Long-lived NIR emission in sulfur-doped zeolites due to the presence of [S3]2- clusters

Detalhes bibliográficos
Autor(a) principal: Viola, Catarina
Data de Publicação: 2023
Outros Autores: Laia, César A. T., Outis, Mani, Ferreira, Luís F. V., Alves, Luís C., Teixeira, Miguel, Folgosa, Filipe, Lima, João C., Ruivo, Andreia, Avó, João
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/154629
Resumo: the individual contract 2020.00252. CEECIND and several projects PTDC/QUI- LA/P/0140/2020, LAQV-REQUIMTE (LA/P/0008/2020). LS4FUTURE Associated Laboratory (LA/P/0087/2020) Publisher Copyright: © 2023 The Author(s)
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spelling Long-lived NIR emission in sulfur-doped zeolites due to the presence of [S3]2- clustersChalcogen-doped zeolitesLuminescent materialsNear-infrared luminescenceOptical spectroscopyTime-resolved spectroscopyCatalysisElectronic, Optical and Magnetic MaterialsBiomaterialsPolymers and PlasticsColloid and Surface ChemistryMaterials Chemistrythe individual contract 2020.00252. CEECIND and several projects PTDC/QUI- LA/P/0140/2020, LAQV-REQUIMTE (LA/P/0008/2020). LS4FUTURE Associated Laboratory (LA/P/0087/2020) Publisher Copyright: © 2023 The Author(s)The exploration of novel long-lived near-infrared (NIR) luminescent materials has attracted significant attention due to their applications in optical communications, anticounterfeiting, and bioimaging. However, these materials usually present low photoluminescence quantum yields and low photo- and chemical stability. Novel emitters that overcome these limitations are in demand. In this study, NIR emission was achieved using widely available, sustainable, and non-toxic materials through the synthesis of sulfur-doped zeolites, with different S/Cl ratios. With a combination of computational calculations (TD-DFT) and spectroscopic data, this emission was assigned to the radiative decay of excited triplet states of [S3]2- clusters, which resulted in a remarkably high Stokes shift (1.97 eV, 440 nm) and an average decay time of 0.54 ms. These new materials present high stability, external quantum efficiency of up to 17%, and a long-lived NIR emission, placing these compounds in a unique position to be used in applications demanding NIR emitters.DQ - Departamento de QuímicaLAQV@REQUIMTEVICARTE - Vidro e Cerâmica para as ArtesInstituto de Tecnologia Química e Biológica António Xavier (ITQB)RUNViola, CatarinaLaia, César A. T.Outis, ManiFerreira, Luís F. V.Alves, Luís C.Teixeira, MiguelFolgosa, FilipeLima, João C.Ruivo, AndreiaAvó, João2023-06-29T22:17:59Z2023-062023-06-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article9application/pdfhttp://hdl.handle.net/10362/154629engPURE: 64823356https://doi.org/10.1016/j.mtchem.2023.101514info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-18T01:43:04Zoai:run.unl.pt:10362/154629Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:55:42.558554Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Long-lived NIR emission in sulfur-doped zeolites due to the presence of [S3]2- clusters
title Long-lived NIR emission in sulfur-doped zeolites due to the presence of [S3]2- clusters
spellingShingle Long-lived NIR emission in sulfur-doped zeolites due to the presence of [S3]2- clusters
Viola, Catarina
Chalcogen-doped zeolites
Luminescent materials
Near-infrared luminescence
Optical spectroscopy
Time-resolved spectroscopy
Catalysis
Electronic, Optical and Magnetic Materials
Biomaterials
Polymers and Plastics
Colloid and Surface Chemistry
Materials Chemistry
title_short Long-lived NIR emission in sulfur-doped zeolites due to the presence of [S3]2- clusters
title_full Long-lived NIR emission in sulfur-doped zeolites due to the presence of [S3]2- clusters
title_fullStr Long-lived NIR emission in sulfur-doped zeolites due to the presence of [S3]2- clusters
title_full_unstemmed Long-lived NIR emission in sulfur-doped zeolites due to the presence of [S3]2- clusters
title_sort Long-lived NIR emission in sulfur-doped zeolites due to the presence of [S3]2- clusters
author Viola, Catarina
author_facet Viola, Catarina
Laia, César A. T.
Outis, Mani
Ferreira, Luís F. V.
Alves, Luís C.
Teixeira, Miguel
Folgosa, Filipe
Lima, João C.
Ruivo, Andreia
Avó, João
author_role author
author2 Laia, César A. T.
Outis, Mani
Ferreira, Luís F. V.
Alves, Luís C.
Teixeira, Miguel
Folgosa, Filipe
Lima, João C.
Ruivo, Andreia
Avó, João
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv DQ - Departamento de Química
LAQV@REQUIMTE
VICARTE - Vidro e Cerâmica para as Artes
Instituto de Tecnologia Química e Biológica António Xavier (ITQB)
RUN
dc.contributor.author.fl_str_mv Viola, Catarina
Laia, César A. T.
Outis, Mani
Ferreira, Luís F. V.
Alves, Luís C.
Teixeira, Miguel
Folgosa, Filipe
Lima, João C.
Ruivo, Andreia
Avó, João
dc.subject.por.fl_str_mv Chalcogen-doped zeolites
Luminescent materials
Near-infrared luminescence
Optical spectroscopy
Time-resolved spectroscopy
Catalysis
Electronic, Optical and Magnetic Materials
Biomaterials
Polymers and Plastics
Colloid and Surface Chemistry
Materials Chemistry
topic Chalcogen-doped zeolites
Luminescent materials
Near-infrared luminescence
Optical spectroscopy
Time-resolved spectroscopy
Catalysis
Electronic, Optical and Magnetic Materials
Biomaterials
Polymers and Plastics
Colloid and Surface Chemistry
Materials Chemistry
description the individual contract 2020.00252. CEECIND and several projects PTDC/QUI- LA/P/0140/2020, LAQV-REQUIMTE (LA/P/0008/2020). LS4FUTURE Associated Laboratory (LA/P/0087/2020) Publisher Copyright: © 2023 The Author(s)
publishDate 2023
dc.date.none.fl_str_mv 2023-06-29T22:17:59Z
2023-06
2023-06-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/154629
url http://hdl.handle.net/10362/154629
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv PURE: 64823356
https://doi.org/10.1016/j.mtchem.2023.101514
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 9
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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