Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol
Autor(a) principal: | |
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Data de Publicação: | 2012 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.9/1916 |
Resumo: | Exploitation of neoteric solvents in the efficient total synthesis of carvacrol, an antimicrobial reagent, has been accomplished. The first reaction aimed supercritical mediated heterogeneous hydrogenation of carvone catalysed by palladium. The second step guided to an application of great salvation capacity of ionic liquids in separation of carvacrol from the post-hydrogenation mixture. The process has been completed by use of a high pressure CO2 potential to extract carvacrol from the ionic liquid reservoir. |
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Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrolHydrogenationSeparationExtractionCarvacrolSupercritical carbon dioxideIonic liquidsExploitation of neoteric solvents in the efficient total synthesis of carvacrol, an antimicrobial reagent, has been accomplished. The first reaction aimed supercritical mediated heterogeneous hydrogenation of carvone catalysed by palladium. The second step guided to an application of great salvation capacity of ionic liquids in separation of carvacrol from the post-hydrogenation mixture. The process has been completed by use of a high pressure CO2 potential to extract carvacrol from the ionic liquid reservoir.ElsevierRepositório do LNEGMelo, Catarina I.Lukasik, Rafal M.Bogel-Lukasik, Ewa2013-07-11T12:07:29Z2012-01-01T00:00:00Z2012-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.9/1916engMelo, Catarina I.; Bogel-Lukasik, R.; Bogel-Lukasik, E. Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol. In: The Journal of Supercritical Fluids, 2012, vol. 61, p. 191-1980896-8446info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2022-09-06T12:26:36Zoai:repositorio.lneg.pt:10400.9/1916Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T15:34:42.347614Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol |
title |
Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol |
spellingShingle |
Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol Melo, Catarina I. Hydrogenation Separation Extraction Carvacrol Supercritical carbon dioxide Ionic liquids |
title_short |
Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol |
title_full |
Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol |
title_fullStr |
Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol |
title_full_unstemmed |
Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol |
title_sort |
Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol |
author |
Melo, Catarina I. |
author_facet |
Melo, Catarina I. Lukasik, Rafal M. Bogel-Lukasik, Ewa |
author_role |
author |
author2 |
Lukasik, Rafal M. Bogel-Lukasik, Ewa |
author2_role |
author author |
dc.contributor.none.fl_str_mv |
Repositório do LNEG |
dc.contributor.author.fl_str_mv |
Melo, Catarina I. Lukasik, Rafal M. Bogel-Lukasik, Ewa |
dc.subject.por.fl_str_mv |
Hydrogenation Separation Extraction Carvacrol Supercritical carbon dioxide Ionic liquids |
topic |
Hydrogenation Separation Extraction Carvacrol Supercritical carbon dioxide Ionic liquids |
description |
Exploitation of neoteric solvents in the efficient total synthesis of carvacrol, an antimicrobial reagent, has been accomplished. The first reaction aimed supercritical mediated heterogeneous hydrogenation of carvone catalysed by palladium. The second step guided to an application of great salvation capacity of ionic liquids in separation of carvacrol from the post-hydrogenation mixture. The process has been completed by use of a high pressure CO2 potential to extract carvacrol from the ionic liquid reservoir. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-01-01T00:00:00Z 2012-01-01T00:00:00Z 2013-07-11T12:07:29Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.9/1916 |
url |
http://hdl.handle.net/10400.9/1916 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Melo, Catarina I.; Bogel-Lukasik, R.; Bogel-Lukasik, E. Combination of supercritical carbon dioxide and ionic liquid in a novel assembly of carvacrol. In: The Journal of Supercritical Fluids, 2012, vol. 61, p. 191-198 0896-8446 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799130211664527360 |