Synthesis and characterization of dicarboxymethyl cellulose

Detalhes bibliográficos
Autor(a) principal: Chagas, Ricardo
Data de Publicação: 2020
Outros Autores: Gericke, Martin, Ferreira, Ricardo B., Heinze, Thomas, Ferreira, Luísa M.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/94102
Resumo: Associate Laboratory for Green Chemistry-LAQV which is financed by national funds from FCT/MCTES (UID/QUI/50006/2019). FCT, Portugal (ROTEIRO/0031/2013–PINFRA/22161/2016, co-financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC).
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spelling Synthesis and characterization of dicarboxymethyl celluloseCellulose etherCellulose functionalizationDicarboxymethyl celluloseHeterogeneous derivatizationPolymers and PlasticsAssociate Laboratory for Green Chemistry-LAQV which is financed by national funds from FCT/MCTES (UID/QUI/50006/2019). FCT, Portugal (ROTEIRO/0031/2013–PINFRA/22161/2016, co-financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC).Synthesis of dicarboxymethyl cellulose (DCMC) under heterogeneous conditions was examined. Cellulose was etherified using sodium bromomalonate in isopropanol/water in the presence of NaOH. The reaction was performed with five different NaOH concentrations (5–30 w/v %) and the products were characterized by anion-exchange high-performance liquid chromatography (AE-HPLC), inductively coupled plasma atomic emission- (ICP-AES), Fourier transform infrared- (FTIR), and nuclear magnetic resonance (1D-/2D-NMR) spectroscopy. Adjusting the amount of NaOH resulted in increasing functionalization of the cellulose achieving an average degree of substitution (DS) between 0.05 and 0.51. Both ICP-AES and AE-HPLC gave comparable DS values. NMR spectroscopic analysis showed that etherification occurred preferably at O-6 and, to a certain extent, at the secondary positions depending on the reaction conditions. Graphic abstract: [Figure not available: see fulltext.].CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)DCM - Departamento de Ciência dos MateriaisLAQV@REQUIMTERUNChagas, RicardoGericke, MartinFerreira, Ricardo B.Heinze, ThomasFerreira, Luísa M.2022-02-08T01:30:26Z2020-03-012020-03-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10362/94102eng0969-0239PURE: 16407388https://doi.org/10.1007/s10570-019-02952-6info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T04:42:11Zoai:run.unl.pt:10362/94102Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:37:53.684747Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Synthesis and characterization of dicarboxymethyl cellulose
title Synthesis and characterization of dicarboxymethyl cellulose
spellingShingle Synthesis and characterization of dicarboxymethyl cellulose
Chagas, Ricardo
Cellulose ether
Cellulose functionalization
Dicarboxymethyl cellulose
Heterogeneous derivatization
Polymers and Plastics
title_short Synthesis and characterization of dicarboxymethyl cellulose
title_full Synthesis and characterization of dicarboxymethyl cellulose
title_fullStr Synthesis and characterization of dicarboxymethyl cellulose
title_full_unstemmed Synthesis and characterization of dicarboxymethyl cellulose
title_sort Synthesis and characterization of dicarboxymethyl cellulose
author Chagas, Ricardo
author_facet Chagas, Ricardo
Gericke, Martin
Ferreira, Ricardo B.
Heinze, Thomas
Ferreira, Luísa M.
author_role author
author2 Gericke, Martin
Ferreira, Ricardo B.
Heinze, Thomas
Ferreira, Luísa M.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
DCM - Departamento de Ciência dos Materiais
LAQV@REQUIMTE
RUN
dc.contributor.author.fl_str_mv Chagas, Ricardo
Gericke, Martin
Ferreira, Ricardo B.
Heinze, Thomas
Ferreira, Luísa M.
dc.subject.por.fl_str_mv Cellulose ether
Cellulose functionalization
Dicarboxymethyl cellulose
Heterogeneous derivatization
Polymers and Plastics
topic Cellulose ether
Cellulose functionalization
Dicarboxymethyl cellulose
Heterogeneous derivatization
Polymers and Plastics
description Associate Laboratory for Green Chemistry-LAQV which is financed by national funds from FCT/MCTES (UID/QUI/50006/2019). FCT, Portugal (ROTEIRO/0031/2013–PINFRA/22161/2016, co-financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC).
publishDate 2020
dc.date.none.fl_str_mv 2020-03-01
2020-03-01T00:00:00Z
2022-02-08T01:30:26Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/94102
url http://hdl.handle.net/10362/94102
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0969-0239
PURE: 16407388
https://doi.org/10.1007/s10570-019-02952-6
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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