Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10316/27391 https://doi.org/10.1016/j.jelechem.2013.06.017 |
Resumo: | In this study, a new inorganic–organic hybrid compound consisting of a Keggin type polyoxometalate, H4SiW12O40 (SiW12), and Nile blue (NB) was synthesized and characterized. The (NB)2H2SiW12O40 (NB2SiW12) hybrid compound was characterized by Fourier transform infrared (FT-IR), elemental (CHNS) analysis, UV–Vis and thermogravimetry techniques, and used as a bulk modifier to fabricate a chemically modified carbon paste electrode (CPE) by direct mixing. The electrochemical behavior of the newly NB2SiW12 composite CPE was analyzed by cyclic voltammetry, and the electrode was applied for nitrite reduction, exhibiting high electrocatalytic activity. Determination of nitrite by fixed potential amperometry was done under various experimental conditions and, at the optimum conditions, the linear response ranged from 5 to 1200 μM with a high sensitivity of and a low detection limit. The electrode has the remarkable advantage of surface renewal owing to bulk modification, as well as simple preparation, good mechanical and chemical stability and reproducibility. No noticeable interferences from other ionic species usually found in natural water were observed. The new developed electrode has been successfully applied for detection of nitrite in real water samples. |
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Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reductionCarbon paste electrodeComposite electrodeInorganic–organic hybrid compoundPolyoxometalateNile blueNitriteIn this study, a new inorganic–organic hybrid compound consisting of a Keggin type polyoxometalate, H4SiW12O40 (SiW12), and Nile blue (NB) was synthesized and characterized. The (NB)2H2SiW12O40 (NB2SiW12) hybrid compound was characterized by Fourier transform infrared (FT-IR), elemental (CHNS) analysis, UV–Vis and thermogravimetry techniques, and used as a bulk modifier to fabricate a chemically modified carbon paste electrode (CPE) by direct mixing. The electrochemical behavior of the newly NB2SiW12 composite CPE was analyzed by cyclic voltammetry, and the electrode was applied for nitrite reduction, exhibiting high electrocatalytic activity. Determination of nitrite by fixed potential amperometry was done under various experimental conditions and, at the optimum conditions, the linear response ranged from 5 to 1200 μM with a high sensitivity of and a low detection limit. The electrode has the remarkable advantage of surface renewal owing to bulk modification, as well as simple preparation, good mechanical and chemical stability and reproducibility. No noticeable interferences from other ionic species usually found in natural water were observed. The new developed electrode has been successfully applied for detection of nitrite in real water samples.Elsevier2013-09-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/27391http://hdl.handle.net/10316/27391https://doi.org/10.1016/j.jelechem.2013.06.017engKAKHKI, Somayeh; SHAMS, Esmaeil; BARSAN, Madalina M. - Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction. "Journal of Electroanalytical Chemistry". ISSN 1572-6657. Vol. 704 (2013) p. 80-851572-6657http://www.sciencedirect.com/science/article/pii/S1572665713002919Kakhki, SomayehShams, EsmaeilBarsan, Madalina M.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2020-05-25T13:17:40Zoai:estudogeral.uc.pt:10316/27391Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:01:48.727736Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction |
title |
Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction |
spellingShingle |
Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction Kakhki, Somayeh Carbon paste electrode Composite electrode Inorganic–organic hybrid compound Polyoxometalate Nile blue Nitrite |
title_short |
Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction |
title_full |
Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction |
title_fullStr |
Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction |
title_full_unstemmed |
Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction |
title_sort |
Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction |
author |
Kakhki, Somayeh |
author_facet |
Kakhki, Somayeh Shams, Esmaeil Barsan, Madalina M. |
author_role |
author |
author2 |
Shams, Esmaeil Barsan, Madalina M. |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Kakhki, Somayeh Shams, Esmaeil Barsan, Madalina M. |
dc.subject.por.fl_str_mv |
Carbon paste electrode Composite electrode Inorganic–organic hybrid compound Polyoxometalate Nile blue Nitrite |
topic |
Carbon paste electrode Composite electrode Inorganic–organic hybrid compound Polyoxometalate Nile blue Nitrite |
description |
In this study, a new inorganic–organic hybrid compound consisting of a Keggin type polyoxometalate, H4SiW12O40 (SiW12), and Nile blue (NB) was synthesized and characterized. The (NB)2H2SiW12O40 (NB2SiW12) hybrid compound was characterized by Fourier transform infrared (FT-IR), elemental (CHNS) analysis, UV–Vis and thermogravimetry techniques, and used as a bulk modifier to fabricate a chemically modified carbon paste electrode (CPE) by direct mixing. The electrochemical behavior of the newly NB2SiW12 composite CPE was analyzed by cyclic voltammetry, and the electrode was applied for nitrite reduction, exhibiting high electrocatalytic activity. Determination of nitrite by fixed potential amperometry was done under various experimental conditions and, at the optimum conditions, the linear response ranged from 5 to 1200 μM with a high sensitivity of and a low detection limit. The electrode has the remarkable advantage of surface renewal owing to bulk modification, as well as simple preparation, good mechanical and chemical stability and reproducibility. No noticeable interferences from other ionic species usually found in natural water were observed. The new developed electrode has been successfully applied for detection of nitrite in real water samples. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-09-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10316/27391 http://hdl.handle.net/10316/27391 https://doi.org/10.1016/j.jelechem.2013.06.017 |
url |
http://hdl.handle.net/10316/27391 https://doi.org/10.1016/j.jelechem.2013.06.017 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
KAKHKI, Somayeh; SHAMS, Esmaeil; BARSAN, Madalina M. - Fabrication of carbon paste electrode containing a new inorganic–organic hybrid based on [SiW12O40]4− polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction. "Journal of Electroanalytical Chemistry". ISSN 1572-6657. Vol. 704 (2013) p. 80-85 1572-6657 http://www.sciencedirect.com/science/article/pii/S1572665713002919 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799133908789362688 |