Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.8/8451 |
Resumo: | The development of a highly oriented fiber morphology by effect of tensile deformation of stereodefective isotactic polypropylene (iPP) samples, starting from the unoriented form, is studied by following the transformation in real time during stretching through wide angle X-ray scattering (WAXS) measurements. In the stretching process, after yielding, the initial form transforms into the mesomorphic form of iPP through mechanical melting and re-crystallization. The analysis of the scattering invariant measured in theWAXS region highlights that the size of the mesomorphic domains included in the well oriented fiber morphology obtained at high deformations increases through a process which involves the coalescence of the small fragments formed by effect of tensile stress during lamellar destruction with the domain of higher dimensions. |
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Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurementsIsotactic polypropyleneStress-induced phase transitionsStructural analysisX-ray diffractionThe development of a highly oriented fiber morphology by effect of tensile deformation of stereodefective isotactic polypropylene (iPP) samples, starting from the unoriented form, is studied by following the transformation in real time during stretching through wide angle X-ray scattering (WAXS) measurements. In the stretching process, after yielding, the initial form transforms into the mesomorphic form of iPP through mechanical melting and re-crystallization. The analysis of the scattering invariant measured in theWAXS region highlights that the size of the mesomorphic domains included in the well oriented fiber morphology obtained at high deformations increases through a process which involves the coalescence of the small fragments formed by effect of tensile stress during lamellar destruction with the domain of higher dimensions.MDPIIC-OnlineAuriemma, FiniziaDe Rosa, ClaudioDi Girolamo, RoccoMalafronte, AnnaScoti, MiriamMitchell, Geoffrey RobertEsposito, Simona2023-04-24T13:16:28Z20182018-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.8/8451engAuriemma, F.; De Rosa, C.; Di Girolamo, R.; Malafronte, A.; Scoti, M.; Mitchell, G.R.; Esposito, S. Time-Resolving Study of Stress-Induced Transformations of Isotactic Polypropylene through Wide Angle X-ray Scattering Measurements. Polymers 2018, 10, 162. https://doi.org/10.3390/polym100201622073-436010.3390/polym10020162info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-01-17T15:57:21Zoai:iconline.ipleiria.pt:10400.8/8451Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T01:51:10.203363Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements |
title |
Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements |
spellingShingle |
Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements Auriemma, Finizia Isotactic polypropylene Stress-induced phase transitions Structural analysis X-ray diffraction |
title_short |
Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements |
title_full |
Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements |
title_fullStr |
Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements |
title_full_unstemmed |
Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements |
title_sort |
Time-resolving study of stress-induced transformations of isotactic polypropylene through wide angle X-ray scattering measurements |
author |
Auriemma, Finizia |
author_facet |
Auriemma, Finizia De Rosa, Claudio Di Girolamo, Rocco Malafronte, Anna Scoti, Miriam Mitchell, Geoffrey Robert Esposito, Simona |
author_role |
author |
author2 |
De Rosa, Claudio Di Girolamo, Rocco Malafronte, Anna Scoti, Miriam Mitchell, Geoffrey Robert Esposito, Simona |
author2_role |
author author author author author author |
dc.contributor.none.fl_str_mv |
IC-Online |
dc.contributor.author.fl_str_mv |
Auriemma, Finizia De Rosa, Claudio Di Girolamo, Rocco Malafronte, Anna Scoti, Miriam Mitchell, Geoffrey Robert Esposito, Simona |
dc.subject.por.fl_str_mv |
Isotactic polypropylene Stress-induced phase transitions Structural analysis X-ray diffraction |
topic |
Isotactic polypropylene Stress-induced phase transitions Structural analysis X-ray diffraction |
description |
The development of a highly oriented fiber morphology by effect of tensile deformation of stereodefective isotactic polypropylene (iPP) samples, starting from the unoriented form, is studied by following the transformation in real time during stretching through wide angle X-ray scattering (WAXS) measurements. In the stretching process, after yielding, the initial form transforms into the mesomorphic form of iPP through mechanical melting and re-crystallization. The analysis of the scattering invariant measured in theWAXS region highlights that the size of the mesomorphic domains included in the well oriented fiber morphology obtained at high deformations increases through a process which involves the coalescence of the small fragments formed by effect of tensile stress during lamellar destruction with the domain of higher dimensions. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018 2018-01-01T00:00:00Z 2023-04-24T13:16:28Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.8/8451 |
url |
http://hdl.handle.net/10400.8/8451 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Auriemma, F.; De Rosa, C.; Di Girolamo, R.; Malafronte, A.; Scoti, M.; Mitchell, G.R.; Esposito, S. Time-Resolving Study of Stress-Induced Transformations of Isotactic Polypropylene through Wide Angle X-ray Scattering Measurements. Polymers 2018, 10, 162. https://doi.org/10.3390/polym10020162 2073-4360 10.3390/polym10020162 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
MDPI |
publisher.none.fl_str_mv |
MDPI |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137003517771776 |