Electrochemical Synthesis of Zinc(II) Phenoxides and their Coordination Compounds

Detalhes bibliográficos
Autor(a) principal: Banait,J.S.
Data de Publicação: 2007
Outros Autores: Singh,B., Kaur,H.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000400005
Resumo: Electrochemical oxidation of phenol, 4-aminophenol, 2-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol, 2-hydroxybenzoic acid, 2-tert-butylphenol and 2-tert-butyl-4-methoxyphenol has been carried out at sacrificial zinc anode. The products of these reactions have been identified by elemental analysis and infrared spectral data and are found to be zinc(II) phenoxides. Though these compounds do not form coordination compounds on refluxing with 1,10-phenanthroline or 2,2'-bipyridyl, yet the coordination compounds of these phenoxides with these ligands have been synthesized electrochemically. Current efficiencies of these systems are quite high.
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spelling Electrochemical Synthesis of Zinc(II) Phenoxides and their Coordination Compoundselectrochemical synthesissacrificial zinc anodephenoxidescoordination compounds and current efficienciesElectrochemical oxidation of phenol, 4-aminophenol, 2-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol, 2-hydroxybenzoic acid, 2-tert-butylphenol and 2-tert-butyl-4-methoxyphenol has been carried out at sacrificial zinc anode. The products of these reactions have been identified by elemental analysis and infrared spectral data and are found to be zinc(II) phenoxides. Though these compounds do not form coordination compounds on refluxing with 1,10-phenanthroline or 2,2'-bipyridyl, yet the coordination compounds of these phenoxides with these ligands have been synthesized electrochemically. Current efficiencies of these systems are quite high.Sociedade Portuguesa de Electroquímica2007-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000400005Portugaliae Electrochimica Acta v.25 n.4 2007reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000400005Banait,J.S.Singh,B.Kaur,H.info:eu-repo/semantics/openAccess2024-02-06T17:06:53Zoai:scielo:S0872-19042007000400005Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:03.210569Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Electrochemical Synthesis of Zinc(II) Phenoxides and their Coordination Compounds
title Electrochemical Synthesis of Zinc(II) Phenoxides and their Coordination Compounds
spellingShingle Electrochemical Synthesis of Zinc(II) Phenoxides and their Coordination Compounds
Banait,J.S.
electrochemical synthesis
sacrificial zinc anode
phenoxides
coordination compounds and current efficiencies
title_short Electrochemical Synthesis of Zinc(II) Phenoxides and their Coordination Compounds
title_full Electrochemical Synthesis of Zinc(II) Phenoxides and their Coordination Compounds
title_fullStr Electrochemical Synthesis of Zinc(II) Phenoxides and their Coordination Compounds
title_full_unstemmed Electrochemical Synthesis of Zinc(II) Phenoxides and their Coordination Compounds
title_sort Electrochemical Synthesis of Zinc(II) Phenoxides and their Coordination Compounds
author Banait,J.S.
author_facet Banait,J.S.
Singh,B.
Kaur,H.
author_role author
author2 Singh,B.
Kaur,H.
author2_role author
author
dc.contributor.author.fl_str_mv Banait,J.S.
Singh,B.
Kaur,H.
dc.subject.por.fl_str_mv electrochemical synthesis
sacrificial zinc anode
phenoxides
coordination compounds and current efficiencies
topic electrochemical synthesis
sacrificial zinc anode
phenoxides
coordination compounds and current efficiencies
description Electrochemical oxidation of phenol, 4-aminophenol, 2-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol, 2-hydroxybenzoic acid, 2-tert-butylphenol and 2-tert-butyl-4-methoxyphenol has been carried out at sacrificial zinc anode. The products of these reactions have been identified by elemental analysis and infrared spectral data and are found to be zinc(II) phenoxides. Though these compounds do not form coordination compounds on refluxing with 1,10-phenanthroline or 2,2'-bipyridyl, yet the coordination compounds of these phenoxides with these ligands have been synthesized electrochemically. Current efficiencies of these systems are quite high.
publishDate 2007
dc.date.none.fl_str_mv 2007-01-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000400005
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000400005
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000400005
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
dc.source.none.fl_str_mv Portugaliae Electrochimica Acta v.25 n.4 2007
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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