Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements

Detalhes bibliográficos
Autor(a) principal: Auriemma, Finizia
Data de Publicação: 2018
Outros Autores: De Rosa, Claudio, Di Girolamo, Rocco, Malafronte, Anna, Scoti, Miriam, Mitchell, Geoffrey Robert, Esposito, Simona
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.8/8451
Resumo: The development of a highly oriented fiber morphology by effect of tensile deformation of stereodefective isotactic polypropylene (iPP) samples, starting from the unoriented form, is studied by following the transformation in real time during stretching through wide angle X-ray scattering (WAXS) measurements. In the stretching process, after yielding, the initial form transforms into the mesomorphic form of iPP through mechanical melting and re-crystallization. The analysis of the scattering invariant measured in theWAXS region highlights that the size of the mesomorphic domains included in the well oriented fiber morphology obtained at high deformations increases through a process which involves the coalescence of the small fragments formed by effect of tensile stress during lamellar destruction with the domain of higher dimensions.
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spelling Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurementsIsotactic polypropyleneStress-induced phase transitionsStructural analysisX-ray diffractionThe development of a highly oriented fiber morphology by effect of tensile deformation of stereodefective isotactic polypropylene (iPP) samples, starting from the unoriented form, is studied by following the transformation in real time during stretching through wide angle X-ray scattering (WAXS) measurements. In the stretching process, after yielding, the initial form transforms into the mesomorphic form of iPP through mechanical melting and re-crystallization. The analysis of the scattering invariant measured in theWAXS region highlights that the size of the mesomorphic domains included in the well oriented fiber morphology obtained at high deformations increases through a process which involves the coalescence of the small fragments formed by effect of tensile stress during lamellar destruction with the domain of higher dimensions.MDPIIC-OnlineAuriemma, FiniziaDe Rosa, ClaudioDi Girolamo, RoccoMalafronte, AnnaScoti, MiriamMitchell, Geoffrey RobertEsposito, Simona2023-04-24T13:16:28Z20182018-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.8/8451engAuriemma, F.; De Rosa, C.; Di Girolamo, R.; Malafronte, A.; Scoti, M.; Mitchell, G.R.; Esposito, S. Time-Resolving Study of Stress-Induced Transformations of Isotactic Polypropylene through Wide Angle X-ray Scattering Measurements. Polymers 2018, 10, 162. https://doi.org/10.3390/polym100201622073-436010.3390/polym10020162info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-01-17T15:57:21Zoai:iconline.ipleiria.pt:10400.8/8451Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T01:51:10.203363Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements
title Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements
spellingShingle Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements
Auriemma, Finizia
Isotactic polypropylene
Stress-induced phase transitions
Structural analysis
X-ray diffraction
title_short Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements
title_full Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements
title_fullStr Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements
title_full_unstemmed Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements
title_sort Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements
author Auriemma, Finizia
author_facet Auriemma, Finizia
De Rosa, Claudio
Di Girolamo, Rocco
Malafronte, Anna
Scoti, Miriam
Mitchell, Geoffrey Robert
Esposito, Simona
author_role author
author2 De Rosa, Claudio
Di Girolamo, Rocco
Malafronte, Anna
Scoti, Miriam
Mitchell, Geoffrey Robert
Esposito, Simona
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv IC-Online
dc.contributor.author.fl_str_mv Auriemma, Finizia
De Rosa, Claudio
Di Girolamo, Rocco
Malafronte, Anna
Scoti, Miriam
Mitchell, Geoffrey Robert
Esposito, Simona
dc.subject.por.fl_str_mv Isotactic polypropylene
Stress-induced phase transitions
Structural analysis
X-ray diffraction
topic Isotactic polypropylene
Stress-induced phase transitions
Structural analysis
X-ray diffraction
description The development of a highly oriented fiber morphology by effect of tensile deformation of stereodefective isotactic polypropylene (iPP) samples, starting from the unoriented form, is studied by following the transformation in real time during stretching through wide angle X-ray scattering (WAXS) measurements. In the stretching process, after yielding, the initial form transforms into the mesomorphic form of iPP through mechanical melting and re-crystallization. The analysis of the scattering invariant measured in theWAXS region highlights that the size of the mesomorphic domains included in the well oriented fiber morphology obtained at high deformations increases through a process which involves the coalescence of the small fragments formed by effect of tensile stress during lamellar destruction with the domain of higher dimensions.
publishDate 2018
dc.date.none.fl_str_mv 2018
2018-01-01T00:00:00Z
2023-04-24T13:16:28Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.8/8451
url http://hdl.handle.net/10400.8/8451
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Auriemma, F.; De Rosa, C.; Di Girolamo, R.; Malafronte, A.; Scoti, M.; Mitchell, G.R.; Esposito, S. Time-Resolving Study of Stress-Induced Transformations of Isotactic Polypropylene through Wide Angle X-ray Scattering Measurements. Polymers 2018, 10, 162. https://doi.org/10.3390/polym10020162
2073-4360
10.3390/polym10020162
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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