Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds
Autor(a) principal: | |
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Data de Publicação: | 2023 |
Outros Autores: | , , , , , , , , , , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10362/155181 |
Resumo: | Y. Ito acknowledges the financial support for the measurements of a part of the data by the REXDAB Collaboration that was initiated within the International Fundamental Parameter Initiative. This research was supported in part by FCT (Portugal) under research center grants UID/FIS/04559/2020 (LIBPhys). This work was also supported by the National Science Centre, Poland under grant number 2017/25/B/ST2/00901 and grant number 2021/05/X/ST2/01664, and by the Slovenian Research Agency (P1-0112). A. Kahoul and A. Hamidani acknowledge the support of the DGRSDT, Ministry of Higher Education and Scientific Research, Algeria, and of Mohamed El Bachir El Ibrahimi University, under project (PRFU) No. B00L02UN340120220001. Paul Indelicato is a member of the Allianz Program of the Helmholtz Association, contract n° EMMI HA-216 “Extremes of Density and Temperature: Cosmic Matter in the Laboratory”. P.I. acknowledge support from the PESSOA Hubert Curien Program 2022, Number 47863UE. Publisher Copyright: © 2023 by the authors. |
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Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compoundsatomic fundamental parameterschemical effects on intensity ratiosX-ray intensity ratiosCatalysisMolecular BiologySpectroscopyComputer Science ApplicationsPhysical and Theoretical ChemistryOrganic ChemistryInorganic ChemistryY. Ito acknowledges the financial support for the measurements of a part of the data by the REXDAB Collaboration that was initiated within the International Fundamental Parameter Initiative. This research was supported in part by FCT (Portugal) under research center grants UID/FIS/04559/2020 (LIBPhys). This work was also supported by the National Science Centre, Poland under grant number 2017/25/B/ST2/00901 and grant number 2021/05/X/ST2/01664, and by the Slovenian Research Agency (P1-0112). A. Kahoul and A. Hamidani acknowledge the support of the DGRSDT, Ministry of Higher Education and Scientific Research, Algeria, and of Mohamed El Bachir El Ibrahimi University, under project (PRFU) No. B00L02UN340120220001. Paul Indelicato is a member of the Allianz Program of the Helmholtz Association, contract n° EMMI HA-216 “Extremes of Density and Temperature: Cosmic Matter in the Laboratory”. P.I. acknowledge support from the PESSOA Hubert Curien Program 2022, Number 47863UE. Publisher Copyright: © 2023 by the authors.(Formula presented.) X-ray lines from photon excitation were measured in selected elements from Mg to Cu using a high-resolution double-crystal X-ray spectrometer with a proportional counter, and the (Formula presented.) intensity ratio for each element was obtained, after correcting for self-absorption, detection efficiency, and crystal reflectance. This intensity ratio increases rapidly from Mg to Ca but, in the (Formula presented.) elements region, the increase becomes slower. This is related to the intensity of the (Formula presented.) line involving valence electrons. The slow increase of this ratio in the (Formula presented.) elements region is thought to be due to the correlation between (Formula presented.) and (Formula presented.) electrons. Moreover, the chemical shifts, FWHM, asymmetry indices, and (Formula presented.) intensity ratios of the Cr compounds, due to different valences, were also investigated using the same double-crystal X-ray spectrometer. The chemical effects were clearly observed, and the (Formula presented.) intensity ratio was found to be compound-dependent for Cr.LIBPhys-UNLDF – Departamento de FísicaRUNIto, YoshiakiTochio, TatsunoriYamashita, MichiruFukushima, SeiShoji, TakashiSłabkowska, KatarzynaSyrocki, ŁukaszPolasik, MarekGomilsek, Jana PadežnikMarques, José PiresSampaio, Jorge MiguelGuerra, MauroMachado, JorgeSantos, José PauloHamidani, AssalaKahoul, AbdelhalimIndelicato, PaulParente, Fernando2023-07-12T22:19:43Z2023-03-142023-03-14T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article15application/pdfhttp://hdl.handle.net/10362/155181eng1661-6596PURE: 65999603https://doi.org/10.3390/ijms24065570info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:37:42Zoai:run.unl.pt:10362/155181Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:55:57.489843Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds |
