Effect of Bathocuproine Concentration on the Photovoltaic Performance of NiOx-Based Perovskite Solar Cells

Detalhes bibliográficos
Autor(a) principal: Alishah, Hamed Moeini
Data de Publicação: 2021
Outros Autores: Choi, Fatma Pinar Gokdemir, Menda, Ugur Deneb, Kahveci, Cihangir, Rodop, Macide Canturk, Mendes, Manuel J., Gunes, Serap
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/130390
Resumo: FBA-2019-3583 NAP
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spelling Effect of Bathocuproine Concentration on the Photovoltaic Performance of NiOx-Based Perovskite Solar CellsBathocuproineElectron transport layerHole-blocking layerPlanar structureChemistry(all)SDG 7 - Affordable and Clean EnergyFBA-2019-3583 NAPBathocuproine (BCP) (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline) is a well-known material that is employed as a hole-blocking layer between electron transport layer (ETL) and metal electrode in perovskite solar cells. It has been demonstrated that the use of BCP as a buffer layer between the ETL and the metal electrode in perovskite solar cells is highly beneficial. In literature, BCP is coated using vacuum processing techniques. Vacuum processing techniques require more energy and cost-effective processing conditions. In this work, we used BCP layers processed through wet processing techniques using sol-gel method with different concentrations. We achieved a short circuit current density (Jsc) of 16.1 mA/cm2 and an open circuit voltage (Voc) of 875 mV were acquired and a fill factor (FF) of 0.37 was calculated for perovskite solar cells without a BCP layer leading to a power conversion efficiency (PCE) of 5.32 % whereas Jsc of 19 mA/cm2, Voc of 990 mV were achieved and a FF of 0.5 was calculated for perovskite solar cells employing BCP layers with concentration of 0.5 mg/ml and spin cast at 4000 rpm, leading to a PCE of 9.4 %. It has been observed that the use of a BCP layer with an optimized concentration led to an improved device performance with an increase of 77 % in PCE in ambient air under high humidity conditions for planar structure perovskite solar cells in the configuration of ITO/NiOx/MAPbI3/PCBM/BCP/Ag.DCM - Departamento de Ciência dos MateriaisCENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)UNINOVA-Instituto de Desenvolvimento de Novas TecnologiasRUNAlishah, Hamed MoeiniChoi, Fatma Pinar GokdemirMenda, Ugur DenebKahveci, CihangirRodop, Macide CanturkMendes, Manuel J.Gunes, Serap2022-01-06T23:52:25Z20212021-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article12application/pdfhttp://hdl.handle.net/10362/130390eng1870-249XPURE: 35839733https://doi.org/10.29356/jmcs.v65i2.1461info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T17:57:54Zoai:run.unl.pt:10362/130390Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T17:57:54Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Effect of Bathocuproine Concentration on the Photovoltaic Performance of NiOx-Based Perovskite Solar Cells
title Effect of Bathocuproine Concentration on the Photovoltaic Performance of NiOx-Based Perovskite Solar Cells
spellingShingle Effect of Bathocuproine Concentration on the Photovoltaic Performance of NiOx-Based Perovskite Solar Cells
Alishah, Hamed Moeini
Bathocuproine
Electron transport layer
Hole-blocking layer
Planar structure
Chemistry(all)
SDG 7 - Affordable and Clean Energy
title_short Effect of Bathocuproine Concentration on the Photovoltaic Performance of NiOx-Based Perovskite Solar Cells
title_full Effect of Bathocuproine Concentration on the Photovoltaic Performance of NiOx-Based Perovskite Solar Cells
title_fullStr Effect of Bathocuproine Concentration on the Photovoltaic Performance of NiOx-Based Perovskite Solar Cells
title_full_unstemmed Effect of Bathocuproine Concentration on the Photovoltaic Performance of NiOx-Based Perovskite Solar Cells
title_sort Effect of Bathocuproine Concentration on the Photovoltaic Performance of NiOx-Based Perovskite Solar Cells
author Alishah, Hamed Moeini
author_facet Alishah, Hamed Moeini
Choi, Fatma Pinar Gokdemir
Menda, Ugur Deneb
Kahveci, Cihangir
Rodop, Macide Canturk
Mendes, Manuel J.
Gunes, Serap
author_role author
author2 Choi, Fatma Pinar Gokdemir
Menda, Ugur Deneb
Kahveci, Cihangir
Rodop, Macide Canturk
Mendes, Manuel J.
Gunes, Serap
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv DCM - Departamento de Ciência dos Materiais
CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias
RUN
dc.contributor.author.fl_str_mv Alishah, Hamed Moeini
Choi, Fatma Pinar Gokdemir
Menda, Ugur Deneb
Kahveci, Cihangir
Rodop, Macide Canturk
Mendes, Manuel J.
Gunes, Serap
dc.subject.por.fl_str_mv Bathocuproine
Electron transport layer
Hole-blocking layer
Planar structure
Chemistry(all)
SDG 7 - Affordable and Clean Energy
topic Bathocuproine
Electron transport layer
Hole-blocking layer
Planar structure
Chemistry(all)
SDG 7 - Affordable and Clean Energy
description FBA-2019-3583 NAP
publishDate 2021
dc.date.none.fl_str_mv 2021
2021-01-01T00:00:00Z
2022-01-06T23:52:25Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/130390
url http://hdl.handle.net/10362/130390
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1870-249X
PURE: 35839733
https://doi.org/10.29356/jmcs.v65i2.1461
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 12
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
_version_ 1817545835906334720

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