Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry

Detalhes bibliográficos
Autor(a) principal: Gabelica, Z.
Data de Publicação: 2004
Outros Autores: Louati, A., Borges, C., Ribeiro, M. F., Lourenço, J. P., Murphy, D. M.
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.1/1256
Resumo: Cyclic voltammetric experiments of framework Co(II) ions in three different CoAPO structures have provided evidence for a screening effect created by solvent or template molecules which results in a facile oxidation (and a difficult reduction) of the Co(II) ions incorporated into the most open (the less strained) structures. An apparent contradiction of these findings with respect to theoretical expectations is discussed.
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spelling Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetryCo incorporationSynthesisCyclic voltammetric experiments of framework Co(II) ions in three different CoAPO structures have provided evidence for a screening effect created by solvent or template molecules which results in a facile oxidation (and a difficult reduction) of the Co(II) ions incorporated into the most open (the less strained) structures. An apparent contradiction of these findings with respect to theoretical expectations is discussed.ElsevierSapientiaGabelica, Z.Louati, A.Borges, C.Ribeiro, M. F.Lourenço, J. P.Murphy, D. M.2012-06-15T14:29:40Z20042012-06-14T14:08:07Z2004-01-01T00:00:00Zconference objectinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10400.1/1256eng9780444518262AUT: JLO01215;info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-11-29T10:55:12Zoai:sapientia.ualg.pt:10400.1/1256Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-11-29T10:55:12Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry
title Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry
spellingShingle Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry
Gabelica, Z.
Co incorporation
Synthesis
title_short Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry
title_full Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry
title_fullStr Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry
title_full_unstemmed Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry
title_sort Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry
author Gabelica, Z.
author_facet Gabelica, Z.
Louati, A.
Borges, C.
Ribeiro, M. F.
Lourenço, J. P.
Murphy, D. M.
author_role author
author2 Louati, A.
Borges, C.
Ribeiro, M. F.
Lourenço, J. P.
Murphy, D. M.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Sapientia
dc.contributor.author.fl_str_mv Gabelica, Z.
Louati, A.
Borges, C.
Ribeiro, M. F.
Lourenço, J. P.
Murphy, D. M.
dc.subject.por.fl_str_mv Co incorporation
Synthesis
topic Co incorporation
Synthesis
description Cyclic voltammetric experiments of framework Co(II) ions in three different CoAPO structures have provided evidence for a screening effect created by solvent or template molecules which results in a facile oxidation (and a difficult reduction) of the Co(II) ions incorporated into the most open (the less strained) structures. An apparent contradiction of these findings with respect to theoretical expectations is discussed.
publishDate 2004
dc.date.none.fl_str_mv 2004
2004-01-01T00:00:00Z
2012-06-15T14:29:40Z
2012-06-14T14:08:07Z
dc.type.driver.fl_str_mv conference object
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.1/1256
url http://hdl.handle.net/10400.1/1256
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 9780444518262
AUT: JLO01215;
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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