A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa
Autor(a) principal: | |
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Data de Publicação: | 2004 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.13/3914 |
Resumo: | A novel high-pressure, ultrasonic cell of extremely reduced internal dimensions ( 0.8 10 6 m3) and good precision for the determination of the speed of propagation of sound in liquids was conceived and built. It makes use of a non-intrusive methodology where the ultrasonic transducers are not in direct contact with the liquid sample under investigation. The new cell was used to carry out speed of sound measurements in 2-propanone (acetone) in broad ranges of temperature (265 < T =K < 340) and pressure (0:1 < p=MPa < 160). (p; q; T ) data for acetone were also determined but in a narrower T ; p range (298 to 333 K; 0.1 to 60 MPa). In this interval, several thermodynamic properties were thus calculated, such as: isentropic (js) and isothermal (jTÞ compressibility, isobaric thermal expansivity (ap), isobaric (cp) and isochoric (cv) specific heat capacity, and the thermal pressure coefficient (cv). Comparisons with values found in the literature generally show good agreement. |
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A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPaSpeed of soundDensityPressure effects2-PropanoneAcetone.Faculdade de Ciências Exatas e da EngenhariaA novel high-pressure, ultrasonic cell of extremely reduced internal dimensions ( 0.8 10 6 m3) and good precision for the determination of the speed of propagation of sound in liquids was conceived and built. It makes use of a non-intrusive methodology where the ultrasonic transducers are not in direct contact with the liquid sample under investigation. The new cell was used to carry out speed of sound measurements in 2-propanone (acetone) in broad ranges of temperature (265 < T =K < 340) and pressure (0:1 < p=MPa < 160). (p; q; T ) data for acetone were also determined but in a narrower T ; p range (298 to 333 K; 0.1 to 60 MPa). In this interval, several thermodynamic properties were thus calculated, such as: isentropic (js) and isothermal (jTÞ compressibility, isobaric thermal expansivity (ap), isobaric (cp) and isochoric (cv) specific heat capacity, and the thermal pressure coefficient (cv). Comparisons with values found in the literature generally show good agreement.ElsevierDigitUMaAzevedo, R. Gomes deSzydlowski, J.Pires, P. F.Esperança, J. M. S. S.Guedes, H. J. R.Rebelo, L. P. N.2021-12-15T14:46:48Z20042004-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.13/3914engAzevedo, R. G., Szydlowski, J., Pires, P. F., Esperança, J. M. S. S., Guedes, H. J. R., & Rebelo, L. P. N. (2004). A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa. The Journal of Chemical Thermodynamics, 36(3), 211-222. https://doi.org/10.1016/j.jct.2003.12.00110.1016/j.jct.2003.12.001info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-10-29T06:43:45Zoai:digituma.uma.pt:10400.13/3914Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T15:07:29.241747Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa |
title |
A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa |
spellingShingle |
A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa Azevedo, R. Gomes de Speed of sound Density Pressure effects 2-Propanone Acetone . Faculdade de Ciências Exatas e da Engenharia |
title_short |
A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa |
title_full |
A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa |
title_fullStr |
A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa |
title_full_unstemmed |
A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa |
title_sort |
A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa |
author |
Azevedo, R. Gomes de |
author_facet |
Azevedo, R. Gomes de Szydlowski, J. Pires, P. F. Esperança, J. M. S. S. Guedes, H. J. R. Rebelo, L. P. N. |
author_role |
author |
author2 |
Szydlowski, J. Pires, P. F. Esperança, J. M. S. S. Guedes, H. J. R. Rebelo, L. P. N. |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
DigitUMa |
dc.contributor.author.fl_str_mv |
Azevedo, R. Gomes de Szydlowski, J. Pires, P. F. Esperança, J. M. S. S. Guedes, H. J. R. Rebelo, L. P. N. |
dc.subject.por.fl_str_mv |
Speed of sound Density Pressure effects 2-Propanone Acetone . Faculdade de Ciências Exatas e da Engenharia |
topic |
Speed of sound Density Pressure effects 2-Propanone Acetone . Faculdade de Ciências Exatas e da Engenharia |
description |
A novel high-pressure, ultrasonic cell of extremely reduced internal dimensions ( 0.8 10 6 m3) and good precision for the determination of the speed of propagation of sound in liquids was conceived and built. It makes use of a non-intrusive methodology where the ultrasonic transducers are not in direct contact with the liquid sample under investigation. The new cell was used to carry out speed of sound measurements in 2-propanone (acetone) in broad ranges of temperature (265 < T =K < 340) and pressure (0:1 < p=MPa < 160). (p; q; T ) data for acetone were also determined but in a narrower T ; p range (298 to 333 K; 0.1 to 60 MPa). In this interval, several thermodynamic properties were thus calculated, such as: isentropic (js) and isothermal (jTÞ compressibility, isobaric thermal expansivity (ap), isobaric (cp) and isochoric (cv) specific heat capacity, and the thermal pressure coefficient (cv). Comparisons with values found in the literature generally show good agreement. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004 2004-01-01T00:00:00Z 2021-12-15T14:46:48Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.13/3914 |
url |
http://hdl.handle.net/10400.13/3914 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Azevedo, R. G., Szydlowski, J., Pires, P. F., Esperança, J. M. S. S., Guedes, H. J. R., & Rebelo, L. P. N. (2004). A novel non-intrusive microcell for sound-speed measurements in liquids. Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa. The Journal of Chemical Thermodynamics, 36(3), 211-222. https://doi.org/10.1016/j.jct.2003.12.001 10.1016/j.jct.2003.12.001 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799129943715610624 |