“In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol

Detalhes bibliográficos
Autor(a) principal: Zhao, Xiaoman
Data de Publicação: 2018
Outros Autores: Noro, Jennifer Martins, Fu, Jiajia, Wang, Hongbo, Silva, C., Cavaco-Paulo, Artur
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/51458
Resumo: "Available online 12 January 2018"
id RCAP_ae87403246797bb9a51cfd455534cf94
oai_identifier_str oai:repositorium.sdum.uminho.pt:1822/51458
network_acronym_str RCAP
network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str 7160
spelling “In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerolImmobilized Candida antarctica lipase BPolymerizationConversion rateLipase from Thermomyces lanuginosusIn situ lipase-catalyzed polymerizationCottonScience & Technology"Available online 12 January 2018"Several polyesters were synthesized from ethylene glycol, glycerol and adipate, succinate dimethyl esters. Immobilized Candida antarctica lipase B was used as catalyst for 6hours under vacuum at 70°C without any further solvents. The highest conversion rate of 88.5% occurred for the polymerization of poly (ethylene adipate), evaluated by 1H NMR. MALDI-TOF analysis indicated that most of the oligomers formed were dimers or trimers. After successfully synthesize the polyesters we set-up the optimal conditions for their in-situ coating onto cotton substrates with a soluble lipase from Thermomyces lanuginosus. This work presents a novel bio-approach to impart hydrophobic properties to coated cotton-based fiber materials.This work was supported by Chinese government scholarship under the State Scholarship Fund (grant number 201706790049), Jiangsu Province Scientific Research Innovation Project for Academic Graduate Students (grant number KYLX16_0788), Training Fund for Excellent Doctoral Student in Jiangnan University, Key Projects of governmental cooperation in international scientific and technological innovation (grant number 2016 YFE0115700) and the National Key R & D Program of China (grant number 2017 YFB0309100). This work was also supported by the Portuguese Foundation for Science and Technology (FCT) under the scope of the strategic funding of UID/BIO/04469/2013 unit and COMPETE 2020 (grant number POCI-01-0145-FEDER-006684) and under the Project RECI/BBB-EBI/0179/2012 (grant number FCOMP01-0124-FEDER-027462). This study was also supported by BioTecNorte operation (grant number NORTE-01-0145-FEDER000004) funded by the European Regional Development Fund under the scope of Norte2020 – Programa Operacional Regional do Norte. This work was also supported by the National Natural Science Foundation of China (grant number 31470509 and 31201134), the Industry-Academic Joint Technological Prospective Fund Project of Jiangsu Province (grant number BY2013015-24 and BY2016022-23), the fundamental research funds for the central universities (grant number JUSRP 51622A), and a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions.info:eu-repo/semantics/publishedVersionElsevierUniversidade do MinhoZhao, XiaomanNoro, Jennifer MartinsFu, JiajiaWang, HongboSilva, C.Cavaco-Paulo, Artur2018-032018-03-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/51458engZhao, Xiaoman; Jennifer Noro; Fu, Jiajia; Wang, Hongbo; Silva, Carla; Cavaco-Paulo, Artur, "In-situ" lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol.1359-51131873-329810.1016/j.procbio.2018.01.002http://www.journals.elsevier.com/process-biochemistry/info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:45:40Zoai:repositorium.sdum.uminho.pt:1822/51458Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:43:32.747320Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv “In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol
title “In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol
spellingShingle “In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol
Zhao, Xiaoman
Immobilized Candida antarctica lipase B
Polymerization
Conversion rate
Lipase from Thermomyces lanuginosus
In situ lipase-catalyzed polymerization
Cotton
Science & Technology
title_short “In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol
title_full “In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol
title_fullStr “In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol
title_full_unstemmed “In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol
title_sort “In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol
author Zhao, Xiaoman
author_facet Zhao, Xiaoman
Noro, Jennifer Martins
Fu, Jiajia
Wang, Hongbo
Silva, C.
Cavaco-Paulo, Artur
author_role author
author2 Noro, Jennifer Martins
Fu, Jiajia
Wang, Hongbo
Silva, C.
Cavaco-Paulo, Artur
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Zhao, Xiaoman
Noro, Jennifer Martins
Fu, Jiajia
Wang, Hongbo
Silva, C.
Cavaco-Paulo, Artur
dc.subject.por.fl_str_mv Immobilized Candida antarctica lipase B
Polymerization
Conversion rate
Lipase from Thermomyces lanuginosus
In situ lipase-catalyzed polymerization
Cotton
Science & Technology
topic Immobilized Candida antarctica lipase B
Polymerization
Conversion rate
Lipase from Thermomyces lanuginosus
In situ lipase-catalyzed polymerization
Cotton
Science & Technology
description "Available online 12 January 2018"
publishDate 2018
dc.date.none.fl_str_mv 2018-03
2018-03-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/51458
url http://hdl.handle.net/1822/51458
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Zhao, Xiaoman; Jennifer Noro; Fu, Jiajia; Wang, Hongbo; Silva, Carla; Cavaco-Paulo, Artur, "In-situ" lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol.
1359-5113
1873-3298
10.1016/j.procbio.2018.01.002
http://www.journals.elsevier.com/process-biochemistry/
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
_version_ 1799132993144487936

Registros relacionados