Structural study and large magnetocaloric entropy change at room temperature of La1-x □ x MnO3 compounds
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10316/106688 https://doi.org/10.1039/c9ra10469k |
Resumo: | In this study, our central focus is to investigate the magnetocaloric characteristics of a La1-x □ x MnO3 (x = 0.1, 0.2 and 0.3) series prepared by a sol-gel technique published in Prog. Mater. Sci., 93, 2018, 112-232. The crystallographic study revealed that our compounds crystallize in a rhombohedral structure with R3̄c. Ferromagnetic (FM) and paramagnetic (PM) characters were detected from the variation in magnetization as a function of magnetic fields at different temperatures. The second order transition was verified from the Arrott plots (M 2 vs. (μ 0 H/M)), where the slopes have a positive value. In order to verify the second order, we traced the variation of magnetization vs. temperature at different magnetic fields for x = 0.2. This revealed a ferromagnetic (FM)-paramagnetic (PM) transition when temperature increases. Relying on the indirect method while using the Maxwell formula, we determined the variation in the entropy (-ΔS M) as a function of temperature for different magnetic fields for the three samples. We note that all the studied systems stand as good candidates for magnetic refrigeration with relative cooling power (RCP) values of around 131.4, 83.38 and 57.26 J kg-1 with magnetic fields below 2 T, respectively. Subsequently, the magnetocaloric effect was investigated by a phenomenological model for x = 0.2. The extracted data confirm that this phenomenological model is appropriate for the prediction of magnetocaloric properties. The study also demonstrated that this La0.8□0.2MnO3 system exhibits a universal behaviour. |
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Structural study and large magnetocaloric entropy change at room temperature of La1-x □ x MnO3 compoundsIn this study, our central focus is to investigate the magnetocaloric characteristics of a La1-x □ x MnO3 (x = 0.1, 0.2 and 0.3) series prepared by a sol-gel technique published in Prog. Mater. Sci., 93, 2018, 112-232. The crystallographic study revealed that our compounds crystallize in a rhombohedral structure with R3̄c. Ferromagnetic (FM) and paramagnetic (PM) characters were detected from the variation in magnetization as a function of magnetic fields at different temperatures. The second order transition was verified from the Arrott plots (M 2 vs. (μ 0 H/M)), where the slopes have a positive value. In order to verify the second order, we traced the variation of magnetization vs. temperature at different magnetic fields for x = 0.2. This revealed a ferromagnetic (FM)-paramagnetic (PM) transition when temperature increases. Relying on the indirect method while using the Maxwell formula, we determined the variation in the entropy (-ΔS M) as a function of temperature for different magnetic fields for the three samples. We note that all the studied systems stand as good candidates for magnetic refrigeration with relative cooling power (RCP) values of around 131.4, 83.38 and 57.26 J kg-1 with magnetic fields below 2 T, respectively. Subsequently, the magnetocaloric effect was investigated by a phenomenological model for x = 0.2. The extracted data confirm that this phenomenological model is appropriate for the prediction of magnetocaloric properties. The study also demonstrated that this La0.8□0.2MnO3 system exhibits a universal behaviour.Royal Society of Chemistry2020-02-24info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/106688http://hdl.handle.net/10316/106688https://doi.org/10.1039/c9ra10469keng354978332046-2069Henchiri, C.Mnasri, T.Benali, A.Hamdi, R.Dhahri, E.Valente, M. A.Costa, B. F. O.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-04-17T09:37:03Zoai:estudogeral.uc.pt:10316/106688Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:23:06.131184Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Structural study and large magnetocaloric entropy change at room temperature of La1-x □ x MnO3 compounds |
title |
Structural study and large magnetocaloric entropy change at room temperature of La1-x □ x MnO3 compounds |
spellingShingle |
Structural study and large magnetocaloric entropy change at room temperature of La1-x □ x MnO3 compounds Henchiri, C. |
title_short |
Structural study and large magnetocaloric entropy change at room temperature of La1-x □ x MnO3 compounds |
title_full |
Structural study and large magnetocaloric entropy change at room temperature of La1-x □ x MnO3 compounds |
title_fullStr |
Structural study and large magnetocaloric entropy change at room temperature of La1-x □ x MnO3 compounds |
title_full_unstemmed |
Structural study and large magnetocaloric entropy change at room temperature of La1-x □ x MnO3 compounds |
title_sort |
Structural study and large magnetocaloric entropy change at room temperature of La1-x □ x MnO3 compounds |
author |
Henchiri, C. |
author_facet |
Henchiri, C. Mnasri, T. Benali, A. Hamdi, R. Dhahri, E. Valente, M. A. Costa, B. F. O. |
author_role |
author |
author2 |
Mnasri, T. Benali, A. Hamdi, R. Dhahri, E. Valente, M. A. Costa, B. F. O. |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Henchiri, C. Mnasri, T. Benali, A. Hamdi, R. Dhahri, E. Valente, M. A. Costa, B. F. O. |
description |
In this study, our central focus is to investigate the magnetocaloric characteristics of a La1-x □ x MnO3 (x = 0.1, 0.2 and 0.3) series prepared by a sol-gel technique published in Prog. Mater. Sci., 93, 2018, 112-232. The crystallographic study revealed that our compounds crystallize in a rhombohedral structure with R3̄c. Ferromagnetic (FM) and paramagnetic (PM) characters were detected from the variation in magnetization as a function of magnetic fields at different temperatures. The second order transition was verified from the Arrott plots (M 2 vs. (μ 0 H/M)), where the slopes have a positive value. In order to verify the second order, we traced the variation of magnetization vs. temperature at different magnetic fields for x = 0.2. This revealed a ferromagnetic (FM)-paramagnetic (PM) transition when temperature increases. Relying on the indirect method while using the Maxwell formula, we determined the variation in the entropy (-ΔS M) as a function of temperature for different magnetic fields for the three samples. We note that all the studied systems stand as good candidates for magnetic refrigeration with relative cooling power (RCP) values of around 131.4, 83.38 and 57.26 J kg-1 with magnetic fields below 2 T, respectively. Subsequently, the magnetocaloric effect was investigated by a phenomenological model for x = 0.2. The extracted data confirm that this phenomenological model is appropriate for the prediction of magnetocaloric properties. The study also demonstrated that this La0.8□0.2MnO3 system exhibits a universal behaviour. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-02-24 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10316/106688 http://hdl.handle.net/10316/106688 https://doi.org/10.1039/c9ra10469k |
url |
http://hdl.handle.net/10316/106688 https://doi.org/10.1039/c9ra10469k |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
35497833 2046-2069 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799134118841155584 |