Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronics

Detalhes bibliográficos
Autor(a) principal: Pinheiro, Tomás
Data de Publicação: 2022
Outros Autores: Correia, Ricardo, Morais, Maria, Coelho, João, Fortunato, Elvira, Sales, M. Goreti F., Marques, Ana C., Martins, Rodrigo
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/149347
Resumo: Publisher Copyright: © 2022 American Chemical Society.
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spelling Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronicselectrochemical sensorslaser-induced graphenemicrosupercapacitorspaperstrain sensorstransfer methodologieswearable electronicsMaterials Science(all)Engineering(all)Physics and Astronomy(all)Publisher Copyright: © 2022 American Chemical Society.Laser-induced graphene (LIG) has gained preponderance in recent years, as a very attractive material for the fabrication and patterning of graphitic structures and electrodes, for multiple applications in electronics. Typically, polymeric substrates, such as polyimide, have been used as precursor materials, but other organic, more sustainable, and accessible precursor materials have emerged as viable alternatives, including cellulose substrates. However, these substrates have lacked the conductive and chemical properties achieved by conventional LIG precursor substrates and have not been translated into fully flexible, wearable scenarios. In this work, we expand the conductive properties of paper-based LIG, by boosting the graphitization potential of paper, through the introduction of external aromatic moieties and meticulous control of laser fluence. Colored wax printing over the paper substrates introduces aromatic chemical structures, allowing for the synthesis of LIG chemical structures with sheet resistances as low as 5 ω·sq-1, translating to an apparent conductivity as high as 28.2 S·cm-1. Regarding chemical properties, ID/IG ratios of 0.28 showcase low defect densities of LIG chemical structures and improve on previous reports on paper-based LIG, where sheet resistance has been limited to values around 30 ω·sq-1, with more defect dense and less crystalline chemical structures. With these improved properties, a simple transfer methodology was developed, based on a water-induced peel-off process that efficiently separates patterned LIG structures from the native paper substrates to conformable, flexible substrates, harnessing the multifunctional capabilities of LIG toward multiple applications in wearable electronics. Proof-of concept electrodes for electrochemical sensors, strain sensors, and in-plane microsupercapacitors were patterned, transferred, and characterized, using paper as a high-value LIG precursor for multiples scenarios in wearable technologies, for improved sustainability and accessibility of such applications.DCM - Departamento de Ciência dos MateriaisCENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)UNINOVA-Instituto de Desenvolvimento de Novas TecnologiasRUNPinheiro, TomásCorreia, RicardoMorais, MariaCoelho, JoãoFortunato, ElviraSales, M. Goreti F.Marques, Ana C.Martins, Rodrigo2023-02-16T22:22:36Z2022-12-272022-12-27T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article14application/pdfhttp://hdl.handle.net/10362/149347eng1936-0851PURE: 53110778https://doi.org/10.1021/acsnano.2c07596info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:31:17Zoai:run.unl.pt:10362/149347Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:53:43.742902Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronics
title Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronics
spellingShingle Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronics
Pinheiro, Tomás
electrochemical sensors
laser-induced graphene
microsupercapacitors
paper
strain sensors
transfer methodologies
wearable electronics
Materials Science(all)
Engineering(all)
Physics and Astronomy(all)
title_short Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronics
title_full Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronics
title_fullStr Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronics
title_full_unstemmed Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronics
title_sort Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronics
author Pinheiro, Tomás
author_facet Pinheiro, Tomás
Correia, Ricardo
Morais, Maria
Coelho, João
Fortunato, Elvira
Sales, M. Goreti F.
Marques, Ana C.
Martins, Rodrigo
author_role author
author2 Correia, Ricardo
Morais, Maria
Coelho, João
Fortunato, Elvira
Sales, M. Goreti F.
Marques, Ana C.
Martins, Rodrigo
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv DCM - Departamento de Ciência dos Materiais
CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias
RUN
dc.contributor.author.fl_str_mv Pinheiro, Tomás
Correia, Ricardo
Morais, Maria
Coelho, João
Fortunato, Elvira
Sales, M. Goreti F.
Marques, Ana C.
Martins, Rodrigo
dc.subject.por.fl_str_mv electrochemical sensors
laser-induced graphene
microsupercapacitors
paper
strain sensors
transfer methodologies
wearable electronics
Materials Science(all)
Engineering(all)
Physics and Astronomy(all)
topic electrochemical sensors
laser-induced graphene
microsupercapacitors
paper
strain sensors
transfer methodologies
wearable electronics
Materials Science(all)
Engineering(all)
Physics and Astronomy(all)
description Publisher Copyright: © 2022 American Chemical Society.
publishDate 2022
dc.date.none.fl_str_mv 2022-12-27
2022-12-27T00:00:00Z
2023-02-16T22:22:36Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/149347
url http://hdl.handle.net/10362/149347
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1936-0851
PURE: 53110778
https://doi.org/10.1021/acsnano.2c07596
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 14
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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