Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.13/3266 |
Resumo: | A series of acid-activated clay catalysts were prepared from a purified bentonite, rich in structural iron, collected at Serra de Dentro on the island of Porto Santo. The purified bentonite exhibited a surface area of 130 m2 g 1 which increased to values as high as 500 m2 g 1 following activation with 4M HCl at 95 8C for 30 min (SD-4M-95-30). The ability of the activated samples to convert limonene to p-cymene was evaluated using a reaction time of 15 min at 80 8C. The sample prepared using 3M HCl at 95 8C for 30 min (SD-3M-95-30) offered the optimum combination of surface area (470 m2 g 1 ) and acidity (0.26 mmol g 1 ) and 95% of the limonene was converted to product. About 15% of the product mixture was p-cymene whilst non-volatile products and polymeric species made up 54% of the product mixture. The presence of iron in the octahedral sheet of the SD bentonite appears responsible for the dehydrogenation activity. TG–MS analysis of acid activated samples, saturated with cyclohexylamine, reflected the dehydrogenation capabilities of the catalysts in that SD-3M-95-30 produced the most benzene and aniline as decomposition/ transformation products. |
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Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentoniteAcid activated claysAcidityCatalysisLimonenep-Cymene.Faculdade de Ciências Exatas e da EngenhariaA series of acid-activated clay catalysts were prepared from a purified bentonite, rich in structural iron, collected at Serra de Dentro on the island of Porto Santo. The purified bentonite exhibited a surface area of 130 m2 g 1 which increased to values as high as 500 m2 g 1 following activation with 4M HCl at 95 8C for 30 min (SD-4M-95-30). The ability of the activated samples to convert limonene to p-cymene was evaluated using a reaction time of 15 min at 80 8C. The sample prepared using 3M HCl at 95 8C for 30 min (SD-3M-95-30) offered the optimum combination of surface area (470 m2 g 1 ) and acidity (0.26 mmol g 1 ) and 95% of the limonene was converted to product. About 15% of the product mixture was p-cymene whilst non-volatile products and polymeric species made up 54% of the product mixture. The presence of iron in the octahedral sheet of the SD bentonite appears responsible for the dehydrogenation activity. TG–MS analysis of acid activated samples, saturated with cyclohexylamine, reflected the dehydrogenation capabilities of the catalysts in that SD-3M-95-30 produced the most benzene and aniline as decomposition/ transformation products.ElsevierDigitUMaFernandes, C.Catrinescu, C.Castilho, P.Russo, P. A.Carrott, M. R.Breen, C.2021-04-09T10:25:03Z20072007-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.13/3266engFernandes, C., Catrinescu, C., Castilho, P., Russo, P. A., Carrott, M. R., & Breen, C. (2007). Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite. Applied Catalysis A: General, 318, 108-120.10.1016/j.apcata.2006.10.048info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-03-19T05:34:12Zoai:digituma.uma.pt:10400.13/3266Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T15:06:15.304349Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite |
title |
Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite |
spellingShingle |
Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite Fernandes, C. Acid activated clays Acidity Catalysis Limonene p-Cymene . Faculdade de Ciências Exatas e da Engenharia |
title_short |
Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite |
title_full |
Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite |
title_fullStr |
Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite |
title_full_unstemmed |
Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite |
title_sort |
Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite |
author |
Fernandes, C. |
author_facet |
Fernandes, C. Catrinescu, C. Castilho, P. Russo, P. A. Carrott, M. R. Breen, C. |
author_role |
author |
author2 |
Catrinescu, C. Castilho, P. Russo, P. A. Carrott, M. R. Breen, C. |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
DigitUMa |
dc.contributor.author.fl_str_mv |
Fernandes, C. Catrinescu, C. Castilho, P. Russo, P. A. Carrott, M. R. Breen, C. |
dc.subject.por.fl_str_mv |
Acid activated clays Acidity Catalysis Limonene p-Cymene . Faculdade de Ciências Exatas e da Engenharia |
topic |
Acid activated clays Acidity Catalysis Limonene p-Cymene . Faculdade de Ciências Exatas e da Engenharia |
description |
A series of acid-activated clay catalysts were prepared from a purified bentonite, rich in structural iron, collected at Serra de Dentro on the island of Porto Santo. The purified bentonite exhibited a surface area of 130 m2 g 1 which increased to values as high as 500 m2 g 1 following activation with 4M HCl at 95 8C for 30 min (SD-4M-95-30). The ability of the activated samples to convert limonene to p-cymene was evaluated using a reaction time of 15 min at 80 8C. The sample prepared using 3M HCl at 95 8C for 30 min (SD-3M-95-30) offered the optimum combination of surface area (470 m2 g 1 ) and acidity (0.26 mmol g 1 ) and 95% of the limonene was converted to product. About 15% of the product mixture was p-cymene whilst non-volatile products and polymeric species made up 54% of the product mixture. The presence of iron in the octahedral sheet of the SD bentonite appears responsible for the dehydrogenation activity. TG–MS analysis of acid activated samples, saturated with cyclohexylamine, reflected the dehydrogenation capabilities of the catalysts in that SD-3M-95-30 produced the most benzene and aniline as decomposition/ transformation products. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007 2007-01-01T00:00:00Z 2021-04-09T10:25:03Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.13/3266 |
url |
http://hdl.handle.net/10400.13/3266 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Fernandes, C., Catrinescu, C., Castilho, P., Russo, P. A., Carrott, M. R., & Breen, C. (2007). Catalytic conversion of limonene over acid activated Serra de Dentro (SD) bentonite. Applied Catalysis A: General, 318, 108-120. 10.1016/j.apcata.2006.10.048 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799129933480460288 |