Imidazo-benzo-15-crown-5 ether bearing arylthienyl and bithienyl moieties as novel fluorescent chemosensors for Pd2+ and Cu2+

Detalhes bibliográficos
Autor(a) principal: Batista, Rosa Maria Ferreira
Data de Publicação: 2011
Outros Autores: Oliveira, Elisabete, Costa, Susana P. G., Lodeiro, Carlos, Raposo, M. Manuela M.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/15118
Resumo: Novel fluorescent ionophores bearing imidazo-arylthienyl or imidazo-bithienyl pi-conjugated bridges functionalized with one or two fused benzo-15-crown-5 ethers as receptor units are reported. The sensing ability of the compounds in the presence of metallic cations (Li+, Na+, K+, Ca2+, Zn2+, Cu2+, Ni2+, Pd2+ and Hg2+) and fluoride ion was studied in MeCN/DMSO solutions by absorption and emission spectroscopy. The experimental results indicate that all compounds could act as selective fluorimetric sensors for Cu2+ and Pd2+ and also for the fluoride ion, in the case of the bis-substituted crown ether derivatives.
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spelling Imidazo-benzo-15-crown-5 ether bearing arylthienyl and bithienyl moieties as novel fluorescent chemosensors for Pd2+ and Cu2+Crown ethersArylthiopheneBithiopheneImidazoleFluorescent chemosensorsCHEQ effectPd2+Cu2+F-Science & TechnologyNovel fluorescent ionophores bearing imidazo-arylthienyl or imidazo-bithienyl pi-conjugated bridges functionalized with one or two fused benzo-15-crown-5 ethers as receptor units are reported. The sensing ability of the compounds in the presence of metallic cations (Li+, Na+, K+, Ca2+, Zn2+, Cu2+, Ni2+, Pd2+ and Hg2+) and fluoride ion was studied in MeCN/DMSO solutions by absorption and emission spectroscopy. The experimental results indicate that all compounds could act as selective fluorimetric sensors for Cu2+ and Pd2+ and also for the fluoride ion, in the case of the bis-substituted crown ether derivatives.Fundação para a Ciência e a Tecnologia (FCT) - PTDC/QUI/66250/2006 (FCOMP-01-0124-FEDER-007428), SFRH/BD/36396/2007ElsevierUniversidade do MinhoBatista, Rosa Maria FerreiraOliveira, ElisabeteCosta, Susana P. G.Lodeiro, CarlosRaposo, M. Manuela M.20112011-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/15118eng0040-402010.1016/j.tet.2011.06.106http://www.sciencedirect.com/info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-11T07:31:54Zoai:repositorium.sdum.uminho.pt:1822/15118Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-11T07:31:54Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Imidazo-benzo-15-crown-5 ether bearing arylthienyl and bithienyl moieties as novel fluorescent chemosensors for Pd2+ and Cu2+
title Imidazo-benzo-15-crown-5 ether bearing arylthienyl and bithienyl moieties as novel fluorescent chemosensors for Pd2+ and Cu2+
spellingShingle Imidazo-benzo-15-crown-5 ether bearing arylthienyl and bithienyl moieties as novel fluorescent chemosensors for Pd2+ and Cu2+
Batista, Rosa Maria Ferreira
Crown ethers
Arylthiophene
Bithiophene
Imidazole
Fluorescent chemosensors
CHEQ effect
Pd2+
Cu2+
F-
Science & Technology
title_short Imidazo-benzo-15-crown-5 ether bearing arylthienyl and bithienyl moieties as novel fluorescent chemosensors for Pd2+ and Cu2+
title_full Imidazo-benzo-15-crown-5 ether bearing arylthienyl and bithienyl moieties as novel fluorescent chemosensors for Pd2+ and Cu2+
title_fullStr Imidazo-benzo-15-crown-5 ether bearing arylthienyl and bithienyl moieties as novel fluorescent chemosensors for Pd2+ and Cu2+
title_full_unstemmed Imidazo-benzo-15-crown-5 ether bearing arylthienyl and bithienyl moieties as novel fluorescent chemosensors for Pd2+ and Cu2+
title_sort Imidazo-benzo-15-crown-5 ether bearing arylthienyl and bithienyl moieties as novel fluorescent chemosensors for Pd2+ and Cu2+
author Batista, Rosa Maria Ferreira
author_facet Batista, Rosa Maria Ferreira
Oliveira, Elisabete
Costa, Susana P. G.
Lodeiro, Carlos
Raposo, M. Manuela M.
author_role author
author2 Oliveira, Elisabete
Costa, Susana P. G.
Lodeiro, Carlos
Raposo, M. Manuela M.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Batista, Rosa Maria Ferreira
Oliveira, Elisabete
Costa, Susana P. G.
Lodeiro, Carlos
Raposo, M. Manuela M.
dc.subject.por.fl_str_mv Crown ethers
Arylthiophene
Bithiophene
Imidazole
Fluorescent chemosensors
CHEQ effect
Pd2+
Cu2+
F-
Science & Technology
topic Crown ethers
Arylthiophene
Bithiophene
Imidazole
Fluorescent chemosensors
CHEQ effect
Pd2+
Cu2+
F-
Science & Technology
description Novel fluorescent ionophores bearing imidazo-arylthienyl or imidazo-bithienyl pi-conjugated bridges functionalized with one or two fused benzo-15-crown-5 ethers as receptor units are reported. The sensing ability of the compounds in the presence of metallic cations (Li+, Na+, K+, Ca2+, Zn2+, Cu2+, Ni2+, Pd2+ and Hg2+) and fluoride ion was studied in MeCN/DMSO solutions by absorption and emission spectroscopy. The experimental results indicate that all compounds could act as selective fluorimetric sensors for Cu2+ and Pd2+ and also for the fluoride ion, in the case of the bis-substituted crown ether derivatives.
publishDate 2011
dc.date.none.fl_str_mv 2011
2011-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/15118
url http://hdl.handle.net/1822/15118
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0040-4020
10.1016/j.tet.2011.06.106
http://www.sciencedirect.com/
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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