Crystal structure of an organic-inorganic supramolecular salt based on a 4,4 '-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a beta-octamolybdate anion

• Autor(a) principal: Amarante, Tatiana R.
• Data de Publicação: 2016
• Outros Autores: Goncalves, Isabel S., Almeida Paz, Filipe A.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
• Texto Completo: http://hdl.handle.net/10773/19788
• topic: COORDINATION POLYMERS; ALCOHOLS; DATABASE; LIGANDS

The asymmetric unit of the title compound, bis[4,4'-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium)] beta-octamolybdate, (C11H18N4)(2)[Mo8O26] or (H(4)mbdpz)(2)[Mo8O26], is composed of an H(4)mbdpz(2+) cation and half of the beta-octamolybdate anion which is completed by inversion symmetry. The organic molecular units are engaged in a series of N-H center dot center dot center dot O hydrogen bonds with neighbouring anions, with N center dot center dot center dot O distances and N-H center dot center dot center dot O angles in the ranges 2.730 (2)-2.941 (2) angstrom and 122-166 degrees, respectively. These interactions lead to the formation of a supramolecular two-dimensional network parallel to the (010) plane.