14T00:00:00Z
2024-03-04T23:57:09Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/164427
url http://hdl.handle.net/10362/164427
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2470-1343
PURE: 83889461
https://doi.org/10.1021/acsomega.3c04262
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