Shell pressure on the core of MnO/Mn3O4 core/shell nanoparticles
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | , , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/20102 |
Resumo: | Here we show that spontaneous oxidation of MnO nanoparticles into MnO/Mn3O4 core/shell nanoparticles has the effect of a local pressure, decreasing the MnO cell parameter and increasing strain, resulting in the increase of the MnO antiferromagnetic/paramagnetic transition temperature T-N. These effects are more severe in smaller nanoparticles. |
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Shell pressure on the core of MnO/Mn3O4 core/shell nanoparticlesMAGNETIC-PROPERTIESMNO NANOPARTICLESPHASE-TRANSITIONSSTRAINED SILICONNANOCRYSTALSEXCHANGEEMISSIONNANORODSFEOGPAHere we show that spontaneous oxidation of MnO nanoparticles into MnO/Mn3O4 core/shell nanoparticles has the effect of a local pressure, decreasing the MnO cell parameter and increasing strain, resulting in the increase of the MnO antiferromagnetic/paramagnetic transition temperature T-N. These effects are more severe in smaller nanoparticles.AMER PHYSICAL SOC2017-12-07T19:35:34Z2013-01-01T00:00:00Z2013info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/20102eng1098-012110.1103/PhysRevB.87.224429Silva, N. J. O.Karmaoui, M.Amaral, V. S.Puente-Orench, I.Campo, J.da Silva, I.Ibarra, A.Bustamante, R.Millan, A.Palacio, F.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T11:39:18Zoai:ria.ua.pt:10773/20102Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:54:48.322051Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Shell pressure on the core of MnO/Mn3O4 core/shell nanoparticles |
title |
Shell pressure on the core of MnO/Mn3O4 core/shell nanoparticles |
spellingShingle |
Shell pressure on the core of MnO/Mn3O4 core/shell nanoparticles Silva, N. J. O. MAGNETIC-PROPERTIES MNO NANOPARTICLES PHASE-TRANSITIONS STRAINED SILICON NANOCRYSTALS EXCHANGE EMISSION NANORODS FEO GPA |
title_short |
Shell pressure on the core of MnO/Mn3O4 core/shell nanoparticles |
title_full |
Shell pressure on the core of MnO/Mn3O4 core/shell nanoparticles |
title_fullStr |
Shell pressure on the core of MnO/Mn3O4 core/shell nanoparticles |
title_full_unstemmed |
Shell pressure on the core of MnO/Mn3O4 core/shell nanoparticles |
title_sort |
Shell pressure on the core of MnO/Mn3O4 core/shell nanoparticles |
author |
Silva, N. J. O. |
author_facet |
Silva, N. J. O. Karmaoui, M. Amaral, V. S. Puente-Orench, I. Campo, J. da Silva, I. Ibarra, A. Bustamante, R. Millan, A. Palacio, F. |
author_role |
author |
author2 |
Karmaoui, M. Amaral, V. S. Puente-Orench, I. Campo, J. da Silva, I. Ibarra, A. Bustamante, R. Millan, A. Palacio, F. |
author2_role |
author author author author author author author author author |
dc.contributor.author.fl_str_mv |
Silva, N. J. O. Karmaoui, M. Amaral, V. S. Puente-Orench, I. Campo, J. da Silva, I. Ibarra, A. Bustamante, R. Millan, A. Palacio, F. |
dc.subject.por.fl_str_mv |
MAGNETIC-PROPERTIES MNO NANOPARTICLES PHASE-TRANSITIONS STRAINED SILICON NANOCRYSTALS EXCHANGE EMISSION NANORODS FEO GPA |
topic |
MAGNETIC-PROPERTIES MNO NANOPARTICLES PHASE-TRANSITIONS STRAINED SILICON NANOCRYSTALS EXCHANGE EMISSION NANORODS FEO GPA |
description |
Here we show that spontaneous oxidation of MnO nanoparticles into MnO/Mn3O4 core/shell nanoparticles has the effect of a local pressure, decreasing the MnO cell parameter and increasing strain, resulting in the increase of the MnO antiferromagnetic/paramagnetic transition temperature T-N. These effects are more severe in smaller nanoparticles. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-01-01T00:00:00Z 2013 2017-12-07T19:35:34Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/20102 |
url |
http://hdl.handle.net/10773/20102 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1098-0121 10.1103/PhysRevB.87.224429 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
AMER PHYSICAL SOC |
publisher.none.fl_str_mv |
AMER PHYSICAL SOC |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137600672366592 |