Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flow

Detalhes bibliográficos
Autor(a) principal: Brett, Christopher M. A.
Data de Publicação: 1996
Outros Autores: Garcia, M. Beatriz Quinaz, Lima, José L. F. C.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/8304
https://doi.org/10.1002/elan.1140081219
Resumo: Square wave adsorptive stripping voltammetry (SWAdSV) of nickel and cobalt at wall-jet electrodes in a continuous flow system has been evaluated. Characteristics and advantages relative to differential pulse adsorptive stripping voltammetry (DPAdSV) in continuous flow systems are explored. Under optimized experimental conditions, sensitivity is approximately a factor of ten higher than DPAdSV, and one-nanomolar detection limits are achieved. Solution deoxygenation is unnecessary and sample throughput is increased.
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spelling Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flowSquare wave adsorptive stripping voltammetry (SWAdSV) of nickel and cobalt at wall-jet electrodes in a continuous flow system has been evaluated. Characteristics and advantages relative to differential pulse adsorptive stripping voltammetry (DPAdSV) in continuous flow systems are explored. Under optimized experimental conditions, sensitivity is approximately a factor of ten higher than DPAdSV, and one-nanomolar detection limits are achieved. Solution deoxygenation is unnecessary and sample throughput is increased.1996info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/8304http://hdl.handle.net/10316/8304https://doi.org/10.1002/elan.1140081219engElectroanalysis. 8:12 (1996) 1169-1173Brett, Christopher M. A.Garcia, M. Beatriz QuinazLima, José L. F. C.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2019-06-02T10:52:29Zoai:estudogeral.uc.pt:10316/8304Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:01:25.493578Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flow
title Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flow
spellingShingle Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flow
Brett, Christopher M. A.
title_short Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flow
title_full Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flow
title_fullStr Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flow
title_full_unstemmed Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flow
title_sort Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flow
author Brett, Christopher M. A.
author_facet Brett, Christopher M. A.
Garcia, M. Beatriz Quinaz
Lima, José L. F. C.
author_role author
author2 Garcia, M. Beatriz Quinaz
Lima, José L. F. C.
author2_role author
author
dc.contributor.author.fl_str_mv Brett, Christopher M. A.
Garcia, M. Beatriz Quinaz
Lima, José L. F. C.
description Square wave adsorptive stripping voltammetry (SWAdSV) of nickel and cobalt at wall-jet electrodes in a continuous flow system has been evaluated. Characteristics and advantages relative to differential pulse adsorptive stripping voltammetry (DPAdSV) in continuous flow systems are explored. Under optimized experimental conditions, sensitivity is approximately a factor of ten higher than DPAdSV, and one-nanomolar detection limits are achieved. Solution deoxygenation is unnecessary and sample throughput is increased.
publishDate 1996
dc.date.none.fl_str_mv 1996
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/8304
http://hdl.handle.net/10316/8304
https://doi.org/10.1002/elan.1140081219
url http://hdl.handle.net/10316/8304
https://doi.org/10.1002/elan.1140081219
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Electroanalysis. 8:12 (1996) 1169-1173
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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