HOMO Energy-Level Lifting in p-Type O-Doped Graphenoids

Detalhes bibliográficos
Autor(a) principal: Rossignon, Alexandre
Data de Publicação: 2022
Outros Autores: Berna, Beatrice Berionni, Parola, A. Jorge, Laia, César A. T., Bonifazi, Davide
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/146556
Resumo: Funding Information D.B. gratefully acknowledges the EU through the MSCA-RISE (project: INFUSION, No. 734834) and MSCA-IF “ENTERPRISE” (project number: 897396) and the University of Vienna for generous financial support. B.B.B. thanks the MSCA-IF “ENTERPRISE” project for her post-doctoral fellowship. A.R. thanks the FNRS for his doctoral fellowship. The collaboration between D.B., J.P. and C.L. is supported by the MSCA-RISE INFUSION project.
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spelling HOMO Energy-Level Lifting in p-Type O-Doped GraphenoidsSynthesis of Electrochromic Alkoxy-Decorated XanthenoxanthenesPolycyclic aromatic hydrocarbonsPXXElectrochromismOxygen heterocyclesElectrochromic devicesFunding Information D.B. gratefully acknowledges the EU through the MSCA-RISE (project: INFUSION, No. 734834) and MSCA-IF “ENTERPRISE” (project number: 897396) and the University of Vienna for generous financial support. B.B.B. thanks the MSCA-IF “ENTERPRISE” project for her post-doctoral fellowship. A.R. thanks the FNRS for his doctoral fellowship. The collaboration between D.B., J.P. and C.L. is supported by the MSCA-RISE INFUSION project.A series of novel O-doped polycyclic aromatic hydrocarbons (PAHs), bearing a different number of electron donating alkoxy substituents, has been prepared using a novel copper-promoted anaerobic protocol for the cyclisation of highly electron rich peri-xanthenoxanthene (PXX) molecular modules. The effect of the number and position of the alkoxy substituents on the optoelectronic properties has thus been investigated, unveiling p-type semiconducting properties. All molecules displayed a significant colour change upon oxidation, suggesting that these compounds can be used to devise chromogenic materials to engineer electrochromic devices.DQ - Departamento de QuímicaLAQV@REQUIMTERUNRossignon, AlexandreBerna, Beatrice BerionniParola, A. JorgeLaia, César A. T.Bonifazi, Davide2022-12-22T22:18:50Z2022-122022-12-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article14application/pdfhttp://hdl.handle.net/10362/146556engPURE: 48434137https://doi.org/10.1055/a-1976-0291info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:27:40Zoai:run.unl.pt:10362/146556Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:52:40.611738Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv HOMO Energy-Level Lifting in p-Type O-Doped Graphenoids
Synthesis of Electrochromic Alkoxy-Decorated Xanthenoxanthenes
title HOMO Energy-Level Lifting in p-Type O-Doped Graphenoids
spellingShingle HOMO Energy-Level Lifting in p-Type O-Doped Graphenoids
Rossignon, Alexandre
Polycyclic aromatic hydrocarbons
PXX
Electrochromism
Oxygen heterocycles
Electrochromic devices
title_short HOMO Energy-Level Lifting in p-Type O-Doped Graphenoids
title_full HOMO Energy-Level Lifting in p-Type O-Doped Graphenoids
title_fullStr HOMO Energy-Level Lifting in p-Type O-Doped Graphenoids
title_full_unstemmed HOMO Energy-Level Lifting in p-Type O-Doped Graphenoids
title_sort HOMO Energy-Level Lifting in p-Type O-Doped Graphenoids
author Rossignon, Alexandre
author_facet Rossignon, Alexandre
Berna, Beatrice Berionni
Parola, A. Jorge
Laia, César A. T.
Bonifazi, Davide
author_role author
author2 Berna, Beatrice Berionni
Parola, A. Jorge
Laia, César A. T.
Bonifazi, Davide
author2_role author
author
author
author
dc.contributor.none.fl_str_mv DQ - Departamento de Química
LAQV@REQUIMTE
RUN
dc.contributor.author.fl_str_mv Rossignon, Alexandre
Berna, Beatrice Berionni
Parola, A. Jorge
Laia, César A. T.
Bonifazi, Davide
dc.subject.por.fl_str_mv Polycyclic aromatic hydrocarbons
PXX
Electrochromism
Oxygen heterocycles
Electrochromic devices
topic Polycyclic aromatic hydrocarbons
PXX
Electrochromism
Oxygen heterocycles
Electrochromic devices
description Funding Information D.B. gratefully acknowledges the EU through the MSCA-RISE (project: INFUSION, No. 734834) and MSCA-IF “ENTERPRISE” (project number: 897396) and the University of Vienna for generous financial support. B.B.B. thanks the MSCA-IF “ENTERPRISE” project for her post-doctoral fellowship. A.R. thanks the FNRS for his doctoral fellowship. The collaboration between D.B., J.P. and C.L. is supported by the MSCA-RISE INFUSION project.
publishDate 2022
dc.date.none.fl_str_mv 2022-12-22T22:18:50Z
2022-12
2022-12-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/146556
url http://hdl.handle.net/10362/146556
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv PURE: 48434137
https://doi.org/10.1055/a-1976-0291
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 14
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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