Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate

Detalhes bibliográficos
Autor(a) principal: California, A.
Data de Publicação: 2011
Outros Autores: Cardoso, V. F., Costa, Carlos M., Sencadas, Vítor João Gomes Silva, Botelho, Gabriela, Gómez Ribelles, J. L., Lanceros-Méndez, S.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/15782
Resumo: Ferroelectric macroporous poly(vinylidene fluoride-trifuoroethylene) membranes have been produced by isothermal crystallization from the solution at different temperatures starting from different diluted solutions of the co-polymer in dimethylformamide. In this way pore architecture, consisting in interconnected spherical pores can be obtained. The mechanism and kinetics of solvent evaporation was investigated and related to the evolution of the polymer microstructure. The mechanism underlying the pattern formation has been discussed on the light of the Flory-Huggins (FH) lattice teory, grain boundary effects and the Cahn-Hilliard equation for mass conservation systems. It was also observed that the temperature or initial concentration of the crystallization process does not affect the phase, ferroelectric transition temperature or the melting temperature of the polymer.
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spelling Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rateElectroactive membranesPorous membranesPVDFSolvent evaporationPhase diagramScience & TechnologyFerroelectric macroporous poly(vinylidene fluoride-trifuoroethylene) membranes have been produced by isothermal crystallization from the solution at different temperatures starting from different diluted solutions of the co-polymer in dimethylformamide. In this way pore architecture, consisting in interconnected spherical pores can be obtained. The mechanism and kinetics of solvent evaporation was investigated and related to the evolution of the polymer microstructure. The mechanism underlying the pattern formation has been discussed on the light of the Flory-Huggins (FH) lattice teory, grain boundary effects and the Cahn-Hilliard equation for mass conservation systems. It was also observed that the temperature or initial concentration of the crystallization process does not affect the phase, ferroelectric transition temperature or the melting temperature of the polymer.Fundação para a Ciência e a Tecnologia (FCT) - PTDC/CTM-NAN/112574/2009, PTDC/CTM/73030/2006, PTDC/CTM/69316/2006, NANO/NMed-SD/0156/2007, SFRH/BD/44289/2008, SFRH/BD/68499/2010, SFRH/BPD/63148/2009Universidad Politécnica de Valencia - Programa de Apoyo a la Investigación y Desarrollo (PAID-00-09)Spanish Ministry of Science - MAT2010-21611-C03-01Conselleria de Sanidad (Generalitat Valenciana)Instituto de Salud Carlos IIIElsevierUniversidade do MinhoCalifornia, A.Cardoso, V. F.Costa, Carlos M.Sencadas, Vítor João Gomes SilvaBotelho, GabrielaGómez Ribelles, J. L.Lanceros-Méndez, S.20112011-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/15782eng0014-305710.1016/j.eurpolymj.2011.10.005http://www.sciencedirect.com/sinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:45:14Zoai:repositorium.sdum.uminho.pt:1822/15782Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:43:03.891757Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate
title Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate
spellingShingle Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate
California, A.
Electroactive membranes
Porous membranes
PVDF
Solvent evaporation
Phase diagram
Science & Technology
title_short Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate
title_full Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate
title_fullStr Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate
title_full_unstemmed Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate
title_sort Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate
author California, A.
author_facet California, A.
Cardoso, V. F.
Costa, Carlos M.
Sencadas, Vítor João Gomes Silva
Botelho, Gabriela
Gómez Ribelles, J. L.
Lanceros-Méndez, S.
author_role author
author2 Cardoso, V. F.
Costa, Carlos M.
Sencadas, Vítor João Gomes Silva
Botelho, Gabriela
Gómez Ribelles, J. L.
Lanceros-Méndez, S.
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv California, A.
Cardoso, V. F.
Costa, Carlos M.
Sencadas, Vítor João Gomes Silva
Botelho, Gabriela
Gómez Ribelles, J. L.
Lanceros-Méndez, S.
dc.subject.por.fl_str_mv Electroactive membranes
Porous membranes
PVDF
Solvent evaporation
Phase diagram
Science & Technology
topic Electroactive membranes
Porous membranes
PVDF
Solvent evaporation
Phase diagram
Science & Technology
description Ferroelectric macroporous poly(vinylidene fluoride-trifuoroethylene) membranes have been produced by isothermal crystallization from the solution at different temperatures starting from different diluted solutions of the co-polymer in dimethylformamide. In this way pore architecture, consisting in interconnected spherical pores can be obtained. The mechanism and kinetics of solvent evaporation was investigated and related to the evolution of the polymer microstructure. The mechanism underlying the pattern formation has been discussed on the light of the Flory-Huggins (FH) lattice teory, grain boundary effects and the Cahn-Hilliard equation for mass conservation systems. It was also observed that the temperature or initial concentration of the crystallization process does not affect the phase, ferroelectric transition temperature or the melting temperature of the polymer.
publishDate 2011
dc.date.none.fl_str_mv 2011
2011-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/15782
url http://hdl.handle.net/1822/15782
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0014-3057
10.1016/j.eurpolymj.2011.10.005
http://www.sciencedirect.com/s
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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