MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes
Autor(a) principal: | |
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Data de Publicação: | 2023 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10198/26621 |
Resumo: | The microporous bioderived Al dicarboxylate MIL-160(Al) MOF in its shaped form has been evaluated as a candidate for biogas upgrading (BU) and/or carbon capture and storage (CCS) by studying adsorption isotherms of CO2, CH4, and N2 at 313, 343, and 373 K until 8 bar. The isotherms disclosed the following loading capacities: 4.2 (CO2), 2.07 (CH4), and 0.69 (N2) mol/kg at 5.8 bar and 313 K, which fitted with the dual-site Langmuir model. The linear-driving-force coefficients (LDFs) for CO2 and CH4 calculated from uptake rate experiments are in the order of 0.021-0.096 and 0.041-0.165 s-1 at 313 K between 0.11 and 2.76 bar, respectively. The Response Surface Methodology (RSM) was also applied to maximize the selectivity for mixtures CO2/CH4 and CO2/N2 with interest for BU or CCS. Breakthrough curve experiments with mixtures CO2/CH4 and CO2/N2 at the optimum selectivity conditions were developed and simulated using ASPEN Adsorption. This work clearly demonstrates the potential of MIL-160(Al) to be used in BU and/or CCS-related applications. |
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MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processesMetal-organic frameworksMolecular simulationGas-adsorptionCarbon captureSeparationWaterPerformanceDesignCH4AdsorbentsSeparationThe microporous bioderived Al dicarboxylate MIL-160(Al) MOF in its shaped form has been evaluated as a candidate for biogas upgrading (BU) and/or carbon capture and storage (CCS) by studying adsorption isotherms of CO2, CH4, and N2 at 313, 343, and 373 K until 8 bar. The isotherms disclosed the following loading capacities: 4.2 (CO2), 2.07 (CH4), and 0.69 (N2) mol/kg at 5.8 bar and 313 K, which fitted with the dual-site Langmuir model. The linear-driving-force coefficients (LDFs) for CO2 and CH4 calculated from uptake rate experiments are in the order of 0.021-0.096 and 0.041-0.165 s-1 at 313 K between 0.11 and 2.76 bar, respectively. The Response Surface Methodology (RSM) was also applied to maximize the selectivity for mixtures CO2/CH4 and CO2/N2 with interest for BU or CCS. Breakthrough curve experiments with mixtures CO2/CH4 and CO2/N2 at the optimum selectivity conditions were developed and simulated using ASPEN Adsorption. This work clearly demonstrates the potential of MIL-160(Al) to be used in BU and/or CCS-related applications.American Chemical SocietyBiblioteca Digital do IPBKarimi, MohsenFerreira, AlexandreRodrigues, AlírioNouar, FaridSerre, ChristianSilva, José A.C.2023-01-20T16:03:27Z20232023-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10198/26621engKarimi, Mohsen; Ferreira, Alexandre; Rodrigues, Alírio; Nouar, Farid; Serre, Christian; Silva, José A.C. (2023). MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes. Industrial & Engineering Chemistry Research. ISSN 0888-5885. 62:12, p. 5216-52290888-588510.1021/acs.iecr.2c04150info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-07T01:18:37Zoai:bibliotecadigital.ipb.pt:10198/26621Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T23:17:04.407401Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes |
title |
MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes |
spellingShingle |
MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes Karimi, Mohsen Metal-organic frameworks Molecular simulation Gas-adsorption Carbon capture Separation Water Performance Design CH4 Adsorbents Separation |
title_short |
MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes |
title_full |
MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes |
title_fullStr |
MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes |
title_full_unstemmed |
MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes |
title_sort |
MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes |
author |
Karimi, Mohsen |
author_facet |
Karimi, Mohsen Ferreira, Alexandre Rodrigues, Alírio Nouar, Farid Serre, Christian Silva, José A.C. |
author_role |
author |
author2 |
Ferreira, Alexandre Rodrigues, Alírio Nouar, Farid Serre, Christian Silva, José A.C. |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Biblioteca Digital do IPB |
dc.contributor.author.fl_str_mv |
Karimi, Mohsen Ferreira, Alexandre Rodrigues, Alírio Nouar, Farid Serre, Christian Silva, José A.C. |
dc.subject.por.fl_str_mv |
Metal-organic frameworks Molecular simulation Gas-adsorption Carbon capture Separation Water Performance Design CH4 Adsorbents Separation |
topic |
Metal-organic frameworks Molecular simulation Gas-adsorption Carbon capture Separation Water Performance Design CH4 Adsorbents Separation |
description |
The microporous bioderived Al dicarboxylate MIL-160(Al) MOF in its shaped form has been evaluated as a candidate for biogas upgrading (BU) and/or carbon capture and storage (CCS) by studying adsorption isotherms of CO2, CH4, and N2 at 313, 343, and 373 K until 8 bar. The isotherms disclosed the following loading capacities: 4.2 (CO2), 2.07 (CH4), and 0.69 (N2) mol/kg at 5.8 bar and 313 K, which fitted with the dual-site Langmuir model. The linear-driving-force coefficients (LDFs) for CO2 and CH4 calculated from uptake rate experiments are in the order of 0.021-0.096 and 0.041-0.165 s-1 at 313 K between 0.11 and 2.76 bar, respectively. The Response Surface Methodology (RSM) was also applied to maximize the selectivity for mixtures CO2/CH4 and CO2/N2 with interest for BU or CCS. Breakthrough curve experiments with mixtures CO2/CH4 and CO2/N2 at the optimum selectivity conditions were developed and simulated using ASPEN Adsorption. This work clearly demonstrates the potential of MIL-160(Al) to be used in BU and/or CCS-related applications. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-01-20T16:03:27Z 2023 2023-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10198/26621 |
url |
http://hdl.handle.net/10198/26621 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Karimi, Mohsen; Ferreira, Alexandre; Rodrigues, Alírio; Nouar, Farid; Serre, Christian; Silva, José A.C. (2023). MIL-160(Al) as a candidate for biogas upgrading and CO2 capture by adsorption processes. Industrial & Engineering Chemistry Research. ISSN 0888-5885. 62:12, p. 5216-5229 0888-5885 10.1021/acs.iecr.2c04150 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799135458133803008 |