New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer

Detalhes bibliográficos
Autor(a) principal: Vilas-Boas, Miguel
Data de Publicação: 1997
Outros Autores: Freire, Cristina, Castro, Baltazar de, Christensen, Paul A., Hillman, A. Robert
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10198/5892
Resumo: Oxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)], in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by ex situ EPR experiments.
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spelling New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymerOxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)], in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by ex situ EPR experiments.ABiblioteca Digital do IPBVilas-Boas, MiguelFreire, CristinaCastro, Baltazar deChristensen, Paul A.Hillman, A. Robert2011-07-18T14:44:23Z19971997-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10198/5892engVilas-Boas, Miguel; Freire, C.; Castro, B.; Christensen, P.A.; Hillman, A.R. (1997). New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer. Inorganic Chemistry. ISSN 0020-1669. 36:22, p. 4919-49290020-166910.1021/ic970467jinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-11-21T10:13:58Zoai:bibliotecadigital.ipb.pt:10198/5892Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T22:57:42.121805Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer
title New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer
spellingShingle New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer
Vilas-Boas, Miguel
title_short New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer
title_full New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer
title_fullStr New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer
title_full_unstemmed New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer
title_sort New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer
author Vilas-Boas, Miguel
author_facet Vilas-Boas, Miguel
Freire, Cristina
Castro, Baltazar de
Christensen, Paul A.
Hillman, A. Robert
author_role author
author2 Freire, Cristina
Castro, Baltazar de
Christensen, Paul A.
Hillman, A. Robert
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Biblioteca Digital do IPB
dc.contributor.author.fl_str_mv Vilas-Boas, Miguel
Freire, Cristina
Castro, Baltazar de
Christensen, Paul A.
Hillman, A. Robert
description Oxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)], in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by ex situ EPR experiments.
publishDate 1997
dc.date.none.fl_str_mv 1997
1997-01-01T00:00:00Z
2011-07-18T14:44:23Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10198/5892
url http://hdl.handle.net/10198/5892
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Vilas-Boas, Miguel; Freire, C.; Castro, B.; Christensen, P.A.; Hillman, A.R. (1997). New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer. Inorganic Chemistry. ISSN 0020-1669. 36:22, p. 4919-4929
0020-1669
10.1021/ic970467j
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv A
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dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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