title |
Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds |
spellingShingle |
Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds Ito, Yoshiaki atomic fundamental parameters chemical effects on intensity ratios X-ray intensity ratios Catalysis Molecular Biology Spectroscopy Computer Science Applications Physical and Theoretical Chemistry Organic Chemistry Inorganic Chemistry |
title_short |
Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds |
title_full |
Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds |
title_fullStr |
Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds |
title_full_unstemmed |
Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds |
title_sort |
Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds |
author |
Ito, Yoshiaki |
author_facet |
Ito, Yoshiaki Tochio, Tatsunori Yamashita, Michiru Fukushima, Sei Shoji, Takashi Słabkowska, Katarzyna Syrocki, Łukasz Polasik, Marek Gomilsek, Jana Padežnik Marques, José Pires Sampaio, Jorge Miguel Guerra, Mauro Machado, Jorge Santos, José Paulo Hamidani, Assala Kahoul, Abdelhalim Indelicato, Paul Parente, Fernando |
author_role |
author |
author2 |
Tochio, Tatsunori Yamashita, Michiru Fukushima, Sei Shoji, Takashi Słabkowska, Katarzyna Syrocki, Łukasz Polasik, Marek Gomilsek, Jana Padežnik Marques, José Pires Sampaio, Jorge Miguel Guerra, Mauro Machado, Jorge Santos, José Paulo Hamidani, Assala Kahoul, Abdelhalim Indelicato, Paul Parente, Fernando |
author2_role |
author author author author author author author author author author author author author author author author author |
dc.contributor.none.fl_str_mv |
LIBPhys-UNL DF – Departamento de Física RUN |
dc.contributor.author.fl_str_mv |
Ito, Yoshiaki Tochio, Tatsunori Yamashita, Michiru Fukushima, Sei Shoji, Takashi Słabkowska, Katarzyna Syrocki, Łukasz Polasik, Marek Gomilsek, Jana Padežnik Marques, José Pires Sampaio, Jorge Miguel Guerra, Mauro Machado, Jorge Santos, José Paulo Hamidani, Assala Kahoul, Abdelhalim Indelicato, Paul Parente, Fernando |
dc.subject.por.fl_str_mv |
atomic fundamental parameters chemical effects on intensity ratios X-ray intensity ratios Catalysis Molecular Biology Spectroscopy Computer Science Applications Physical and Theoretical Chemistry Organic Chemistry Inorganic Chemistry |
topic |
atomic fundamental parameters chemical effects on intensity ratios X-ray intensity ratios Catalysis Molecular Biology Spectroscopy Computer Science Applications Physical and Theoretical Chemistry Organic Chemistry Inorganic Chemistry |
description |
Y. Ito acknowledges the financial support for the measurements of a part of the data by the REXDAB Collaboration that was initiated within the International Fundamental Parameter Initiative. This research was supported in part by FCT (Portugal) under research center grants UID/FIS/04559/2020 (LIBPhys). This work was also supported by the National Science Centre, Poland under grant number 2017/25/B/ST2/00901 and grant number 2021/05/X/ST2/01664, and by the Slovenian Research Agency (P1-0112). A. Kahoul and A. Hamidani acknowledge the support of the DGRSDT, Ministry of Higher Education and Scientific Research, Algeria, and of Mohamed El Bachir El Ibrahimi University, under project (PRFU) No. B00L02UN340120220001. Paul Indelicato is a member of the Allianz Program of the Helmholtz Association, contract n° EMMI HA-216 “Extremes of Density and Temperature: Cosmic Matter in the Laboratory”. P.I. acknowledge support from the PESSOA Hubert Curien Program 2022, Number 47863UE. Publisher Copyright: © 2023 by the authors. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-07-12T22:19:43Z 2023-03-14 2023-03-14T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/155181 |
url |
http://hdl.handle.net/10362/155181 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1661-6596 PURE: 65999603 https://doi.org/10.3390/ijms24065570 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
15 application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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