Effect of annealing temperature on structural, morphology and dielectric properties of La0.75Ba0.25FeO3 perovskite
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/37066 |
Resumo: | The effect of annealing temperature on the structure, morphology and dielectric properties of La0.75Ba0.25FeO3 compound prepared by the sol-gel method was investigated. The increase of the annealing temperature from 900 to 1100 °C, promotes an increase of the average grain size value. Two dielectric relaxations are detected using the dielectric modulus formalism, attributed to grain and grain boundary relaxations. This behavior was confirmed by both Nyquist and Argand's plots of dielectric impedance and Modulus results at different measuring temperatures. The ac conductivity could be described by Jonscher's power law revealing the presence of both overlapping large polaron tunneling and non-overlapping small polaron tunneling mechanisms. |
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Effect of annealing temperature on structural, morphology and dielectric properties of La0.75Ba0.25FeO3 perovskitePerovskiteSol-gelImpedance spectroscopyAnnealing effectAc conductivityThe effect of annealing temperature on the structure, morphology and dielectric properties of La0.75Ba0.25FeO3 compound prepared by the sol-gel method was investigated. The increase of the annealing temperature from 900 to 1100 °C, promotes an increase of the average grain size value. Two dielectric relaxations are detected using the dielectric modulus formalism, attributed to grain and grain boundary relaxations. This behavior was confirmed by both Nyquist and Argand's plots of dielectric impedance and Modulus results at different measuring temperatures. The ac conductivity could be described by Jonscher's power law revealing the presence of both overlapping large polaron tunneling and non-overlapping small polaron tunneling mechanisms.Elsevier2023-04-14T14:48:31Z2018-05-01T00:00:00Z2018-05info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/37066eng0749-603610.1016/j.spmi.2018.03.048Abdallah, F. B.Benali, A.Triki, M.Dhahri, E.Graça, M. P. F.Valente, M. A.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T12:11:29Zoai:ria.ua.pt:10773/37066Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:07:43.650733Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Effect of annealing temperature on structural, morphology and dielectric properties of La0.75Ba0.25FeO3 perovskite |
title |
Effect of annealing temperature on structural, morphology and dielectric properties of La0.75Ba0.25FeO3 perovskite |
spellingShingle |
Effect of annealing temperature on structural, morphology and dielectric properties of La0.75Ba0.25FeO3 perovskite Abdallah, F. B. Perovskite Sol-gel Impedance spectroscopy Annealing effect Ac conductivity |
title_short |
Effect of annealing temperature on structural, morphology and dielectric properties of La0.75Ba0.25FeO3 perovskite |
title_full |
Effect of annealing temperature on structural, morphology and dielectric properties of La0.75Ba0.25FeO3 perovskite |
title_fullStr |
Effect of annealing temperature on structural, morphology and dielectric properties of La0.75Ba0.25FeO3 perovskite |
title_full_unstemmed |
Effect of annealing temperature on structural, morphology and dielectric properties of La0.75Ba0.25FeO3 perovskite |
title_sort |
Effect of annealing temperature on structural, morphology and dielectric properties of La0.75Ba0.25FeO3 perovskite |
author |
Abdallah, F. B. |
author_facet |
Abdallah, F. B. Benali, A. Triki, M. Dhahri, E. Graça, M. P. F. Valente, M. A. |
author_role |
author |
author2 |
Benali, A. Triki, M. Dhahri, E. Graça, M. P. F. Valente, M. A. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Abdallah, F. B. Benali, A. Triki, M. Dhahri, E. Graça, M. P. F. Valente, M. A. |
dc.subject.por.fl_str_mv |
Perovskite Sol-gel Impedance spectroscopy Annealing effect Ac conductivity |
topic |
Perovskite Sol-gel Impedance spectroscopy Annealing effect Ac conductivity |
description |
The effect of annealing temperature on the structure, morphology and dielectric properties of La0.75Ba0.25FeO3 compound prepared by the sol-gel method was investigated. The increase of the annealing temperature from 900 to 1100 °C, promotes an increase of the average grain size value. Two dielectric relaxations are detected using the dielectric modulus formalism, attributed to grain and grain boundary relaxations. This behavior was confirmed by both Nyquist and Argand's plots of dielectric impedance and Modulus results at different measuring temperatures. The ac conductivity could be described by Jonscher's power law revealing the presence of both overlapping large polaron tunneling and non-overlapping small polaron tunneling mechanisms. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-05-01T00:00:00Z 2018-05 2023-04-14T14:48:31Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/37066 |
url |
http://hdl.handle.net/10773/37066 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
0749-6036 10.1016/j.spmi.2018.03.048 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137731669917696 |