Synthesis, spectroscopic characterization and Second Harmonic Generation efficiencies of monocyclopenta¬dienylruthenium(II) complexes with substituted thiophene nitrile ligands

Detalhes bibliográficos
Autor(a) principal: Mendes, Paulo J.
Data de Publicação: 2009
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10174/5327
Resumo: A systematic series of η5-monocyclopentadienylruthenium(II) complexes with substituted thiophene nitrile ligands of general formula [Ru5-C5H5)(P_P)(NC{SC4H2}nNO2)][PF6] (P_P=dppe, (+)-diop; n=1-3) has been synthesized and characterized. Spectroscopic and electrochemical data were used in order to get an insight on the molecular nonlinear-optical properties of these complexes when compared to those found for the reported thiophene iron(II) and p-benzonitrile or 1,2-di-(2-thienyl)-ethene derived iron(II)/ruthenium(II) related complexes. The compound Ru5-C5H5)(dppe)(NC{SC4H2}2NO2)][PF6] was also characterized by X-ray diffraction. The solid state nonlinear optical properties of the chiral compounds were also evaluated by Kurtz powder technique with a Nd:YAG laser emitting at 1064 nm .
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spelling Synthesis, spectroscopic characterization and Second Harmonic Generation efficiencies of monocyclopenta¬dienylruthenium(II) complexes with substituted thiophene nitrile ligandsRuthenium(II)MonocyclopentadienylThiophene ligandsCyclic voltammetrySecond harmonic generationA systematic series of η5-monocyclopentadienylruthenium(II) complexes with substituted thiophene nitrile ligands of general formula [Ru5-C5H5)(P_P)(NC{SC4H2}nNO2)][PF6] (P_P=dppe, (+)-diop; n=1-3) has been synthesized and characterized. Spectroscopic and electrochemical data were used in order to get an insight on the molecular nonlinear-optical properties of these complexes when compared to those found for the reported thiophene iron(II) and p-benzonitrile or 1,2-di-(2-thienyl)-ethene derived iron(II)/ruthenium(II) related complexes. The compound Ru5-C5H5)(dppe)(NC{SC4H2}2NO2)][PF6] was also characterized by X-ray diffraction. The solid state nonlinear optical properties of the chiral compounds were also evaluated by Kurtz powder technique with a Nd:YAG laser emitting at 1064 nm .Elsevier2012-10-11T10:02:00Z2012-10-112009-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10174/5327http://hdl.handle.net/10174/5327engJ. Organomet. Chem. 694 (2009) 2888-2897http://www.sciencedirect.com/science/article/pii/S0022328X0900271XQUI-Publicações-Artigos em Revistas Internacionais com Arbitragem Científicapjgm@uevora.pt306Mendes, Paulo J.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-01-03T18:43:57Zoai:dspace.uevora.pt:10174/5327Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T01:00:19.953774Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Synthesis, spectroscopic characterization and Second Harmonic Generation efficiencies of monocyclopenta¬dienylruthenium(II) complexes with substituted thiophene nitrile ligands
title Synthesis, spectroscopic characterization and Second Harmonic Generation efficiencies of monocyclopenta¬dienylruthenium(II) complexes with substituted thiophene nitrile ligands
spellingShingle Synthesis, spectroscopic characterization and Second Harmonic Generation efficiencies of monocyclopenta¬dienylruthenium(II) complexes with substituted thiophene nitrile ligands
Mendes, Paulo J.
Ruthenium(II)
Monocyclopentadienyl
Thiophene ligands
Cyclic voltammetry
Second harmonic generation
title_short Synthesis, spectroscopic characterization and Second Harmonic Generation efficiencies of monocyclopenta¬dienylruthenium(II) complexes with substituted thiophene nitrile ligands
title_full Synthesis, spectroscopic characterization and Second Harmonic Generation efficiencies of monocyclopenta¬dienylruthenium(II) complexes with substituted thiophene nitrile ligands
title_fullStr Synthesis, spectroscopic characterization and Second Harmonic Generation efficiencies of monocyclopenta¬dienylruthenium(II) complexes with substituted thiophene nitrile ligands
title_full_unstemmed Synthesis, spectroscopic characterization and Second Harmonic Generation efficiencies of monocyclopenta¬dienylruthenium(II) complexes with substituted thiophene nitrile ligands
title_sort Synthesis, spectroscopic characterization and Second Harmonic Generation efficiencies of monocyclopenta¬dienylruthenium(II) complexes with substituted thiophene nitrile ligands
author Mendes, Paulo J.
author_facet Mendes, Paulo J.
author_role author
dc.contributor.author.fl_str_mv Mendes, Paulo J.
dc.subject.por.fl_str_mv Ruthenium(II)
Monocyclopentadienyl
Thiophene ligands
Cyclic voltammetry
Second harmonic generation
topic Ruthenium(II)
Monocyclopentadienyl
Thiophene ligands
Cyclic voltammetry
Second harmonic generation
description A systematic series of η5-monocyclopentadienylruthenium(II) complexes with substituted thiophene nitrile ligands of general formula [Ru5-C5H5)(P_P)(NC{SC4H2}nNO2)][PF6] (P_P=dppe, (+)-diop; n=1-3) has been synthesized and characterized. Spectroscopic and electrochemical data were used in order to get an insight on the molecular nonlinear-optical properties of these complexes when compared to those found for the reported thiophene iron(II) and p-benzonitrile or 1,2-di-(2-thienyl)-ethene derived iron(II)/ruthenium(II) related complexes. The compound Ru5-C5H5)(dppe)(NC{SC4H2}2NO2)][PF6] was also characterized by X-ray diffraction. The solid state nonlinear optical properties of the chiral compounds were also evaluated by Kurtz powder technique with a Nd:YAG laser emitting at 1064 nm .
publishDate 2009
dc.date.none.fl_str_mv 2009-01-01T00:00:00Z
2012-10-11T10:02:00Z
2012-10-11
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10174/5327
http://hdl.handle.net/10174/5327
url http://hdl.handle.net/10174/5327
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv J. Organomet. Chem. 694 (2009) 2888-2897
http://www.sciencedirect.com/science/article/pii/S0022328X0900271X
QUI-Publicações-Artigos em Revistas Internacionais com Arbitragem Científica
pjgm@uevora.pt
306
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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