Cure and performance of castor oil polyurethane adhesive
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/36971 |
Resumo: | iming at the development of sustainable materials, in this study, a biobased wood polyurethane adhesive (PUA), derived from castor oil (CO), was synthetized and its properties were compared with a conventional wood adhesive. Different NCO/OH ratios have been used to assess its effect on the properties of the ensuing adhesives. FTIR, and DMA were used to monitor the extent of reaction and the glass transition temperature of the adhesive, respectively. In turn, the wood bonding properties of the PUA over time were assessed by lap shear using pine wood specimens. Is was observed that the lap shear strength increases with the increase of the RNCO/OH up to RNCO/OH = 2.50. Above this ratio, the adhesive performance decreases slightly, due to the rigidity of the PUA. Comparison with a conventional wood adhesive showed that CO derived adhesives presented similar strength properties but required less time to develop the ultimate bonding strength. The chemical and thermal stability of the most promising CO adhesive was also assessed. Despite of being sensitive to the chemical environment, the castor oil derived adhesives presented higher thermal stability than conventional wood adhesives. Finally, the cure process of CO derived adhesives was studied by differential scanning calorimetry and the Kissinger and Ozawa methods were used to determine the activation energy (Ea). The former afforded a value for Ea = 80.55 and the latter Ea = 87.07 kJ mol−1. Moreover, it was observed that the activation energy is dependent on the degree of cure, increasing slightly up to 0.6 and decreasing significantly afterwards. |
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Cure and performance of castor oil polyurethane adhesiveAdhesives for woodPolyurethaneCureiming at the development of sustainable materials, in this study, a biobased wood polyurethane adhesive (PUA), derived from castor oil (CO), was synthetized and its properties were compared with a conventional wood adhesive. Different NCO/OH ratios have been used to assess its effect on the properties of the ensuing adhesives. FTIR, and DMA were used to monitor the extent of reaction and the glass transition temperature of the adhesive, respectively. In turn, the wood bonding properties of the PUA over time were assessed by lap shear using pine wood specimens. Is was observed that the lap shear strength increases with the increase of the RNCO/OH up to RNCO/OH = 2.50. Above this ratio, the adhesive performance decreases slightly, due to the rigidity of the PUA. Comparison with a conventional wood adhesive showed that CO derived adhesives presented similar strength properties but required less time to develop the ultimate bonding strength. The chemical and thermal stability of the most promising CO adhesive was also assessed. Despite of being sensitive to the chemical environment, the castor oil derived adhesives presented higher thermal stability than conventional wood adhesives. Finally, the cure process of CO derived adhesives was studied by differential scanning calorimetry and the Kissinger and Ozawa methods were used to determine the activation energy (Ea). The former afforded a value for Ea = 80.55 and the latter Ea = 87.07 kJ mol−1. Moreover, it was observed that the activation energy is dependent on the degree of cure, increasing slightly up to 0.6 and decreasing significantly afterwards.Elsevier2023-04-13T09:07:45Z2019-12-01T00:00:00Z2019-12info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/36971eng0143-749610.1016/j.ijadhadh.2019.102413Gama, NunoFerreira, ArturBarros-Timmons, Anainfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T12:11:19Zoai:ria.ua.pt:10773/36971Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:07:39.792277Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Cure and performance of castor oil polyurethane adhesive |
title |
Cure and performance of castor oil polyurethane adhesive |
spellingShingle |
Cure and performance of castor oil polyurethane adhesive Gama, Nuno Adhesives for wood Polyurethane Cure |
title_short |
Cure and performance of castor oil polyurethane adhesive |
title_full |
Cure and performance of castor oil polyurethane adhesive |
title_fullStr |
Cure and performance of castor oil polyurethane adhesive |
title_full_unstemmed |
Cure and performance of castor oil polyurethane adhesive |
title_sort |
Cure and performance of castor oil polyurethane adhesive |
author |
Gama, Nuno |
author_facet |
Gama, Nuno Ferreira, Artur Barros-Timmons, Ana |
author_role |
author |
author2 |
Ferreira, Artur Barros-Timmons, Ana |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Gama, Nuno Ferreira, Artur Barros-Timmons, Ana |
dc.subject.por.fl_str_mv |
Adhesives for wood Polyurethane Cure |
topic |
Adhesives for wood Polyurethane Cure |
description |
iming at the development of sustainable materials, in this study, a biobased wood polyurethane adhesive (PUA), derived from castor oil (CO), was synthetized and its properties were compared with a conventional wood adhesive. Different NCO/OH ratios have been used to assess its effect on the properties of the ensuing adhesives. FTIR, and DMA were used to monitor the extent of reaction and the glass transition temperature of the adhesive, respectively. In turn, the wood bonding properties of the PUA over time were assessed by lap shear using pine wood specimens. Is was observed that the lap shear strength increases with the increase of the RNCO/OH up to RNCO/OH = 2.50. Above this ratio, the adhesive performance decreases slightly, due to the rigidity of the PUA. Comparison with a conventional wood adhesive showed that CO derived adhesives presented similar strength properties but required less time to develop the ultimate bonding strength. The chemical and thermal stability of the most promising CO adhesive was also assessed. Despite of being sensitive to the chemical environment, the castor oil derived adhesives presented higher thermal stability than conventional wood adhesives. Finally, the cure process of CO derived adhesives was studied by differential scanning calorimetry and the Kissinger and Ozawa methods were used to determine the activation energy (Ea). The former afforded a value for Ea = 80.55 and the latter Ea = 87.07 kJ mol−1. Moreover, it was observed that the activation energy is dependent on the degree of cure, increasing slightly up to 0.6 and decreasing significantly afterwards. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-12-01T00:00:00Z 2019-12 2023-04-13T09:07:45Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/36971 |
url |
http://hdl.handle.net/10773/36971 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
0143-7496 10.1016/j.ijadhadh.2019.102413 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137731157164032 |