Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production

Detalhes bibliográficos
Autor(a) principal: Roze, Frédéric
Data de Publicação: 2021
Outros Autores: Pignat, Patrice, Ferreira, Olga, Pinho, Simão, Jaubert, Jean-Noël, Coniglio, Lucie
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10198/23841
Resumo: The aim of this paper is to bring valuable phase equilibria information for the design and operation of biolubricant and related biofuel product processes. As a result, Vapor-Liquid Equilibrium (VLE) measurements, at different temperatures, pressures and global compositions, for the ternary systems [Ethanol + 2-Ethyl-1-hexanol + 1-Dodecanol] and [Ethanol + 1-Octanol + 1-Dodecanol], as well as a multicomponent system containing these alcohols together with Balanites aegyptiaca fatty acid ethyl esters are reported for the first time (data pressure and temperature ranges: 4394–26790 Pa, 306–423 K). The Dortmund modified UNIFAC model showed very high accuracy in the prediction of these VLE, with overall average absolute deviations on the liquid and vapor molar compositions of 0.007 and 0.0003 for the ternary systems, 0.003 and 0.006 for the multicomponent system.
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spelling Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct productionVapor-liquid equilibriaMulticomponent systemsEbulliometryDortmund modified UNIFACBiodieselBiolubricantsThe aim of this paper is to bring valuable phase equilibria information for the design and operation of biolubricant and related biofuel product processes. As a result, Vapor-Liquid Equilibrium (VLE) measurements, at different temperatures, pressures and global compositions, for the ternary systems [Ethanol + 2-Ethyl-1-hexanol + 1-Dodecanol] and [Ethanol + 1-Octanol + 1-Dodecanol], as well as a multicomponent system containing these alcohols together with Balanites aegyptiaca fatty acid ethyl esters are reported for the first time (data pressure and temperature ranges: 4394–26790 Pa, 306–423 K). The Dortmund modified UNIFAC model showed very high accuracy in the prediction of these VLE, with overall average absolute deviations on the liquid and vapor molar compositions of 0.007 and 0.0003 for the ternary systems, 0.003 and 0.006 for the multicomponent system.The authors express their acknowledgments to the ENSIC students who contributed to this work through their Master 1 training. S.P.P. thanks support to project CIMO-Mountain Research Center, UIDB/00690/2020, financed by national funds through the Portuguese Foundation for Science and Technology/MCTES.Biblioteca Digital do IPBRoze, FrédéricPignat, PatriceFerreira, OlgaPinho, SimãoJaubert, Jean-NoëlConiglio, Lucie2021-08-31T10:28:35Z20212021-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10198/23841engRoze, Frédéric; Pignat, Patrice; Ferreira, Olga: Pinho, Simão; Jaubert, Jean-Noël; Coniglio, Lucie (2021). Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production. Fuel. ISSN 0016-2361. 306, p. 1-90016-236110.1016/j.fuel.2021.121304info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-11-21T10:53:19Zoai:bibliotecadigital.ipb.pt:10198/23841Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T23:14:46.638140Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production
title Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production
spellingShingle Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production
Roze, Frédéric
Vapor-liquid equilibria
Multicomponent systems
Ebulliometry
Dortmund modified UNIFAC
Biodiesel
Biolubricants
title_short Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production
title_full Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production
title_fullStr Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production
title_full_unstemmed Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production
title_sort Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production
author Roze, Frédéric
author_facet Roze, Frédéric
Pignat, Patrice
Ferreira, Olga
Pinho, Simão
Jaubert, Jean-Noël
Coniglio, Lucie
author_role author
author2 Pignat, Patrice
Ferreira, Olga
Pinho, Simão
Jaubert, Jean-Noël
Coniglio, Lucie
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Biblioteca Digital do IPB
dc.contributor.author.fl_str_mv Roze, Frédéric
Pignat, Patrice
Ferreira, Olga
Pinho, Simão
Jaubert, Jean-Noël
Coniglio, Lucie
dc.subject.por.fl_str_mv Vapor-liquid equilibria
Multicomponent systems
Ebulliometry
Dortmund modified UNIFAC
Biodiesel
Biolubricants
topic Vapor-liquid equilibria
Multicomponent systems
Ebulliometry
Dortmund modified UNIFAC
Biodiesel
Biolubricants
description The aim of this paper is to bring valuable phase equilibria information for the design and operation of biolubricant and related biofuel product processes. As a result, Vapor-Liquid Equilibrium (VLE) measurements, at different temperatures, pressures and global compositions, for the ternary systems [Ethanol + 2-Ethyl-1-hexanol + 1-Dodecanol] and [Ethanol + 1-Octanol + 1-Dodecanol], as well as a multicomponent system containing these alcohols together with Balanites aegyptiaca fatty acid ethyl esters are reported for the first time (data pressure and temperature ranges: 4394–26790 Pa, 306–423 K). The Dortmund modified UNIFAC model showed very high accuracy in the prediction of these VLE, with overall average absolute deviations on the liquid and vapor molar compositions of 0.007 and 0.0003 for the ternary systems, 0.003 and 0.006 for the multicomponent system.
publishDate 2021
dc.date.none.fl_str_mv 2021-08-31T10:28:35Z
2021
2021-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10198/23841
url http://hdl.handle.net/10198/23841
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Roze, Frédéric; Pignat, Patrice; Ferreira, Olga: Pinho, Simão; Jaubert, Jean-Noël; Coniglio, Lucie (2021). Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production. Fuel. ISSN 0016-2361. 306, p. 1-9
0016-2361
10.1016/j.fuel.2021.121304
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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